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Fundamental Study on Developing Lignocellulosic Fillers for Papermaking(II) - Effect of lignocellulosic fillers on paper properties - (목질계 제지용 충전제 개발을 위한 기초연구(II) - 목질계 충전제가 종이 물성에 미치는 영향 연구 -)

  • Kim, Chul-Hwan;Lee, Ji-Young;Lee, Young-Rok;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Gwak, Hye-Joeng;Gang, Ha-Ryun;Kim, Sung-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.1-6
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    • 2009
  • The purpose of this study was to investigate effects of lignocellulosic fillers made of wood powder and inorganic fillers, such as GCC and PCC, on physical properties of papers. Mechanical treatment and chemical treatment were carried out subsequently for generating lignocellulosic fillers, and then inorganic filler and wood powder were mixed together, and then mechanically treated for making lignocellulosic fillers covered with inorganic fillers. Consequently the particle size of lignocellulosic fillers was higher than that of inorganic fillers, which led to lumen loading and simultaneously surface coverage of fine inorganic fillers. Lignocellulosic fillers contributed to the increase of both bulk and opacity of handsheets dramatically, but some of properties including tensile strength, brightness and roughness decreased compared to inorganic fillers.

Properties of Wood-Based Board Prepared with Bed-Logs Decayed by Oak Mushroom(Lentinus edodes) (표고 폐골목으로 제조한 목질보드의 성질)

  • Choi, Yong-Soon;Hwang, Won-Jung;Han, Tae-Hyung;Kim, Nam-Hun;Kwon, Jin-Heon
    • Journal of Forest and Environmental Science
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    • v.14 no.1
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    • pp.138-144
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    • 1998
  • To provide further information for reutilization of the bed-logs decayed by oak mushroom(Lentinus edodes), the properties of wood-based board prepared with mixed materials of normal wood and bed-logs were examined. Wood fibers in bed-logs showed different morphology from normal wood fibers, that is, shorter length and rough surface. Thickness swelling increased with increasing mixing ratio of bed-log. On the other hand, modulus of rupture(MOR) in bending strength decreased. In products, the visual surface of board prepared from higher mixing rate of bed-log chips was smooth. Consquently, it is considered that the optimum mixing rate of bed-log to normal wood is the range of 25-50% and the bed-log can be used for raw material of board instead of normal wood.

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Characteristics of Microbial Decomposition of Bast Fibers by Wood Rot Fungi (목질분해균에 의한 인피섬유의 미생물분해 특성)

  • 윤승락;최인규;이재원;김재경
    • Journal of Korea Foresty Energy
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    • v.20 no.1
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    • pp.6-11
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    • 2001
  • In order to use bast fibers of mulberry tree at a pulp source of Hanji, the bast fibers were microbiologically treated with several wood rot fungi, and the microscopic characteristics of bast fibers depending on treatment days were evaluated. By wood rot fungi, Phanerochaete chrysosporium and Trametes versicolor, the weight reduction ratio was approximately 50 percent within incubation for 20 days. occurring together with decomposition of useful fibers. However, Hwterobasidion insularis and Stereum hirsutum have completely decomposed the utmost layer of black blue colored bast fibers, and not caused the damage if fibers. Until incubation for 10 days, the cellulose content of vast fibers by Stereum hirsutum was 78.9 percent with lignin content of 7.2 percent, showing an appropriate decomposition for useful fibers. By microscopic observation, the bundled fibers were separated to single fiber within treatement days 30 by Pleurotus ostreatus, and there were no damage on the surface of fiber by treatment days 50.

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Development of Vibraction and Impact Noise Dampling Wood-based Composites(I) -Dynamic Mechanical and Vibration Damping Properties of Plasticized PVC- (진동.충격음 흡수성능을 지니는 목질계 복합재료의 개발(I) -가소화 폴리염화비닐의 동적점탄성과 진동흡수성능-)

  • 이현종
    • Journal of Korea Foresty Energy
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    • v.17 no.1
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    • pp.36-46
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    • 1998
  • The aim of this study was to develop the noise and vibration damping wood-based composites by using viscoelastic polymer materials. Polyvinylchloride(PVC) was plasticized with 20-140 phr bis(2-ethylhexyl) phthalate(DOP) and the dynamic tensile mechanical properties were measured at 110Hz and approximate temperature range -100 to 150$^{\circ}$ using a Rheovibron Instrument. The PVC/DOP blends were shown to be compatible in all proportions, and both T(E”$_{max}$) and T(tan${\delta}_{max}$) shifted to the lower temperature side as the DOP content increased. The vibration damping properties of wood/polymer composites were measured using the Rheovibron instrument in a bending mode. The composite damping factor(tan ${\delta}_{c}$) of wood /PVC-DOP/wood sandwich structure correlated with the loss factor and that of the coated structure correlated with the loss modulus(E”) of the polymer layer. In addition, the sandwich structure was found to be more effective in damping than the coated structure. The logarithmic decrement (${\Delta}$c) curve of a sandwich structure, which was determined by the free-free flexural vibration method was similar in shape to the tan ${\delta}_{c}$ curve.

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Effect of Various Culture Conditions on the Activity of Extracellular Enzymes from Fomitopsis palustris, Brown Rot Fungi (침엽수 혼합목분에서 배양조건을 달리한 Fomitopsis palustris 의 균체외효소 활성 변화)

  • Lee, Young-Min;Choi, Doo-Yul;Kim, Hyun-Jung;Yoon, Jeoung-Jun;Kim, Yeong-Suk
    • Journal of Forest and Environmental Science
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    • v.24 no.1
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    • pp.53-59
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    • 2008
  • Extracellular enzyme activities of Fomitopsis palustris were determined by the particle sizes, culture periods and concentrations of wood particle substrate which was mixture of 4 domestic coniferous woods, such as Pinus densiflora, Larix leptolepsis, Pinus koraiensis, and Pinus rigida. The results showed that the culture conditions had an effect on the secretion of most of the extracellular enzymes from Fomitopsis palustris in the mixed wood particle substrate. :The optimal culture conditions for enzyme activities were 80~100 mesh in wood particle size, 7.5% in concentrations of wood substrate, and 4~8 weeks in culture period.

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Morphological and cultural characteristics of a novel Phellinus linteus KACC93057P (신규 목질진흙버섯 KACC93057P의 배양적, 형태적 특성)

  • Min, Gyeong-Jin;Kwak, A-Min;Seok, Sun-Ja;Kang, Hee-Wan
    • Journal of Mushroom
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    • v.14 no.3
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    • pp.75-80
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    • 2016
  • Morphological and culture characteristics of the novel Phellinus linteus variant KACC93057P collected in Korea were characterized in this study. The surface of the was angular, sessile, tough-woody, concentrically zonate, and dark brown in color. Basidiocarppores were circular, with 5-7 pores per mm. The hyphal system was dimitic, and basidiospores were ellipsoid or oval, $4.5-6{\times}4-5$, exhibiting characteristics typical of P. linteus. The optimum temperature for mycelial growth was $25-30^{\circ}C$, and optimal pH for growth was 5-7. The mycelial growth rate of P. linteus KACC93057P was faster than that of other P. baumii isolates. On growth medium, KACC93057P formed aerial mycelia with density higher than that of other isolates. The internal transcribed spacer (ITS)-ribosomal DNA sequences were closely related to the sequences P. linteus complex.

Modeling of Torrefaction process for agro-byproduct I : Rate constant & mass reduction model (농업부산물 반탄화 공정 예측 모델 I : 반응속도 상수 도출 및 질량감소 모델 정립)

  • Park, Sun Young;Lee, Sang Yeol;Joo, Sang Yeon;Cho, La Hoon;Oh, Kwang Cheol;Lee, Seo Hyeon;Jeong, In Seon;Lee, Chung Geon;Kim, Dae Hyun
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.32-32
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    • 2017
  • 2012년부터 도입된 "신재생에너지 의무할당제(RPS)"로 인하여 500MW이상의 설비 용량을 갖춘 발전소의 경우 총발전량에서 일정 비율을 신재생에너지로 공급하여야 한다. 이러한 신재생에너지 중 농업부산물은 목질계 바이오매스의 한 종류로 '탄소중립(Carbon Neutral)' 연료이며 기존 화석연료와 혼소로 활용 할 수 있는 장점을 지니고 있다. 그러나 낮은 발열량, 운송 및 저장비용, 일정하지 않은 연소특성의 문제로 인하여 대부분 노지에 방치되거나 버려지고 있다. 이러한 버려지는 농업부산물을 효율적으로 활용하기 위한 방법 중 하나로 반탄화(Torrefacation) 처리가 대두되고 있다. 반탄화 처리 시, 발열량이 증대되며, 저장과 이송에서의 이점을 갖게 된다. 그러나, 반탄화는 공정 과정중 질량손실에 따른 에너지 총량의 감소한다는 단점을 가지고 있다. 이에 본 연구에서는 효율적인 반탄화공정을 위한 질량감소모델을 제시 하고자한다. 승온 속도(heating rate)를 $7.5^{\circ}C/min$, $15^{\circ}C/min$, $22.5^{\circ}C/min$의 조건에서의 열중량분석 결과를 토대로 속도모델식(Arrhenius method, Ingraham & Marrier method 등)을 적용하여, 반응속도상수를 도출하였다. 이 반응속도상수를 이용하여 질량감소 모델을 정립하였고, 이를 실험결과와 비교, 검증하였다.

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Antioxidant Activity of Isolated Compounds from the Heartwoods of Rhus verniciflua (옻나무(Rhus verniciflua) 목질부에서 분리한 화합물의 항산화활성)

  • Ahn, Eun-Mi;Park, Sang-Jae;Choi, Won-Cheol;Choi, Suk-Hoon;Baek, Nam-In
    • Applied Biological Chemistry
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    • v.50 no.4
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    • pp.358-361
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    • 2007
  • The heartwoods of Rhus verniciflua was extracted with $H_2O$ and the concentrated extract was partitioned with $CHCl_3$, EtOAc, n-BuOH and $H_2O$, successively. From the EtOAc and n-BuOH fractions, four compounds were isolated through the repeated silica gel, ODS and Sephadex LH-20 column chromatographies. They were determined as sinapyl aldehyde (1), 2,4-dihydroxybenzaldehyde (2), 2,4-dihydroxybenzoic acid (3) and 2,4-dihydroxyphenylglyoxylic acid (4) on the basis of spectroscopic data, respectively. Among the isolated compounds, sinapyl aldehyde $(34.7{\pm}0.6%)$ and 2,4-dihydroxyphenylglyoxylic acid $(43.8{\pm}0.9%)$ showed the strong antioxidative activity than artificial antioxidant BHT $(14.4{\pm}0.3%)$ in DPPH radical scavenging activity.

Synthesis Gas Production from Gasification of Woody Biomass (목질계 바이오매스로부터 가스화에 의한 합성가스 제조 연구)

  • Cho, Won-Jun;Mo, Yong-Gi;Song, Taek-Yong;Baek, Young-Soon;Kim, Seung-Soo
    • Journal of Hydrogen and New Energy
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    • v.21 no.6
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    • pp.587-594
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    • 2010
  • Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas has played an important role of synthesizing the valuable chemical compounds, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuel and chemicals. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C$/min in thermogravimetric analysis. Bubbling fluidized bed reactor was used to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, $CO_2$, $H_2$ and a small fraction of $C_1-C_4$ hydrocarbons.

Environment-Friendly Bonding of Decorative Veneer by SIS-Based Hotmelt Pressure-Sensitive Adhesives (환경친화성 SIS계 핫멜트 점착제를 이용한 무늬목 접착)

  • Lim, Dong-Hyuk;Kim, Sumin;Park, Young-Jun;Kim, Hyun-Joong;Yang, Han-Seung
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.22-29
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    • 2006
  • The overlaid panels are important materials in interior and construction with added surface layers (PVC films, decorative paper, decorative veneer). Generally, the adhesive for decorative veneer to wood-based panel is urea-formaldehyde (UF) adhesive which cause the emission of formaldehyde during not only the manufacturing process, but also service life. In this study, environment-friendly SIS-based hotmelt pressure-sensitive adhesive (PSA) was evaluated as a adhesive for bonding a decorative veneer. The various SIS-based hotmelt PSA was blended as a function of diblock content, softening point of tackifier, tackifier content, and applied to bonding the decorative veneer.