• Title/Summary/Keyword: 망상구조

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Removal of Hydrogen Sulfide using Reticulated Polyurethan Carrier in Biofilter (망상구조 폴리우레탄 담체를 이용한 황화수소 제거)

  • Jeong, Gwi-Taek;Lee, Gwang-Yeon;Cha, Jin-Myoung;Park, Don-Hee
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.372-377
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    • 2007
  • In order to assess its capability as biofilter bed material under variable conditions of two parameters (inlet gas concentration and inlet gas flow rate), reticulated polyurethan was applied to remove hydrogen sulfide via a biological process. We detected a maximal elimination capacity (critical loading rate) of $488.3(330.1)g-H_2S/m^3{\cdot}hr$, when reticulated polyurethane was employed as supporting material of biofilter. This study show that the application of reticulated polyurethane carrier might be a favorable choice as a packing material in biofilter for the biological removal of hydrogen sulfide.

A Study on Magnetic Properties of Amphiphilic Polymer Networks Nanocomposites by Mossbauer Spectroscopy (뫼스바우어 분광법에 의한 양친매성 고분자 망상구조 나노복합체의 자기적 성질 연구)

  • Yoon, In-Seop
    • Journal of the Korean Magnetics Society
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    • v.20 no.6
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    • pp.216-221
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    • 2010
  • Magnetic nanocomposites contained iron oxide were synthesized by through cross-linking polymerization of dimethylacetamide (DMAc) solution and toluen solution on the amphiphilic polymer networks based on urethan acrylate nonionomer (UAN) precursor chains. For the study on microscopic structures and magnetic properties of the magnetic nanoparticles, FESEM and XRD and Mossbauer spectroscopy were used. The results investigated show that there are magnetic nanoparticles of $Fe_2O_3$ in samples and the magnetic nanocomposites contained iron oxide in polymer networks of UAN using DMAc solution are more smaller than using toluen solution. All of the Fe ions in the samples present $Fe^{3+}$ and the magnetic property of samples are paramagnetic by superparamagnetic effect at room temperature.

Geochemical Behaviour of Zn, Mn and As during the Weathering of Sphalerite, Rhodochrosite, and Manganoan Calcite in the Waste-rock Dumps of the Dadeok Mine (다덕광산 폐석내 섬아연석, 능망간석, 함망간 방해석의 화학적 풍화작용과 Zn, Mn, As의 지구화학적 거동)

  • 정기영;이병윤;이석훈
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.2
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    • pp.73-83
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    • 2000
  • 다덕 광산 폐석내 섬아연석과 함망간탄산염 광물의 풍화현상과 그에 따른 중금속의 거동을 조사 하였다. 섬아연석은 풍화초기에 극미립 산화철의 망상구조 집합체로 교대되었으며, 후기에는 자연황이 용해중인 섬아연석과 산화철 집합체 사이에 침전되었다. 산화철 집합체에는 As가 다량 함유되어 있다. 능망간석와 함망간 방해석은 함아연산화망간의 망상구조 집합체로 교대되었으며, 함망간방해서과 함아연산화망간 사이에는 스미소나이트가 침전되었다. 선택적 용해외 X선회절분석을 이용하여 감정한 결과, 함아연산화망간은 헤테롤라이트/하이드로헤테롤라이트인 것으로 판명되었다. Zn의 일부는 규산과 결합하여 입간 공극에 월레마이트로 침전되었다. 풍화 초기에 형성되는 극미립 산화철 및 함아연산화망간의 치밀한 망상 집합체는 풍화용액의 순환을 차단하여, 모광물의 풍화 반응을 지체시키는 지화학적 장벽 역할을 하였다. 이에 따라 망상구조 내에 조성된 국지적 미환경하에서 풍화중간산물들이 침전되었다. 이상의 연구 결과로 다음과 같은 사항을 추론할 수 있다. 섬아연석의 Fe와 함망간탄산염의 Mn은 각각 산화철과 산화망간으로 침전되어 산성화에 기여하였다. 폐광석 더미내 As의 활동도는 저결정질 산화철에의 흡착에 의해 조절되며, Zn의 활동도는 미소환경조건에 따라 하이드로헤테롤라이트/헤테롤라이트, 스미소나이트, 월레마이트 등의 다양한 이차광물의 용해도에 의하여 조절된다.

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The Characteristics of Rat Hepatocyte Treated with Diethylnitrosamine (Diethylnitrosamine(DENA)에 의한 흰쥐 간세포의 변화)

  • 이혜영;류재혁
    • The Korean Journal of Zoology
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    • v.34 no.3
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    • pp.403-409
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    • 1991
  • 화학적 암 유발물인 diethylnitrosamine(DENA) 연여로 야기되는 흰쥐 (Sprague Dawley) 간세포의 변화 양상을 전자현미경과 silver염색방법으로 관찰하였다. DENA는 간세포내의 핵, 미토콘드리아, 담즙관에 뚜렷한 형태적 변화를 일으켰으며 인(nucleolus)의 크기와 수도 증가하였다. 또한 정상세포보다 인 (nucleolus) 부위의 염색 정도도 강하였는데 이것은 silver granule이 서로 연결되어 망상구조를 형성하기 때문인 것으로 생각되며 이들 망상구조는 순수한 rDNA부분과 핵내 단백질이 인내에서 서로 엉킨어 나타나는 현상일 것으로 사료된다. 또한 DENA투여 켤과 나타난 인의 크기와 인부위의 수적 증가현상의 결과로 rRNA 합성물의 변화를 유추할 수 있었다.

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The Geometric Properties of the Drainage Structures based on Fractal Tree (Fractal 나무를 기반으로 한 배수구조의 기하학적 특성)

  • Kim, Joo-Cheol;Kim, Jae-Han
    • Journal of Korea Water Resources Association
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    • v.41 no.8
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    • pp.797-806
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    • 2008
  • The geometric properties of the drainage structures are analyzed through depicting the drainage network which is composed of the whole drainage paths in the natural basin defined at the specific scale. The theoretical consideration is performed on the general structures of networks organized by ramification process based on Fractal tree and Horton's law. The drainage network is generated via ArcGIS, ordered by Strahler's ordering scheme and investigated with Strahler's order. As a results of the Richardson's method it is shown that there may exist the distinct behavioral characteristics between overland-flow and channel flow and the natural stream networks would be space-filling Fractals. As a result, it is shown that the values estimated by considering the overland-flow on being applied to the field data give the different results from the empirical method applied until now. As expected, therefore the results obtained from this study are sure to be devoted further researches on the channel networks.

Alterations of Zonulae Occludentes in some Different Conditions of Bile Canaliculi (상태의 차이에 따른 담세관 주위 폐쇠띠의 변화)

  • Shin, Young-Chul
    • Applied Microscopy
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    • v.27 no.3
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    • pp.295-308
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    • 1997
  • Liver tissues were taken from rats 20 min after administration of dehydrocholic acid and biligrafin, fasted for 8 days, and bile duct ligation for 48 hr. And the zonulae occludentes around the bile canaliculi were investigated by the freeze fracture method. In the normal rats, the zonulae occludentes showed networks consisting of one to four strands in many regions. After administration of dehydrocholic acid, the depth of zonulae occludentes were increased and networks consist of six to nine strands. The zonulae occludentes, however, were disorganized, and strands were reduced after administration of biligrafin. In the fasting rats, the zonulae occludentes showed one or two strands which were loosely linked. After ligation of bile duct, the zonulae occludentes were disorganized, and strands were reduced or still in a state not to be reduced. The strands were interrupted by gaps or linear particles in all the groups, especially in the biligrafin and the ligation. The free ends were remarkable in the fasting group and contact or surround the lateral gap junctions in the dehydrocholic acid group. The discontinuities and free ends of strands were also encountered in the normal group, thus suggesting that the barrier is not complete even in the normal state. The aggregation of particles appeared within the meshwork of zonulae occludentes in all the group, except for the ligation. From the evidence, it is assumed that zonulae occludentes are labile, differ in the structure according to the situation of bile canaliculi and show regional alterations even in the same bile canaliculi, that zonulae occludentes are affected by mechanical stress or certain other factors, and that there is a correlation between the strands and particle aggregations in association with the alteration of zonulae occludentes.

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Estimation of fractal dimension for Seolma creek experimental basin on the basis of fractal tree concept (Fractal 나무의 개념을 기반으로 한 설마천 시험유역의 Fractal 차원 추정)

  • Kim, Joo-Cheol;Jung, Kwan Sue
    • Journal of Korea Water Resources Association
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    • v.54 no.1
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    • pp.49-60
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    • 2021
  • This study presents a methodology to estimate two distinct fractal dimensions of natural river basin by using fractal tree concept. To this end, an analysis is performed on fractal features of a complete drainage network which consists of all possible drainage paths within a river basin based on the growth process of fractal tree. The growth process of fractal tree would occur only within the limited drainage paths possessing stream flow features in a river basin. In the case of small river basin, the bifurcation process of network is more sensitive to the growth step of fractal tree than the meandering process of stream segment, so that various bifurcation structures could be generated in a single network. Therefore, fractal dimension of network structure for small river basin should be estimated in the form of a range not a single figure. Furthermore, the network structures with fractal tree from this study might be more useful information than stream networks from a topographic or digital map for analysis of drainage structure on small river basin.

Correlation of morphological changes of rice starch granules with rheological properties during heating In excess water (가열 조리시 쌀 전분 입자들의 형태학적 변화와 리올로지 특성과의 관계)

  • Lee, Young-Eun;Osman, Elizabeth M.
    • Applied Biological Chemistry
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    • v.34 no.4
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    • pp.379-385
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    • 1991
  • Morphological changes of starch granules from 12 different varieties of rice were examined by scanning electron microscopy during heating at 2.5% (w/v) concentration. Rice starch granules proceeded through a similar pattern of progressive morphological changes daring heating, regardless of variety. Rice starch granules began to swell radially in the initial stage of gelatinization and then undergo radial contraction and random tangential expansion to form complex structures in the latter stage of gelatinization temperature range. At higher temperatures, starch granules softened and melted into thin flat discs, and then stretched into thin filaments to form three-dimensional networks. These progressive morphological changes were reflected in the changes of swelling power, solubility and amylograph viscosity of starch. During the transition of melting or softening, swelling power, solubility and amylograph viscosity increased rapidly. The time of loss of granular structure of starch depended on gelatinization temperature range. The ratio of amylose to amylopectin was largely responsible fur the rate of melting or softening and the fineness of a three-dimensional filamentous network above the gelatinization temperature range. Therefore, both the gelatinization temperature range and amylose content of starch affect the rate of cooking, and amylose content of starch affects the final texture of cooked starch paste.

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Phase Separation Structure of (PVC/Liquid Crystal) Composite Membrane ((Polyvinylchloride/액정) 복합막의 상분리 구조)

  • 이미선;최성부;이한섭;박관선;김병식
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.68-69
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    • 1998
  • 1. 서론 : 고분자/액정 복합막은 액정의 높은 분자운동성이 물질의확산에 기여하여 우수한 투과성을 나타낸다. 이 막은 3차원의 망상구조를 갖는 매트릭스 고분자내에 액정이 연속상으로 안정하게 분산된 상분리 구조를 가지고 있다. 이 복합막은 그러한 상분리 구조에 기인하여 자기지지형(self support LC) 복합막이라고도 한다. 복합막 중에 액정은 탄화수소가스에 대하여 높은 선택성을 나타내어 막속으로 흡착을 촉진하고 액정물질이 결정에서 액정으로 변화는 전이온도에서 투과계수가 100-200 증가한다고 보고하였다. (생략)

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A Study of the Mechanical Properties of Human Trabecular Bone by Spherical Indentation Test (구형압입시험을 통한 망상골의 기계적 물성 연구)

  • 배태수;김정규;이태수;최귀원
    • Journal of Biomedical Engineering Research
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    • v.22 no.5
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    • pp.419-424
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    • 2001
  • We intended to evaluate the Young's modulus of trabecular bone of a human distal femur by spherical Indentation test and CT images and to quantify relationships between the direction of load, density. and Young's modulus. The specimens were scanned at 1 mm intervals on CT scanner After scanning the bones were sectioned with diamond saw. producing 8mm cubes of trabecular bone. The tubes were mechanically tested in inferior-superior(IS), anterior-posterior(AP). and medial-lateral(ML) direction with custom-made device. After testing, the real apparent density of specimens were measured. The results of this study showed that the IS modulus was significant1y greater than both the AP and ML modulus and the AP modulus was also greater than ML modulus significantly(p〈0.01) A significant Power relationship between the apparent density and the modulus was also found.

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