• Title/Summary/Keyword: 무게감량

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석탄회 세슘포집재의 고온안정성 분석

  • 박장진;전관식;신진명;조영현;박현수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.596-602
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    • 1996
  • 석탄화력발전소 폐기물인 석탄회로 포집한 세슘의 고온안정성 분석을 위하여 Cs/Al의 몰비를 0.1에서 1.5까지 변화시켜 제조한 시료를 TGA, XRD, SEM등으로 분석하였다. 몰비가 0.75이상에서부터 pollucite 상 이외에 CsAlSiO$_4$상이 나타나기 시작하였으며 몰비가 증가할수록 CsAlSiO$_4$상이 증가하였다. 몰비가 0.5까지 세슘의 휘발로 인한 무게감량은 없었고 0.75부터는 몰비가 증가할수록 무게감량이 증가하였다. 이는 몰비가 증가할수록 세슘 증기압이 큰 CsAlSiO$_4$상이 증가하기 때문인 것으로 사료된다.

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환원분위기하에서의 석탄회 세슘포집재의 고온 안정성 분석

  • 박장진;전관식;신진명;김종호;이종규
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.329-334
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    • 1997
  • 석탄화력발전소 폐기물인 석탄회로 포집한 세슘의 환원분위기(He+4% H$_2$)하에서 고온안정성 분석을 위하여 몰비를 0.1에서 1.5까지 변화시켜 제조한 시료를 머플로에서 열처리 및 XRD로 분석하였다 Cs/Al의 몰비가 증가할 수록 세슘 포집량이 증가하였다. 세슘 포집량 0.48(g-Cs$_2$O/g-fly ash) 이상에서 부터 pollucite 상 이외에 CsAlSiO$_4$상이 나타나기 시작하였고 세슘 포집량이 증가할 수록 CsAlSiO$_4$ 상이 증가하였다. 세슘 포집량 0.15(g-Cs$_2$O/g-fly ash) 까지 세슘의 휘발로 인한 무게감량은 없었고, 포집량 0.32(g-Cs$_2$O/g-fly ash)부터는 포집량이 증가할 수록 무게감량이 증가하였다. 이는 세슘 포집량이 증가할 수록 세슘 증기압이 큰 CsAlSiO$_4$상이 증가하기 때문인 것으로 사료된다.

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Effect of In Vitro Degradation on the Weight Loss and Tensile Strength of PLA/PEG Melt Blend Fiber (In Vitro 분해가 PLA/PEG 용융블렌드 섬유의 무게감량률 및 인장강도에 미치는 영향)

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.581-587
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    • 2009
  • PLA/PEG blend fibers composed of poly (lactic acid) (PLA) and poly (ethylene glycol) (PEG) were prepared via melt blending and spinning for bioabsorbable filament sutures. The blend fibers hydrolyzed with the immersion in a phosphate buffer solution at pH 7.4 and $37\;^{\circ}C$ for 1~8 weeks. The effects of blending time, blend composition, and hydrolysis time on the weight loss and tensile strength of the hydrolyzed blend fibers were investigated. After hydrolysis, the weight loss of the blend fibers increased with increasing PEG content, blending time, and hydrolysis time. The tensile strength and tensile modulus of the blend fibers decreased with increasing PEG content, blending time, and hydrolysis time. Therefore, it can be concluded that the weight loss of the PLA/PEG blend fibers was less than 0.9% even at hydrolysis time of 2 weeks and their strength retentions were over 90%.

Variation of Adenosine tri-Phosphate(ATP) in Fermentation-Extinction of Food Wastes with Wood Bio-Chip (목질바이오칩에 의한 음식물쓰레기 발효-소멸반응에서의 아데노신3인산의 변화)

  • Oh, Jeong-Ik
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.4
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    • pp.363-368
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    • 2010
  • The overall indicator of microbial activity in the fermentation-extinction reaction of food waste by using bio wood-chips were investigated by considering adenosine tri-phosphate(ATP). Degradation rate of organic compounds, which was represented by chemical oxygen demand(COD) and total nitrogen(TN), was increased with the concentration of adenosine tri-phosphate during fermentation-extinction reaction of food waste by using bio-wood chips. With this view, the ATP would be one of the overall evaluation indicator of organic degradation in the species of bio-wood chip for the fermentation-extinction of food waste.

High Temperature Thermal Behavior of EAF Dust by Coke at Initial Reaction Stage (초기 반응단계에서 코크스에 의한 EAF DUST의 고온열적 거동)

  • 정봉진;배상민;문석민;신형기
    • Resources Recycling
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    • v.7 no.5
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    • pp.19-25
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    • 1998
  • High temperature thermal behaviors of EAF dust by coke at initial reaction stage were studied to obtain the fundamental data of EAF dust treatment process, that is Extended Arc Plasma Furnace System called RAPID system. In this study thermal behaviors including calcination of limestone, devolatilization of EAF dust itself, and reduction & devolatilization of mixture(EAF dust : coke : limestone = 80 : 10 : 10 wt.%) were investigated as functions of reaction temperature (1000~1300$^{\circ}C$) and reaction time (3~12 min), considering the 180% equivalence of carbon reduction and 1.7 bacisity for optimum reduction and melting of EAF dust in the RAPID system. Size of sample was about below 0.1 mm for these experiments. Limestone was completely calcined at above 1100$^{\circ}C$ within 1 minutes. In the case of devolatilization of EAF dust itself, weight loss of EAF dust was about 14% at 1300$^{\circ}C$ and 12 minutes, and partial sintering and melting were found in part of sample. Weight loss of mixtures increased with increasing reaction temperature and time, about 46% weight loss in it was occurred at 1300$^{\circ}C$ and 12 minutes. From these weight losses showing devolatilization and reduction of EAF dust, the treatment time of EAF dust inside.

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Packaging Design Guideline for PET Bottle using Lightness Index (경량화 지수를 이용한 페트병의 패키징 설계 기준)

  • Kim, Sun-jong;Nastaran, Moghimi;Jang, Si-hoon;Park, Su-il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.163-168
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    • 2016
  • In this study, we analyzed the empty body weight and nominal volume of different types of polyethylene terephthalate (PET) bottles commercialized in Korean market. Over 780 PET bottles were collected and classified into four types, heat resistance bottle, normal resistance bottle, pressure resistance bottle, and long period using bottle. Each PET bottle's lightness index was established using bottle weight and nominal volume. Based on the index value, "acceptable" and "optimum" criteria for design guideline of PET bottle were summarized for each PET bottle type. In this paper, we suggest the use of PET bottle lightness index as a design guideline for material resource reduction of PET bottle for Korean beverage industries and bottle makers. For example, we can achieve 2~4 g weight reduction in normal pressure bottle for 500 mL drinking water.

Study of Biodegradable Ability of Biodegradable Plastic in Anaerobic Digestion (혐기성소화에 의한 생분해성 플라스틱의 생분해능 검토)

  • Park, Jeong-Soo;Joo, Hung-Soo;Ryu, Jae-Young;Phae, Chae-Gun;Jeon, Young-Seung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.1
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    • pp.109-119
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    • 2002
  • This study is to estimate that food waste bags with biodegradable plastic are really decomposed by microorganism in composting with food waste and to examinate how biodegradable plastic affects composting. 6 kinds of 30%, 4 kinds of 100% and 2 kinds of none biodegradable plastics were used in d1is study. In 30% biodegradable plastics the highest Degradation rare is 6% in meso-condition and 10% in thermal-condition. Srain at auto break decreased to 150% in meso-condition and 120% in thermal-condition. Stress at max load were also reduced to $180kgf/cm^2$ in mesocondition and $200kgf/cm^2$ in thermal-condition. Usually, LLDPE decreased larger than HDPE in physical characreristics but HDPE is higher in degradation rate. 1n stain at auto break and stress ar max load 100% biodegradable plastic declined to 230% and to $380kgf/cm^2$ in meso-condition and to 440% and to $400/cm^2$ in thermal-condition respectively. 100% biodegradable plastics showed higher biodegradation and decomposition then 30%. They appeared clearly through SEM observation. As a result, it was not appropriate to use 30% biodegradable plastics as food waste bag because they were not decomposed perfectly. It is possible to use 100% biodegradable plastic as it but cost is too high. So development of technique is needed.

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Evaluation of Safety Characteristic in Chemical Decontamination at Extremely Severe Condition of Stainless Steels for Coolant Pump (가장 가혹한 조건에서 화학 제염한 경우 냉각재 펌프용 스테인리스강의 안정성 평가)

  • Kim, Seong-Jong;Jang, Seok-Ki;Kim, Ki-Joon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.4 s.27
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    • pp.253-259
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    • 2006
  • This paper investigated on anti-corrosion characteristic in chemical decontamination at extremely severe condition{process model-2) of stainless steels used with reactor coolant pump. The electrochemical properties of stainless steel{STS) 304 with the lapse qf cycle is better than those of STS 415 and STS 431. The STS 304 in process model-1 and process model-2 present the lowest weightloss ratio. The experiment results for STS 304, STS 415, and STS 431 in process model-2 solution, it was ascertained that weightloss ratio of process model-2 solution for process model-1 solution show 2..908, 2.572, and 2.370 times, respectively. The reason suggests that process model-2 is higher concentration of chemical and temperature compare to process model-1.

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Study on the Thermal Characteristic Comparison of Fire.Explosion Hazard of Fugitive Dust Generated in the Manufacturing Process (제조공정상 발생하는 비산분진의 화재·폭발 위험성에 대한 열적특성 비교에 관한 연구)

  • Sun, Ko Jae
    • Journal of the Society of Disaster Information
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    • v.10 no.1
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    • pp.71-83
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    • 2014
  • This study carried out an experiment in order to compare thermal characteristics after collecting dust generated in the process of disposing of waste tire, plywood flour in the process of manufacturing plywood, salicylic acid dust in the process of manufacturing functional soap, and dust in the process of manufacturing wheat powder, which has potential fire and explosion hazard. According to the results of experiment, the analysis showed that all samples subject to the experiment were in the condition where heat flux decreased and temperature decreased as the quantity of added talc was increased. This shows that decomposition rate decreased, and hazard decreased. However, in all of samples subject to the experiment, as heating rate increased, endothermic onset temperature moved to the low-temperature part, and the amount of absorbed heat was largely increased. This showed that the decomposition hazard of sample increased as heating rate increased, according to the analysis. Besides, TGA experiment results showed that thermal stability was secured because total weight loss decreased as the amount of talc was increased for all samples subject to the experiment regarding the ratio of weight loss. It is expected that the continuous research and supplementation of dust explosion mechanism in the future will contribute to the establishment of measures for the effective dust explosion prevention.

A Study on the Comparison of Explosive Lower Limit Concentration & Thermal Specific of Wheat Powder Dust & Salicylic Acid Dust (밀가루분진 및 살리실산분진의 폭발하한농도 및 열적특성 비교에 관한 연구)

  • Ko, Jae-Sun
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.1-9
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    • 2012
  • We have examined In order to compare each other from explosion and combustion characteristics about the dusts which collects from manufacturing process of wheat flour and cosmetics manufacturing process of functional Keratin removal soap at the small and medium enterprise style. We measured explosive pressure and explosive lower limit which follows in change of concentration change at the time of talc addition uses Hartman dust explosion apparatus, also measured weight loss and endothermic quantity uses DSC and TGA. The explosion test results show that increased explosive lower limit concentration and explosive pressure decreased by the increased ratio of the talc dust. And the DSC results show that heat flux and temperature decreased by the increased ratio of the talc dust. Also increased in raising temperature causes initial smoldering temperature to move towards low temperature section and the endothermic quantity increased on a large scale. Together the TGA results show that weight loss decreased by the increased ratio of the talc dust. From this research we have assured the successive dust explosion mechanism study will play a key role as a significant safety securing guideline against the dust explosion.