• Clean Technology
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• v.20 no.2
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• pp.189-201
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• 2014

Partial oxidation, $CO_2$ reforming and the oxidative $CO_2$ reforming of $CH_4$ to produce synthesis gas over supported Ni hydrotalcite-type ($Ni_{0.5}Ca_{2.5}Al$ catalyst) catalysts were carried out and the effects of metal supports (i.e.; Mg and Ca) on the formation of a stable double-layer structure on the catalysts were evaluated. The $CH_4$ reforming stability was determined to be affected by the differences in the interaction strength between the active Ni ions and support metal ions. Only a Ni-Mg-Al composition produced a highly stable hydrotalcite-type double-layered structure; while the Ni-Ca-Al-type composition did not. Such structure provides excellent stability for the catalyst (-80% efficiency) as confirmed by the long-term $CO_2$ reforming test (-100 h), while the Ni-Ca-Al catalyst exhibited deactivation phases starting at the beginning of the reaction. The interaction strength between the active metal (Ni) and the supporting components (Mg and Al) was determined by temperature-programed reduction (TPR) analyses. The affinity was also confirmed by the TPR temperature because the Ni-Mg-Al catalyst required a higher temperature to reduce the Ni relative to the Ni-Ca-Al catalyst. The highest initial activity for synthesis gas production was observed for the $Ni_{0.5}Ca_{2.5}Al$ catalyst; however, this activity decreased quickly due to coke formation. The $Ni_{0.5}Ca_{2.5}Al$ catalyst exhibited a high reactivity and was more stable than the other catalysts because it had a higher resistance to coke formation.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.4
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• pp.362-370
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• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

• Fire Science and Engineering
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• v.18 no.4
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• pp.22-26
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• 2004

The static eliminator is used for prevention of disasters by static discharge, improvement of production efficiency, protection of a sensitive electronic element on the discharge of static, and it is handled for elimination of static in the painting plant, the film manufacturing plant, the producing semi-conductor factory. This study described on the explosion appearance by discharge phenomena on the voltage input type eliminator's ion generation bar of inflammable gas through an experimental tests. It was used Hydrogen, Ethylene, Propane, Methane gas with the inflammable gas and it was studied on the ignition phenomena by the length of ion-generation static bar, the number of ion-generation electrode and the variation of input voltage to the ion-generation electrode. As a result of this study it was confirmed that the shorter of the bar's length, the greater of explosion danger. And it is considered that there will not ignite at general using inflammable gas, in case of more than 900 mm bar and one electrode.

• Economic and Environmental Geology
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• v.47 no.3
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• pp.265-273
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• 2014

Unconventional resources are natural resources which require greater than industry-standard levels of technology or investment to exploit the commercial development. The key point is that unconventional resources are lower quality fuel sources and are not as economically viable as crude oil and conventional gas. Over the past 100 years, Conventional oil and gas has been satisfied with the energy demands. But developing countries such as China and India, the introduction of the developed countries and the surge of energy due to the depletion of unconventional energy resources will be the limelight. According to be analyzed in the academic literature to unconventional gas and oil(2000~2012) by the program of 'web of science', the research activities 402 papers in unconventional gas and 1,581 papers in unconventional oil.

• Korean Journal of Environmental Agriculture
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• v.35 no.2
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• pp.128-136
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• 2016

BACKGROUND: Hydrothermal carbonization reaction is the thermo-chemical energy conversion technology for producing the solid fuel of high carbon density from organic wastes. The hydrothermal carbonization reaction is accompanied by the thermal hydrolysis reaction which converse particulate organic matters to soluble forms (hydro-thermal hydrolysate). Recently, hydrothermal carbonization is adopted as a pre-treatment technology to improve anaerobic digestion efficiency. This research was carried out to assess the effects of hydro-thermal reaction temperature on the methane potential and anaerobic biodegradability in the thermal hydrolysate of organic sludge generating from the wastewater treatment plant of poultry slaughterhouse .METHODS AND RESULTS: Wastewater treatment sludge cake of poultry slaughterhouse was treated in the different hydro-thermal reaction temperature of 170, 180, 190, 200, and 220℃. Theoretical and experimental methane potential for each hydro-thermal hydrolysate were measured. Then, the organic substance fractions of hydro-thermal hydrolysate were characterized by the optimization of the parallel first order kinetics model. The increase of hydro-thermal reaction temperature from 170℃ to 220℃ caused the enhancement of hydrolysis efficiency. And the methane potential showed the maximum value of 0.381 Nm³ kg^-1-VS_added in the hydro-thermal reaction temperature of 190℃. Biodegradable volatile solid(VSB) content have accounted for 66.41% in 170℃, 72.70% in 180℃, 79.78% in 190℃, 67.05% in 200℃, and 70.31% in 220℃, respectively. The persistent VS content increased with hydro-thermal reaction temperature, which occupied 0.18% for 170℃, 2.96% for 180℃, 6.32% for 190℃, 17.52% for 200℃, and 20.55% for 220℃.CONCLUSION: Biodegradable volatile solid showed the highest amount in the hydro-thermal reaction temperature of 190℃, and then, the optimum hydro-thermal reaction temperature for organic sludge was assessed as 190℃ in the aspect of the methane production. The rise of hydro-thermal reaction temperature caused increase of persistent organic matter content.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.2
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• pp.59-66
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• 2016

The purpose of this study was to review of technical, economical feasibilities regarding Integrated Two-Phase Anaerobic Digestion(ITPAD) method. In order for that, operation conditions and data with 24tpd capacity of operating ITPAD plant were analyzed. The result showed that VS removal efficiency was 73.7% and total amount of biogas was generated $1,239m^3/day$ on the average that represents $54.4m^3/ton$-input of generation efficiency. ITPAD had advantages in terms of required area and energy for heating which were analyzed 15.9%~47%, 11.6%~17.8% lower respectively compared to Conventional Separated Two-Phase Anaerobic Digestion(CSTPAD) method. Thus, it is considered the ITPAD has comparatively high feasibility to be expanded and commercialized to dispose high concentration organic matter of waste such as food waste and its leachate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.10
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• pp.2779-2785
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• 2009

Among the livestock, chickens are raised because of the merit ingested protein in low-priced cost of production and are primary livestock increased the consumption of meat. The factors of influencing condition, odor is the most important factor. Odor substances are ammonia, amines, hydrogen sulfide and mercaptan which come from night soil. Livestock are prevented from rearing by means of these odor substances. Though the henhouse is heated using hot air type heater in the winter season, it is ventilated for the control of odor because of the increase of odor concentration. In the present work, composite catalytic system combined the existing facilities(hot air type heater) with catalytic system was developed, it could controled odor and hazardous gas using the oxidation/reduction reaction without extra operating cost. Moreover, the purpose of this work is to develop the catalysts which are cost competitive and can maximize energy efficiency. The catalysts are noble metal(Pt-Rh) and composite transition metal(Mn) type.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.3
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• pp.247-259
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• 2015

This study was performed to investigate the application of dark $H_2$ fermentation to two-stage bioprocesses for organic waste treatment and energy production. We reviewed information about the two-stage bioprocesses combining dark $H_2$ fermentation with $CH_4$ fermentation, photo $H_2$ fermentation, microbial fuel cells (MFCs), or microbial electrolysis cells (MECs) by using academic information databases and university libraries. Dark fermentative bacteria use organic waste as the sole source of electrons and energy, converting it into $H_2$. The reactions related to dark $H_2$ fermentation are rapid and do not require sunlight, making them useful for treating organic waste. However, the degradation is not complete and organic acids remain. Thus, dark $H_2$ fermentation should be combined with a post-treatment process, such as $CH_4$ fermentation, photo $H_2$ fermentation, MFCs, or MECs. So far, dark $H_2$ fermentation followed by $CH_4$ fermentation is a promising two-stage bioprocess among them. However, if the problems of manufacturing expenses, operational cost, scale-up, and practical applications will be solved, the two-stage bioprocesses combining dark $H_2$ fermentation with photo $H_2$ fermentation, MFCs, or MECs have also infinite potential in organic waste treatment and energy production. This paper demonstrated the feasibility of two-stage bioprocesses combining dark $H_2$ fermentation as a novel system for organic waste treatment and energy production.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.249-256
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• 2011

In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~$350^{\circ}C$, $H_2$/CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 $ml/g_{-cat{\cdot}}{\cdot}h$. It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of $NiAl_2O_4$ structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of $Ni_3C$ during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.

• KSBB Journal
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• v.18 no.2
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• pp.111-116
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• 2003

Hydrogen producing acidogenic microorganisms were self-immobilized using organic-inorganic hybrid polymer within 5 minutes. During the continuous tratment of synthetic wastewater at a hydraulic retention time of 20 hours, at 37$^{\circ}C$, pH 5.0, the self-immobillized granules were maintained in a stirred tank reactor. The black colored granules gradually became milky. Image analysis showed that the mean diameter of the milky colored granules ranged from 1.5 to 20. mm. The maximum bio-gas procuction rate was 380 ml/L/hy and the concentration of H$_2$was around 50%, while no methane was detected. Granular ECP was extracted and its content was measured to elucidate the role of the organic-inorganic hybrid polymer. Further increases of granule concentration are expected to increase the hydrogen production rate.