• Title/Summary/Keyword: 모노시란

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Lipase-Catalyzed Reactions for Fats and Oils in Non-Polar Solvent (유기용매 내에서의 유지의 리파제 촉매반응)

  • Daeseok Han;Kwon, Dae-Young;Rhee, Joon-Shick
    • Microbiology and Biotechnology Letters
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    • v.16 no.3
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    • pp.250-258
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    • 1988
  • Lipases are well known as the enzymes which catalyze the hydrolysis of ester bonds combining aliphatic chains and glycerol on mono-, di- and triglycerides. Their reactions are characterized by be-ing heterogeneous and catalyzing the water-insoluble substrates. This property has been one of the Hurdles which delayed the application of lipases in fats and oils industry, However, with the development of biological reaction system of which organic solvent is introduced in part or whole as the reaction media, enzymatic manipulation of fats and oils is attracting increasing attention from the academic and industrial sectors. Trials in two-phase system and reversed micellar system to produce fatty acids through enzymatic hydrolysis of triglycerides preyed to be efficient in respect to volumetric productivity, fat hydrolysis rate, product separation, etc. In organic solvent system lipases have been found to have the ability to catalyze aminolysis, transesterification, esterification, thiotransesterification and oximolysis that are virtually impossible to catalyze in water. The organic solvent system is being extensively used in interesterifying glycerides to produce a fat with the modified physical and chemical nature.

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Study on Conversion of Carbon Dioxide to Methyl Alcohol over Ceramic Monolith Supported CuO and ZnO Catalysts (세라믹 모노리스에 담지된 CuO와 ZnO계 촉매에 의한 이산화탄소의 메탄올로의 전환에 관한 연구)

  • Park, Chul-Min;Ahn, Won-Ju;Jo, Woong-Kyu;Song, Jin-Hun;Kim, Ki-Joong;Jeong, Woon-Jo;Sohn, Bo-Kyun;Ahn, Byeong Kwon;Chung, Min-Chul;Park, Kwon-Pil;Ahn, Ho-Geun
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.1
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    • pp.97-104
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    • 2013
  • Methyl alcohol is one of the basic intermediates in the chemical industry and is also being used as a fuel additive and as a clean burning fuel. In this study, conversion of carbon dioxide to methyl alcohol was investigated using catalytic chemical methods. Ceramic monoliths (M) with $400cell/in^2$ were used as catalyst supports. Monolith-supported CuO-ZnO catalysts were prepared by wash-coat method. The prepared catalysts were characterized by using ICP analysis, TEM images and XRD patterns. The catalytic activity for carbon dioxide hydrogenation to methyl alcohol was investigated using a flow-type reactor under various reaction temperature, pressure and contact time. In the preparation of monolith-supported CuO-ZnO catalysts by wash-coat method, proper concentration of precursors solution was 25.7% (w/v). The mixed crystal of CuO and ZnO was well supported on monolith. And it was known that more CuO component may be supported than ZnO component. Conversion of carbon dioxide was increased with increasing reaction temperature, but methyl alcohol selectivity was decreased. Optimum reaction temperature was about $250^{\circ}C$ under 20 atm because of the reverse water gas shift reaction. Maximum yield of methyl alcohol over CuO-ZnO/M catalyst was 5.1 mol% at $250^{\circ}C$ and 20 atm.

Inhibitory Effects of an Eicosanoid Biosynthesis Inhibitor, Benzylideneacetone, Against Two Spotted Spider Mite, Tetranychus urticae, and a Bacterial Wilt-causing Pathogen, Ralstonia solanacearum (아이코사노이드 생합성 저해제인 벤질리덴아세톤의 점박이응애(Tetranychus urticae)와 세균성풋마름병 세균(Ralstonia solanacearum)에 대한 억제효과)

  • Park, Ye-Sol;Kim, Min-Je;Lee, Geon-Hyung;Chun, Won-Soo;Yi, Young-Keun;Kim, Yong-Gyun
    • The Korean Journal of Pesticide Science
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    • v.13 no.3
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    • pp.185-189
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    • 2009
  • A monoterpenoid compound, benzylideneacetone (BZA), is a metabolite of an entomopathogenic bacterium, Xenorhabdus nematophila. Its primary biological activity is an inhibitor of phospholipase $A_2$, which catalyzes the committed step of biosynthesis of various eicosanoids that are critically important to mediate insect immune responses. When BZA was applied to two-spotted spider mite, Tetranychus urticae, it exhibited a dose-dependent mortality in leaf-disc assay. Subsequently BZA was tested against T. urticae infesting apples in a field orchard, in which it showed a significant control efficacy, which was not statistically different with that of a commercial acaricide. BZA also had significant antibacterial activities against three species of plant pathogenic bacteria when it was added to the bacterial cultures, in which it showed the highest inhibitory activity against a bacterial wilt-causing pathogen, Ralstonia solanacearum. The bacterial pathogen caused significant disease symptom to young potato plants. However, BZA significantly suppressed the disease occurrence. This study suggests that BZA can be used to develop a novel crop protectant to control mite and bacterial pathogen.

Development of a Mountainous Area Monitoring System based on IoT Technology (IoT 기술 기반의 산악지 모니터링 시스템 개발)

  • Kim, Kyoon-Tai
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.437-446
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    • 2017
  • 70 percent of Korea's territory is covered with mountains, whose difficult conditions can cause damage to facilities. Recently, the demand for facilities related to outdoor activities including monorails has been on the rise, and such facilities are much more likely to become damaged. For this reason, a monitoring system applying IoT to mountainous areas was developed and its applicability is evaluated in this study. The current status of the existing mountainous facilities and monitoring systems were reviewed, and the current wired monitoring technology was analyzed. A scenario for IoT-based monitoring was developed, and then sensor nodes were developed, which include an RF-communication module and interface, power-supply and solar-cell. A testbed was set up at K University. The same data was collected by the wireless system as had been collected by the wired one. The study findings are as follows. Firstly, by using the wireless system, it is estimated that the construction duration can be reduced by about 25 percent, while the construction costs can be reduced by about 3~52 percent. Secondly, the safety of the construction workers can be improved by making the working conditions less dangerous, such as by eliminating the need to transport cables.

Evaluating Shear Wave Velocity of Rock Specimen Through Compressional Wave Velocities Obtained from FFRC and Ultrasonic Velocity Methods (양단자유공진주 및 초음파속도법으로 획득한 압축파 속도를 이용한 암석시편의 전단파 속도 도출)

  • Bang, Eun Seok;Park, Sam Gyu;Kim, Dong Soo
    • Geophysics and Geophysical Exploration
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    • v.16 no.4
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    • pp.250-256
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    • 2013
  • Using shear wave velocity is more reasonable to estimate strength and integrity of rock compared with using compressional wave. It is often ambiguous to pick the dominant frequency caused by torsional wave when evaluating $V_S$ of rock specimen from FFRC method. It is also sometimes ambiguous to pick the first arrival point of S wave compared with P wave in the signals acquired from ultrasonic velocity method. Otherwise, the procedure of evaluating $V_P$ using ultrasonic velocity method and $V_L$ using FFRC method is relatively stable. Through the relationship between elastic modulus, poisson's ratio and $V_S$ can be obtained from $V_P$, $V_L$. Applicability was checked using model specimens having different material property and length and rock specimens sampled in mine area, and usefulness of proposed procedure was verified.

Arsenic removal from artificial arsenic water using CaAl-monosulfate and CaAl-ettringite (CaAl-monosulfate와 CaAl-ettringite를 이용한 인공비소폐수의 비소 제거 연구)

  • Shim, Jae-Ho;Kim, Ki-Baek;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.141-148
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    • 2012
  • The objective of this study is to remove arsenate from artificially contaminated wastewater using CaAl-ettringite and CaAl-monosulfate which were synthesized in laboratory. The study was carried on the basis of solidification/stabilization of waste using cement. Monosulfate and ettringite are constituents of cement paste. The CaAl-ettringite has a chemical formula of $Ca_6Al_2O_6(SO_4)_3{\cdot}32H_2O$ and has a needle like morphology. Whereas CaAl-monosulfate $Ca_4Al_2O_6(SO_4){\cdot}12H_2O$ has layered double hydroxide structure (LDH) in which the mainlayer consists of Ca and Al and S as interlayer. Ettringite and monosulfate were synthesized by reaction of tricalcium aluminate and gypsum and hydrating this mixture at elevated temperature. The synthesized mineral were characterized by PXRD and FESEM to ensure purity. It was found that concentrations of As(V) in contaminated water were reduced from initial concentration of 1.335 mmol/L to 0.054 mmol/L and 0.300 mmol/L by CaAl-monosulfate and CaAl-ettringite respectively. The post experimental results of PXRD and FESEM analysis indicate that arsenate removal was by ion exchange.

Design of 2.4/5.8GHz Dual-Frequency CPW-Fed Planar Type Monopole Active Antennas (2.4/5.8GHz 이중 대역 코프래너 급전 평면형 모노폴 능동 안테나 설계)

  • Kim, Joon-Il;Chang, Jin-Woo;Lee, Won-Taek;Jee, Yong
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.44 no.8
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    • pp.42-50
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    • 2007
  • This paper presents design methods for dual-frequency(2.4/5.8GHz) active receiving antennas. The proposed active receiving antennas are designed to interconnect the output port of a wideband antenna to the input port of an active device of High Electron Mobility Transistor directly and to receive RF signals of 2.4GHz and 5.2GHz simultaneously where the impedance matching conditions are optimized by adjusting the length of $1/20{\lambda}_0$(@5.8GHz) CPW transmission line in the planar antenna The bandwidth of implemented dual-frequency active receiving antennas is measured in the range of 2.0GHz to 3.1GHz and 5.25GHz to 5.9GHz. Gains are measured of 17.0dB at 2.4GHz and 15.0dB at 5.2GHz. The measured noise figure is 1.5dB at operating frequencies.

The Characteristics of Monoterpene and Air Quality in Ambient Air at Forested Road in Jeollanam-do (전남지역 숲길의 모노테르펜류 농도와 공기질 특성)

  • Oh, Gil-Young;Seo, Yun-Gyu;Park, Gui-Hwan;Kim, Ik-San;Bae, Ju-Soon;Park, Hye-Young;Yang, Soo-In;Jeon, Jun-Min;Jeong, Man-Ho;Seo, Yun-Seob;Lee, Wan-Jin
    • Journal of Korean Society of Forest Science
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    • v.101 no.2
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    • pp.195-202
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    • 2012
  • Three-season field study was conducted to investigate the distribution of monoterpene(10) and air anion in ambient air at five forests. ${\alpha}$-Pinene, camphene, sabinene, ${\beta}$-pinene, myrcene, terpinolene, limonene, 1,8-cineol, linalool, and camphor were quantified in the samples collected. The highest 4-hour mean concentration of total monoterpene were ${\beta}$-pinene+myrcene as 958 pptv at Juknokwon dominated by bamboo and ${\alpha}$-pinene (524 pptv), limonene (445 pptv) at Wood Land and Suncheon Bay, respectively. The seasonal means were observed to peak during spring with their maximum at Wood Land and Seonam Temple and during summer at Juknokwon and Suncheon Bay. The 24 hour concentration mean of atmosphere standards were found with much lower values than those by law. The highest concentrations of air anion were measured $400{\sim}3,000ea{\cdot}mL^{-1}$ through the sites. There is no significant correlation between the concentration of monoterpene and air anion.

A Study on the Advance Transportation System for Inter Terminal Transshipment: Focused on the Busan New Port (타부두 환적화물에 적합한 운송수단에 관한 연구;부산항 신항을 중심으로)

  • Jo, Mi-Ji;Lee, Seung-Pil;Kim, Hwan-Seong
    • Journal of Navigation and Port Research
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    • v.44 no.4
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    • pp.298-304
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    • 2020
  • The purpose of this study was to identify evaluation factors and analyze the relative importance among factors to select a suitable transportation method for transferring the increasing amount of transshipment at multiple terminals at the Busan new port. To accomplish this, the evaluation factors were selected through a literature survey and brainstorming of a group of experts associated with the port operation, and were classified into five major factors and 15 middle factors. The evaluation factors classified hierarchically were surveyed relative to workers in organizations such as shipping companies, port corporations, container terminals, and related ministries. The importance of each factor was calculated using the hierarchical analysis process (AHP). As a result of the importance analysis, priority was assigned in order of safety, productivity, investment efficiency, operational efficiency, and policy conformity. Through this, it was necessary to select a suitable transportation method for the transshipment cargo in terminals while focusing on the cargo and terminal security and preventing accidents. As a result of calculating from six ITT transportation candidates, the priority was determined in order of monorail, Autocon, and so on as ITT transportation suitable for the Busan new port..

A Design and Manufacture of Antenna with DGS(Defected Ground System) for WLAN/WiMAX system (WLAN/WiMAX 시스템 적용을 위한 DGS를 갖는 삼중대역 안테나 설계 및 제작)

  • Seo, Na-Hyun;Rhee, Young-Chul;Yoon, Joong-Han
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.4
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    • pp.679-687
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    • 2017
  • In this paper, a microstrip-fed triple-band monopole antenna with DGS (Defected Ground Structure) for WLAN/WiMAX applications was proposed. The proposed antenna is based on a microstrip-fed structure, and composed of two strip lines and DGS structure and then designed in order to get triple band characteristics. We carried out simulation about parameters. Adjusted the position and length of the two strips and three slits, we get the optimized parameters. The proposed antenna is fabricated on an FR-4 substrate of which the dielectric constant is 4.4, and its overall size is $34mm(W_1){\times}34mm(L_1){\times}1.6mm(t)$, and its proposed antenna size is $17.0mm(W_6){\times}30.75mm(L_3+L_4+L_9)$. From the fabricated and measured results, return loss of the proposed antenna satisfied return loss -10dB bandwidth 360 MHz (2.335~2.695 GHz), 645 MHz (3.37~4.015 GHz) and 1,770 MHz (5.14~6.91 GHz). And measured results of gain and radiation patterns characteristics displayed for operating bands.