• 베이커리
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• no.12 s.389
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• pp.96-99
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• 2000

• 베이커리
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• no.8 s.349
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• pp.34-50
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• 1997

• Membrane Journal
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• v.30 no.2
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• pp.131-137
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• 2020

In this study, effect of inorganic particles on organic fouling was investigated by a laboratory-scaled pressurized membrane filtration. In order to cause organic fouling, sodium alginate (SA) was used as a feed solution. Regardless of the presence of inorganic SiO₂ particles, the complete pore blocking played an important role in determining the fouling rate during the initial period of membrane filtration. However, the formation of cake layer resulted in the membrane fouling more dominantly as filtration time progressed. In the presence of inorganic particles, both specific cake resistance and compressibility associated with the membrane fouling formed were relatively lower than that without SiO₂ particles. Membrane fouling was more severe at constant flux mode of filtration than that observed at constant pressure mode probably due to the concomitant increase of compressibility of fouling layer with transmembrane pressure (TMP). It was found that the presence of SA and SiO₂ particles in feed solution provided the synergistic effect on the hydraulic backwashing to reduce membrane fouling as compared to the SA solution alone without the inorganic particles.

• Membrane Journal
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• v.27 no.6
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• pp.519-527
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• 2017

Membrane fouling is the main issue hindering the expansion of low pressure membrane processes for surface water treatment. Therefore, applying periodic hydraulic cleaning for fouling control should be well optimized. Better understanding of membrane fouling associated with periodic hydraulic cleaning would be useful to optimize membrane cleaning strategies. By comparing experimental permeability data with the classical Hermia blocking laws, this study aims at analyzing membrane fouling and understanding dominant fouling mechanisms occurring when filtering a synthetic surface water solution with a pressurized membrane process during six filtration cycles of 30 min each, separated with cyclic cleaning of 1 min by backwashing and forward flushing separately and combined. When applying single cleaning technique, membrane fouling during the first cycles was controlled by complete blocking mechanism while the last cycles were dominated by cake formation. Nevertheless, when combining cleaning technique better membrane regeneration was obtained and fouling was mainly due to cake formation.

• The KSFM Journal of Fluid Machinery
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• v.14 no.6
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• pp.35-44
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• 2011

Membrane filtration has become firmly established as a primary process for ensuring the purity, safety and efficiency of treatment of water or effluents. Several researches have been performed to develop and design membrane systems in order to increase the accuracy and performance of the processes. In this study, a lattice Boltzmann method for the cake layer has been developed using particle dynamics based on an immersed boundary method and the cake layer formation process on membrane has been numerically simulated. Case studies including various particle sizes were also performed for a microfiltration process. The growth rate of the cake layer thickness and the permeation flow rate along the membranes were predicted. The results of this study agreed well with that of previous experiments. Effects of various particle diameters on the membrane performance were studied. The cake layer of a large particle tended to be growing fast and the permeation flow going down rapidly at the beginning. The layer thickness of a small particle increased constantly and the flow rate was smaller than that of the large particle at the end of simulation time.

• Membrane Journal
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• v.12 no.1
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• pp.41-50
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• 2002

The streaming potential generated by the electrokinetic flow within electric double layer of charged microchannel is applied to determine the zeta potential of hollow-fiber membrane pore by using the general Helmholtz-Smoluchowski equation. The streaming potential is know to provide a useful real-time information on the surface property and the interaction between pore and particles in actual situations and physicochemical conditions. The influence of physicochemical parameters upon the filtration with hollow-fibers has been examined with an in-situ and simultaneously monitoring the streaming potential as well as permeate flux. In particular, the present study examined an experimental method to identify the effect of cake layer which can vary according to the axial position of a hollow-fiber and the progress of membrane fouling by measuring the position-dependent streaming potential. As the latex concentration increases, the permeate flux decreased but the streaming potential increased. The growth of cake layer has been mire developed with increasing latex concentration, however, the effect of surface charges of latexes deposited on the membrane surface leads to increase the streaming potential. With increasing ionic concentration of KCI, both the permeate flux and the streaming potential decrease. The increase of ionic concentration provides a compact cake layer due to the shrinkage of Debye length and the decreased streaming potential results from the weakened ionic flows owing to a thin diffusive double layer.

• Membrane Journal
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• v.14 no.1
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• pp.66-74
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• 2004

Total resistance of membrane in a micro-filtration system using a metal membrane was mainly attributed to the permeate resistance of cake layer($R_c$), which was formed by deposited particles from the physico-chemical interactions of solids on membrane surface. Intermittent back ozonation was highly effective than the air backwashing for fouling reduction. As far the operational effect, under same ozone injection, the increase of gas flow-rate was more favorable than the increase of injection time far the recovery of permeation flux. As the filtration time was longer, the effect of flux recovery by intermittent back-ozonation decreased. Therefore, it is preferable to operate membrane cleaning before the foulant is consolidated on membrane surface.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.6
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• pp.406-413
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• 2012

Effect of three additives, chitosan, ferric chloride, and MPE50 on membrane fouling reduction was studied. They were introduced with various dosing rate into activated sludge, and changes in filtration resistance measured by the batch cell filtration test were evaluated. Both the filtration resistance and the specific cake resistance were minimized at 20 mg/g-MLSS with chitosan, 70 mg/g-MLSS with ferric chloride, and 20 mg/g-MLSS with MPE50 addition, respectively. Introduction of the additives into the activated sludge resulted in reduction of not only cake resistance, but also fouling resistance. However, the chitosan addition to three different activated sludge resulted in three different optimal dose of 10, 20, 30 mg/g-MLSS, respectively. This implies that the optimal dose is dependent on sludge characteristics rather than a constant value. Overdose above the optimal dosage always aggravated filterability in all cases. Zeta potential of sludge flocs, relative hydrophobicity, floc size distribution, soluble EPS concentration and supernatant turbidity were measured in order to analyze fouling reduction mechanism. Nearly neutral surface charge along with the largest particle size was observed at the optimal dose. This could be explained by particle destabilization and restabilization mechanism as positively charged additives were injected into sludge flocs of negative surface charge. Both soluble EPS concentration and supernatant turbidity also showed the lowest value at the optimal dose. These foulants are believed to be coagulated and entrapped in sludge flocs during flocculation. Chitosan and MPE50 which are cationic polymeric substances showed higher reduction in both soluble EPS and fine particles comparing with ferric chloride.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.959-970
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• 2000

A laboratory-scale experiment was conducted to investigate the effect of soluble microbial products(SMP) on permeate flux in the submerged membrane separation activated sludge process. Continuous and batch filtration test were operated to understand mechanism of relationship between membrane fouling and SMP. Synthetic wastewater(phenol) was used as a carbon source. Hydraulic retention time(HRT) and mixed-liquor volatile suspended solids(MLVSS) of the reactor were kept at 12 hours and 9.000mg VSS/L, respectively. Batch filtration tests ($J_{60}/J_o$) using the mixed liquor from reactor showed that the increase of accumulated SMP concentration in the reactor caused to the decreasing permeate flux and the increasing of the adhesion matters which form cake and gel layer. The resistance value of cake layer was measured $2.9{\times}10^{10}{\sim}4.0{\times}10^{10}(1/m)$, this value showed more significant effect on flux drop than that of among other resistance layers. Batch phenol-degradation experiment was conducted to observe SMP type expected $SMP_{nd}$ and $SMP_{e}$ (SMP resulted from endogenous cell decomposition), these are non-biodegradable high molecular weight organic matter and playa significant role in permeate flux drop. Also, SMP concentration was accumulated as increased of HRT against flux drop.

• Membrane Journal
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• v.28 no.4
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• pp.252-259
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• 2018

An acidic, real metal-plating wastewater was treated by a fluidized bed membrane reactor introduced with granular activated carbon (GAC) as fluidized media. With GAC fluidization, there was no increase in suction pressure with time at each flux set-point applied. At neutral solution pH, much less fouling rate was observed than acidic pH under GAC fluidization. Higher solution pH resulted in the increase in particle size in metal-finishing wastewater, thus producing a less dense cake structure on membrane. More than 95% of chemical oxygen demand was observed from the fluidized bed membrane reactor under GAC fluidization. Total suspended solid concentration in membrane permeate was near zero. At the raw wastewater pH, no removal of copper and chromium by the fluidized bed membrane reactor was observed. As the pH was increased to 7.0, removal efficiency of copper and chromium was increased considerably to 99 and 94%, respectively. Regardless of solution pH tested, more than 95% of cyanide was removed possibly due to the strong adsorption of organic-cyanide complex on GAC in fluidized bed membrane reactor.