• Title/Summary/Keyword: 무기인산

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Changes and Availability of Inorganic Phosphate during the Composting (Pig Manure) (퇴비화 과정 중 인산의 가용화와 무기태 인산의 변화)

  • Lee, Yu-Ri;Lee, Jong-Eun;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.1
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    • pp.127-128
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    • 2003
  • 본 연구는 퇴비화 과정 중 난용성 인산의 가용화와 무기태 인산의 변화를 알아보기 위하여 수행하였다. 비료와 퇴비중의 인산형태는 다른 성분들보다 토양에 흡착 또는 고정되거나 불용화 되는 양이 많아 작물의 흡수량이 적다. 시비된 인산의 흡수율은 낮고, 그 대부분은 난용화되기 때문에 토양에 축적되거나 세탈과 용탈에 의해 수질을 오염화시키는 주원인이 되고 있다. 퇴비화 과정중의 인산형태별 함량변화를 분석조사하여 작물에 시비되는 인산비료와 퇴비의 시용량을 적절하게 조절하여 인산의 과잉 시비량을 저감시키기 위한 연구이다. 돈분을 원료로 한 퇴비화 과정에서 단계별로 퇴비시료를 채취하여 총인산(T-P), 유효인산(Avail. -P)과 무기태인산분획별(Ca-P, Al-P, Fe-P)로 분석한 결과는 다음과 같다. 퇴적더미의 초기부피는 570L였으며, 약 2개월간의 퇴비화를 통해서 시료채취와 미생물등의 분해작용으로 최종부피는 430L정도로 감소하였다. 이는 초기의 부피보다 25% 감소하였다. 퇴적더미의 분해로 인한 용적밀도의 변화를 고려하면, 총인산 함량은 초기 약 17,500mg/kg에서 최종시료는 22,500mg/kg로 증가되었다. 또한 퇴비화가 진행됨에 따라 인산의 가용태가 증가하는 결과를 보였으며, 초기의 유효인산이 4,500mg/kg에서 최종시료에서는 8,900mg/kg으로 증가되었다. 그리고 무기태 인산분획별 인산의 형태별 변화를 조사한 결과, 퇴비화 과정 중 Ca-P의 경우 pH와의 중요한 상관관계를 갖고 있었다. 유기물분해를 통해 유리된 인산과 Ca은 난용태로 전환되는데, 초기의 약 10일 동안 Ca-P의 감소원인은 pH의 감소로 인한 Ca이 유리되는 정도가 낮기 때문인 것으로 해석된다. 초기 Ca-P형태의 인산함량은 11,900mg/kg으로 Fe-P와 Al-P보다 많았다. 또한 퇴비화가 안정화되어 부숙된 최종시료의 무기태 인산분획물 중 Ca-P는 18,000mg/kg로 증가하였으며, Ca-P>Al-P>Fe-P의 순 이었다. 그러나 Al-P와 Fe-P 형태의 무기태인산은 초기의 함량비율보다 다소 감소한 결과를 보였다. 결론적으로, 퇴비화과정 중 단계별 인산함량의 형태전환을 분석한 결과 총인산의 함량은 퇴비화가 안정화될수록 부피감소로 인한 인산함량이 증가하는 경향을 보였지만, 유기물질의 분해로 인한 원료내 인산의 형태가 불용태와 난용태에서 가용태 인산으로 전환되는 것을 도출하였다. 또한 무기태 인산분획물에서는 Ca-P 인산형태가 퇴비화가 진행될수록 증가한다는 결과를 얻었으며, Fe-P와 Al-P는 분해된 유기물의 킬레이트작용으로 감소되었다고 판단되며, 그 존재형태가 경쟁적임을 알 수 있었다. 따라서 화학비료와 퇴비의 시용이 병행될 경우에는 퇴비의 가용태 인산함량뿐만 아니라 무기태 인산의 함량을 분석한 후 인산질비료의 시비량을 조절해야할 것으로 판단된다.

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Studies on the Changes in Activities of ALPase, ACPase, ATPase and Synthesis of Volutin Granules upon Phosphate Concentration in Saccharomyces uvarum (Saccharomyces uvarum의 인삼염첨가배양에 따른 ALPase, ACPase, ATPase 활성도와 volutin과립의 함량변화)

  • 이기성;최영길
    • Korean Journal of Microbiology
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    • v.23 no.2
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    • pp.84-89
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    • 1985
  • The effect of exogenous phosphate supply on the regulation of phosphate metabolism was investegated during catabolic repression and catabolic derepression in yeast (Saccharomyces uvarum). As the results, when sugar was supplimented in cells cultivated under phosphate free, the growith rate was low but it was capable of cell division. Polyphosphate "B" was accumulated highly in proportion to amount of phosphate added to the medium. Without regard to phosphate supply of the medium, the total amount of polyphospgate was almost similar, although each polyphosphate was turned over. Activities of all phosphatases remained continuousoy high in the cells cultivated in the phosphate free medium. Especially under catabolic repression, the function of polyphosphate system was shown to compensate the ATP/ADP system as phosphate donor, energy source and regulator.

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Distribution of phosphorus in particle-size separates and specific gravity separates of soils (입경 및 비중별(比重別) 토양분화과 인산분포(燐酸分布))

  • Hong, Jung-Kook
    • Korean Journal of Soil Science and Fertilizer
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    • v.12 no.4
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    • pp.179-187
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    • 1980
  • 1) Soils (volcanic ash and muck) were fractionated into particle-size separates (200 - 20, 20 - 2, 2 - 0.5 and finer than $0.5{\mu}$ in diamter), and of which the silt fraction was further fractionated into specific gravity separates (more than 2.0, 2.0 - 1.7, 1.7 - 1.4 and less than 1.4 in $g/cc^3$). And total organic and inorganic phosphorus in the separates were determined. 2) The amounts of total, organic and inorganic phosphorus distributed in the particle-size separates were as follows fine clay > coarse clay > silt > fine sand fraction. The increase rate in the amounts of phosphorus was great in the separates finer than $20{\mu}$, and greatest in the fine clay fraction. 3) The amounts of total, oganic and inorganic phosphorus distributed in the specific gravity separates were as follows: 2.0 - 1.7 > 1.7 - 1.4 > heavier than 2.0 fraction. The increase rate in the amounts of phosphorus was in the following order 2.0 - 1.7 > 1.7 - 1.4 > heavier than 2.0 fraction. 4) Distribution of carbon, amorphous aluminum and free iron oxides in the particle-size separates and the specific gravity separates were examined, and the distribution and the formes of organo-minera1 complexes in the separates were discussed to shed light on the factors affecting the distribution of phosphorous into the separates. And it was estimated that there was close relation among the distribution of organic and inorganic phosphorus, and the distribution and the formes of organo-minera1 complexes.

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Accumulation of inorganic arsenic, and growth rate by changing of phosphate concentration in Hizikia fusiforme (인산염 농도 변화에 따른 톳(Hizikia fusiforme)의 무기비소(As (V)) 축적 및 생장률 변동)

  • Hwang, Un-Ki;Choi, Hoon;Choi, Min-Kyu;Kim, Min-Seob;Choi, Jong-Woo;Heo, Seung;Lee, Ju-Wook
    • Korean Journal of Environmental Biology
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    • v.37 no.2
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    • pp.189-195
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    • 2019
  • In this study, we performed an analysis of the accumulation of inorganic arsenic and growth rate with changes in phosphate concentration in Hizikia fusiforme. When exposed to inorganic arsenic for fourteen days, we found that the collection of inorganic arsenic hardly increased at high phosphate concentrations (2 mg L-1). However, when the phosphate concentration was low (0.02 mg L-1), accumulation of inorganic arsenic increased. Additionally, H. fusiforme decreased in a growth rate of 14.5% in low phosphate concentration (0.02 mg L-1) and fell in a growth rate of 30% when exposed to inorganic arsenic (10 ㎍ L-1). H. fusiforme cannot distinguish between phosphate and inorganic arsenic. Thus, when phosphate concentration was lower, the inorganic arsenic accumulation increased, and accumulated inorganic arsenic inhibited photosynthesis and cell division, reducing the growth rate. H. fusiforme is known to have higher inorganic arsenic accumulation than other seaweeds. Therefore, various studies are needed to secure the food safety of H. fusiforme which is an essential aquaculture species in Korea.

Influence of Mineral Nutritions and Phosphorus Concentration in Culture Solution to the Ferrous Absorption of Rice and Barley (배양액중의 무기영양, 인산통도가 수도, 대맥의 철흡수에 미치는 영향)

  • Kyeong-Bea Park;Ho-Sung Ha
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.23 no.1
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    • pp.14-20
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    • 1978
  • To find out the influence of mineral nutritions and phosphorus concentration to ferrous absorption of rice and barley plants were studied in the culture solution which has various levels of ferrous and phosphorus with deficiency of mineral nuritiont. The ferrous absorption of rice and barley plants were greatly affected by phosphorus and potassium in the culture solution among mineral nutritions. The ferrous absorption was decreased with the increasing of phosphorus concentration. The rate of ferrous translocation was higher in barley plant than that of rice plant. And also, the symptoms of ferrous toxicity occurred easily in the barley plant. From these results, it was concluded that the ferrous was more influential upon the growth of barley than that of rice.

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Studies on the Characteristics of Phosphorus in the Upland Soil I. Composition of Accumulated Phosphorus Forms and Available Phosphorus (경작지(耕作地) 전토양(田土壤)의 인산특성(燐酸特性)에 관(關)한 연구(硏究) I. 축적인산(蓄積燐酸)의 형태별(形態別) 조성(造成)과 유효인산(有效燐酸) 함량(含量)과의 관계(關係))

  • Shin, Cheol-Woo;Kim, Jeong-Je;Yoon, Jung-Hui
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.1
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    • pp.21-29
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    • 1988
  • A laboratory experiment was conducted to evaluate the phosphorus status and define the relationship between composition of phosphorus forms and available phosphorus with 149 phosphorus accumulated soil samples. Distribution percentage of inorganic, organic and available phosphorous to total phosphorus were 68.9 (Saloid-p 2.7, Al-p 26.4, Fe-p 27.6, Ca-p 12.2%), 6.7 and 26.0%, respectively. In the relationship between available phosphorus and inorganic phosphorus in soil, Al-p, Saloid-P, and Ca-P showed significant correlation with available phosphorus which did not showed significant one with Fe-p. Multiple liner regression equation between available and inoganic phosphorus abtained as follow, $Av.P=81.694+0.858Sa-p^{***}+0.648Al-p^{***}+0.091Ca-p^{**}(R=0.826^{***})$ and contribution rates of Saloid-p, Al-p, and Ca-p to available phosphorus were 26.1, 65.2, and 8.7%, respectively. Relationship between available and water soluble phosphorus, water soluble phosphorus and $0.01M-CaCl_2-p$ were highly significant, respectively, and soil solution P extracted with $0.01M-CaCl_2$ for 30 minutes was selected as one of usable diagnostic techniques for soil P status.

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Arbuscular-Mycorrhizae Colonization and Mineral Nutrient Uptake of Poncirus trifoliata Seedling in Volcanic Ash Soil (화산회토양에서 인산 시용수준별 탱자 유묘의 공생균근 형성과 무기양분 흡수)

  • Kang, Suk-Bum;Moon, Doo-Khil;Chung, Jong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.4
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    • pp.283-291
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    • 2000
  • The beneficial effects of mycorrhizal fungi on plant growth has largely been attributed to higher uptake of P and other mineral nutrients. However, the effects of mycorrhizal colonization on uptake of mineral nutrients are conflicting in various past investigations. This study was carried out to investigate the effect of P application rate on mycorrhizal colonization and nutrient uptake of Poncirus trifoliata (trifoliate orange) seedlings grown in non-cultivated volcanic ash soil of Cheju island. Five levels of P (40, 573, 1,106, 1,373. $1,640mg\;P\;kg^{-1}$) were applied with double superphosphate. Seedlings inoculated with mycorrhizal fungi were grown for 5 month in a greenhouse. As the level of P application increased, mycorrhizal colonization in the seedlings decreased, and the colonization was significantly reduced when available P was higher than $150mg\;P\;kg^{-1}$ levels. There was a significant correlation between mycorrhizal colonization and P uptake by trifoliate orange seedlings at lower P applications. The effectiveness of mycorrhiaze on P uptake was more significant at lower P applications. Uptake of N, K, Ca, Mg an Zn by trifoliate orange seedlings also increased as mycorrhizal colonization increased, but mycorrhizae could not enhance the uptake of Cu by trifoliate orange seedlings in volcanic ash soil of Cheju island.

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A Study on Composition of Inorganic phosphorus Forms and Methods of Determining Available Phosphorus in Volcanic Ash (제주도토양의 무기태인산(無機態燐酸) 조성(組成)과 유효인산의 정량법(定量法) 비교(比較))

  • Shin, Cheol-Woo;Ryu, In-Soo;Yoon, Jung-Hui
    • Korean Journal of Soil Science and Fertilizer
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    • v.13 no.3
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    • pp.93-97
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    • 1981
  • Laboratory experiment was carried out to investigate the changes in the amount of inorganic phosphorus fractions of native and applied phosphorus and to compare the some analytical methods of soil phosphorus in volcanic ash. The rates of inorganic phosphorus to total-pP were varied with the kinds of soil in the ranges of 6.9 to 28.8% for Al-P, 24.1 to 26.9% for Fe-P, 7.4 to 11.9% for Ca-P and 0.7 to 8.0% for available phosphorus. The composition of inorganic phosphorus after incubation for 60 days was in the order of Al-P>Fe-P>Ca-P in Black soil, Fe-P>Al-P>Ca-P in Very dark brown soil, Fe-P>Ca-P>Al-P in Dark brown soil and Fe-P Al-P>Ca-P on Red yellow soil. The amounts of phosphorus extracted from soil varied with the methods for available phosphorus estimation. The magnitute of available P measured by Bray No. 2 method was the greatest. In relationship between inorganic phosphorus forms and available phophorus, Bray No. 2 method was closely related to Ca-P only and Olsen method correlated to Al-P, Fe-P, Ca-P and Total-P.

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Characteristics of Inorganic Phosphorus Fractions Accrued from the Application of paper Mill Sludge Compost in Naked Soil(I) (제지슬러지퇴비를 시용한 나지 토양의 무기태인산의 특성변화(I))

  • Lim, Hyun-Taek;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.3
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    • pp.104-111
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    • 2000
  • The study war carried out to evaluate the characteristics of inorganic phosphate factions in soil mixed with paper mill sludge compost(PMSC). The experiments were conducted by an incubation test. For the incubation test, application rates of PMSC to soil were 0, 2, 8, and 16%. Water content of the samples mixed with PMSC were adjusted to 10% and 15% and incubating temperatures of the samples were kept at $4^{\circ}C$ and $30^{\circ}C$, respectively. The results can be concluded as follows; pH increased depending on the higher rates of PMSC application to the soil during the incubation tests, because calcium content was $4.9cmol_c/kg$ and contents of nutrients were high. When the application rates of PMSC were increased Saloid-P and Fe-P decreased, while Al-P and Ca-P in soil increased during the incubation tests.

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An Experimental Study on the Hydration Heat of Concrete Using Phosphate based Inorganic Salt (인산계 무기염을 이용한 콘크리트의 수화 발열 특성에 관한 실험적 연구)

  • Jeong, Seok-Man;Kim, Se-Hwan;Yang, Wan-Hee;Kim, Young-Sun;Ki, Jun-Do;Lee, Gun-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.6
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    • pp.489-495
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    • 2020
  • Whereas the control of the hydration heat in mass concrete has been important as the concrete structures enlarge, many conventional strategies show some limitations in their effectiveness and practicality. Therefore, In this study, as a solution of controling the heat of hydration of mass concrete, a method to reduce the heat of hydration by controlling the hardening of cement was examined. The reduction of the hydration heat by the developed Phosphate Inorganic Salt was basically verified in the insulated boxes filled with binder paste or concrete mixture. That is, the effects of the Phosphate Inorganic Salt on the hydration heat, flow or slump, and compressive strength were analyzed in binary and ternary blended cement which is generally used for low heat. As a result, the internal maximum temperature rise induced by the hydration heat was decreased by 9.5~10.6% and 10.1~11.7% for binder paste and concrete mixed with the Phosphate Inorganic Salt, respectively. Besides, the delay of the time corresponding to the peak temperature was apparently observed, which is beneficial to the emission of the internal hydration heat in real structures. The Phosphate Inorganic Salt that was developed and verified by a series of the aforementioned experiments showed better performance than the existing ones in terms of the control of the hydration heat and other performance. It can be used for the purpose of hydration heat of mass concrete in the future.