• Title/Summary/Keyword: 무기물 특성

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Development of the Quantum Dot/ZnO Nanowire Heterostructure and Their Photoelectrochemical Application

  • Hwang, In-Seong;Seol, Min-Su;Kim, Hui-Jin;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.378-378
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    • 2011
  • ZnO 나노선 구조는 나노선 구조를 통해 입사한 빛을 산란시켜 광흡수를 촉진시키고, 바닥 전극으로 바로 이어진 수직의 1차원 구조를 통해 전자가 빠르게 이동할 수 있으며, 넓은 표면적을 가지고 있는 등의 장점을 가지고 있어 오래전부터 광전소자에 이용되었다. 하지만 ZnO 물질 자체의 밴드갭 에너지가 3.2 eV로 비교적 큰 편이라 가시광 영역의 빛을 흡수, 이용하기 위해서는 작은 밴드갭을 가지는 광감응 물질이 필요하다. 본 연구에서는 저온의 수열합성법을 통해 합성한 ZnO 나노선 구조 상에 Cd 계열의 무기물 양자점을 증착하여 이종구조를 형성하는 방법을 개발하였다. 본 연구에서 사용한 양자점인 CdS와 CdSe는 벌크 밴드갭 에너지가 각각 2.3 eV, 1.7 eV로 가시광 영역의 빛을 흡수할 수 있으며, ZnO 나노선과 type-II 밴드구조를 가지기 때문에 전자-정공 분리 및 포집에 유리하다. 합성된 구조를 이용하여 photoelectrochemical 특성을 분석하였으며, 그 결과 양자점의 증착으로 광전류 생성이 향상됨을 확인하였다. 특히 ZnO 나노선 상에 CdS 양자점 증착 후 추가적으로 CdSe 양자점을 증착하여 다중접합 나노선 구조를 형성한 경우 광전류 생성이 가장 크게 향상된 결과를 확인하였다.

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The Preparation and Properties of Petroleum Sulfonate Dispersant (열분해 잔유를 원료로 한 분산제의 제조 및 특성)

  • Choi, Sang-Won;Kim, Eun-Young;Chang, Woo-Seok;Kim, Viktor;Moon, Jang-Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.490-494
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    • 2007
  • Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

Modelling and Simulation on Non-isothermal Expansion of Water Oversaturated Perlite (퍼라이트 비등온 팽창 모델 및 전산모사)

  • Kim, Ji-Hwan;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.397-401
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    • 2008
  • To verify model adaptation and flexibility, non-isothermal simulation for perlite expansion has been carried out. Temperature-dependent perlite properties are applied to energy equations for bubble temperature change and perlite melt temperature gradient. Bubble temperature is changed with volume change, water evaporation, and heat flux from melt. Temperature gradient of perlite melt is affected by decreasing bubble temperature. As a result, prediction model and code have been developed below 1100 K with 5% accuracy. At 1100~1400 K, lower 7% accuracy has been obtained from the calculation results.

Otical Properties of P3HT-$TiO_2$ Hybrid Photovoltaic Cell (P3HT-$TiO_2$ 복합형 태양전지의 광학적 특성)

  • Her, Hyun-Jung;Baek, Un-Hyuk;Kim, Jae-Wan;Choi, Y.J.;Kang, C.J.;Kim, Yong-Sang
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1243-1244
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    • 2007
  • 전자주개물질 (elelctron donating material)인 poly(3-hexylthiophene) (P3HT)와 전자받개물질 (electron accepting material)인 티타니아 ($TiO_2$)를 이용한 복합형 태양전지에 대해 연구하였다. 유기물 태양전지에 응용되는 전도성 고분자의 여기자 (exiton)의 확산거리가 매우 짧기 때문에 그것을 보완하기 위해 전자주개물질과 받개물질의 표면적을 넓힐 필요가 있다. 비교적 패턴을 형성하기 쉬운 무기물인 티타니아를 이용해 표면적을 증가시켰으며 그렇지 않은 태양전지에 비해 효율이 두 배 증가하는 것을 볼 수 있었다. 티타니아의 표면적을 증가시킨 태양전지의 개방회로전압 ($V_{oc}$), 단락회로전류 ($I_{sc}$), FF (fill factor) 및 효율 (${\eta}$)은 각각 560 mV, 0.657 mA, 48.3 %, 0.18% 이다.

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Physical Properties of Functional Hanji Added Inorganic Marerials (무기물을 첨가한 기능성 한지의 특성)

  • Jo, Hyun-Jin;Yoon, Seung-Lak;Park, Soung-Bae;Kim, Yun-Geun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.1
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    • pp.23-28
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    • 2008
  • Functional hanji was manufactured using the bast fiber of Broussonetia kazinoki and various inorganic compounds such as kaolin, talc, elvan, and ocher, and the physical and optical properties were investigated. The residual percentages of kaolin, talc, elvan and ocher in the functional hanji were above 50%. The density of the hanji increased with the increase of the content of inorganic compounds. The hanji manufactured using ocher showed the highest density. The breaking length and burst factor decreased with the increase of inorganic materials, indicating that physical properties of hanji were not improved by adding inorganic materials. The emission rates of far-infrared radiation increased in the hanji manufactured using inorganic materials. The higher emission rates were observed in the hanji with elvan or ocher. Addition of inorganic compounds to hanji showed the flame retardative effect. The colorfastness to light of the hanji with elvan or ocher was the degree of 4, which explained by the characteristic color of the inorganics.

Electrical and Mechanical Properties of Epoxy/Heterogeneous Inorganic Composites Materials for the Application of Electric Power GIS Appliances (친환경 GIS용 전력기기의 적용을 위한 에폭시 이종무기물 복합재료의 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.12
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    • pp.1633-1640
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    • 2018
  • Epoxy resin is a polar thermosetting polymer that is widely employed in different branches of industry and everyday life, due to their stable physical and chemical properties. Of all the polymer materials currently being used in the electrical insulation industry, epoxy resin is the most widely used kind, chosen as the base polymer material in the present study. Composites were prepared according to the mixing ratio (MS: MA, 1: 9, 3: 7, 5: 5, 7: 3, 9: 1)of mixture for Heterogeneous Minerals(Micro Silica:MS, Micro Alumina:MA) (MS+MA). We have investigated for AC electrical insulation breakdown characteristics and the dielectric properties (permittivity, dielectric loss, and conductivity) with frequency changes. The electrical AC insulation breakdown performance was improved with the increase of the mixing ratio of MS according to heterogeneous mineral material mixture(MS+MA). As Dielectric properties, the dielectric constant and dielectric loss increased with decreasing frequency and decreased with increasing MS content ratio of heterogeneous mineral mixture. Tensile strength and flexural strength according to the mixing ratio (MS + MA) of epoxy / heterogeneous mineral mixture were studied by mechanical properties. The performance of mechanical tensile and flexural strength was significantly improved as the fill contents ratio of MS increased.

Crystallographical Characteristics of Solar Salts Produced from Jeonnam Area by X-Ray Diffraction Technique (X선 회절법에 의한 전남지역 천일염의 결정학적 특성)

  • Jeong, Byung-Jo;Kim, Yong;Kim, Chang-Dae;Hyun, Seung-Cheol;Ham, Gyung-Sik
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.9
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    • pp.1284-1288
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    • 2009
  • Identification of various inorganic compound crystals contained in solar salts, which are produced from 12 areas of Jeonnam, was firstly made by the X-ray diffraction (XRD) technique. The analysis of the XRD spectra was carried out on the basis of Joint Committee on Powder Diffraction Standards (JCPDS) data and the results of Energy Dispersive X-ray Spectrometer (EDX) measurements. In particular, the analysis of the XRD spectra supported that each solar salt contains $Na_2S$ (Shinan Jeungdo and Sinui), $KMgCl_3$ (Shinan Bigeum), $Ca(ClO_3)_2$ (Shinan Docho), $CaAl_4O_7$ (Haenam Songji), $CaSiO_3$ and $CaCl_2$ (Goheung) as inorganic compound crystals, which have not been reported for the solar salts. Also, the XRD results indicated that the solar salts maintain a cubic NaCl crystal structure without any change of lattice parameters etc. However, it was shown in the Field Emission Scanning Electron Microscope (FE-SEM) images that an external form of the solar salts has a lamination layer shape of a cubic structure, which is different from a simple cubic form for the purified salts and the reagent NaCl.

Comparison of Antioxidant Activities and Carotenoid Contents Between Marketable and Unmarketable Sweet Pepper Fruits (파프리카 상품과 및 비상품과의 항산화 활성 및 카로티노이드 함량 비교)

  • Yoon, Seungri;Kim, Jin Hyun;Shin, Minju;Jeong, Ho Jeong
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.393-400
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    • 2022
  • Postharvest quality of sweet pepper fruits was mainly defined as external appearance, i.e., shape, fruit weight and surface color. These quality traits tend to involve esthetic appeal, it disregards gustatory properties and nutritional value. However, comparative studies according to the marketability of sweet pepper fruits are insufficient. This study was carried out to compare the physicochemical components, antioxidant activity and carotenoid contents of marketable and unmarketable sweet pepper fruits (Capsicum annuum L.). Physicochemical components (proximate composition, minerals and total phenolic contents) and antioxidant activities using various methods were investigated. The proximate composition values (%) of marketable and unmarketable fruits were: moisture (90.28 and 90.29), ash (0.74 and 0.26), crude protein (0.67 and 0.72), crude lipid (0.38 and 0.32). There were no significant differences in antioxidant activity, while total phenolic content was higher in marketable fruit. Carotenoids contents were 29.3 ± 2.6 and 31.9 ± 2.9 ㎍·g-1 in marketable and unmarketable fruits respectively, and identified β-carotene, violaxanthin, neoxanthin, and zeaxanthin. Lutein and capsaicin were not detected. In this study, potential value of unmarketable sweet pepper fruit could be identified to be applied as a food ingredient and functional food material.

Technology Trend in Ionic Liquids (이온성 액체의 기술 동향)

  • Lee, Hyunjoo;Lee, Je Seung;Ahn, Byoung Sung;Kim, Hoon Sik
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.595-602
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    • 2005
  • Ionic liquids (ILs) are the ionic salts pertaining to liquid-state at lower temperature than $100^{\circ}C$. ILs have attracted attention as new media because of their peculiar chemical, physical or electrical properties such as low volatility, nonflammability, liquid-phase stability at high temperature, high ability in solvating organic, inorganic or polymeric materials, and high ionic conductivity. Since the properties can be modified by assembling the pair using various anions and cations, ILs are often called designer solvents. In addition, ILs have been expected as new green media to replace the volatile organic solvents, which have been widely used in chemical, energy, material, and electronic industries, as well as to enhance the reaction activity and selectivity. In this review paper, the structures, properties, applications, and technology trend of ILS are introduced.

Solidify Properties of Radioactive Waste using Paraffin Wax (파라핀 왁스를 이용한 방사성 폐기물의 고화 특성)

  • Lee, Han Chul;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.391-396
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    • 2006
  • When radioactive wastewater was solidified treatment by cement, the drying rate of cement and the volume reduction ratio was decreased because of boric acid component in the wastewater. In order to supplement the demerit, effects of paraffin wax investigated in this study. Paraffin wax has a hydrophobic properties and a low affinity with inorganic materials. When the radioactive wastewater was tested by a small of wax, the compressive strength of solidified waste are decreased Therefore boric acid in radioactive wastewater are first treated by alkali salt and coated by the stearic acid. During the solidification step, The amount of paraffin wax addition get the result that the compressive strength of solidification with cement was the same as that with paraffin wax. The leaching properties of radioactive waste solidified was the same CFL (cumulative fraction leached), PR (penetration rate), effective diffusivity if paraffin wax content in solidified waste was 20% or 25%.