• 한국수소및신에너지학회논문집
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• 제19권1호
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• pp.35-40
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• 2008

Ni-based amorphous alloy ribbon was prepared by a single-roller melt-spinning technique. Palladium coating was found to enhance significantly the absorption/desorption behavior of hydrogen in amorphous alloy. The hydrogen permeability of a Pd-coated $(Ni_{60}Nb_{40}){_{100-X}}$TaX(x=5, 10) amorphous alloy was examined in the temperature range of $623{\sim}773K$, comparable with those of $Pd_{60}-Cu_{40}$ alloys. The permeated hydrogen flux was increased with increasing the temperature and the difference of hydrogen pressure between the feed side and permeates side of the membrane. The Ni-based amorphous alloys were characterized by X-ray diffractometry(XRD) and differential scanning calorimetry(DSC). The morphology of surface and roughness was observed by using scanning electron microscopy(SEM) and atomic force microscopy(AFM).

• 한국수소및신에너지학회논문집
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• 제18권2호
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• pp.182-188
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• 2007

[ $Zr_{50}-Ni_{27}-Nb_{18}-Co_5$ ] amorphous alloys ribbon was prepared by a single-roller melt-spinning technique. In order to improve the hydrogen kinetics Pd-coating were carried out on each side of the amorphous ribbon. Pd prevents oxidation of Zr and catalyses the dissociation of molecular hydrogen to atomic hydrogen. In this work, the hydrogen embrittlement and surface properties on Zr-based amorphous alloys were investigated. The Zr-based amorphous alloys were characterized by X-ray diffractometry(XRD) and differential scanning calorimetry(DSC). The morphology of surface and roughness was observed by using scanning electron microscopy(SEM) and atomic force microscopy (AFM). A lattice parameter of both Pd and Zr-based amorphous alloy was increased after hydrogen permeation at 473 K. After hydrogen permeation at 473 K, some cracks were observed on the surface of Pd, which was the cause for the hydrogen embrittlement. The crystallization temperature of Zr-based amorphous alloy was decreased due to the permeated hydrogen.

• 한국주조공학회지
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• 제44권4호
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• pp.97-102
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• 2024

본 연구는 부분적으로 비정질 구조와 특성을 가진 Zr-14Cu-7.5Ni-2.6Al 광폭 리본의 특성을 Hall effect, SEM-EDX, XRD 등을 사용하여 분석하였다. 멜트 스피닝 방법으로 제작된 이 Zr-14Cu-7.5Ni-2.6Al 기반 합금 리본은 두께가 96㎛ 이하이고 폭이 100mm이다. 인장강도 l,641MPa, 항복강도 l,541MPa, 연신율 1%, 탄성계수 98GPa의 성능을 나타냈다. Bulk concentration, Resistivity, Mobility 값은 일반적인 heavy doping 세라믹과 금속의 중간값을 보이고 일반 금속보다 약 100배 정도 약하여 Si에 근접하며 전기 전도도가 좋은 편이다. 또한, 극한 온도에서의 폴딩 테스트를 수행하여 -20℃에서 150,000회, 24℃에서 300,000회, 60℃에서 150,000회를 견디며 폴딩 불량이 나타나지 않았다. 이 결과는 Zr-14Cu-7.5Ni-2.6Al 광폭리본 합금의 우수한 내구성과 신뢰성을 보여주며, 이러한 합금을 사용한 전자 제품의 개발 가능성을 시사한다.