• Proceedings of the Korean Ceranic Society Conference
• /
• 2000.10a
• /
• pp.129.1-129
• /
• 2000

• Electronics and Telecommunications Trends
• /
• v.38 no.6
• /
• pp.128-136
• /
• 2023

Lithium accounts for only 0.0017% of the earth crust, and it is produced in geographically limited regions such as South America, the United States, and China. Since the first half of 2017, the price of lithium has been continuously increasing, and with the rapid adoption of electric vehicles, lithium resources are expected to be depleted in the near future. In addition, economic blocs worldwide face intensifying scenarios such as competition for technological supremacy and protectionism of domestic industries. Consequently, Korea is deepening its dependence on China for core materials and is vulnerable to the influence of the United States Inflation Reduction Act. We analyze post-lithium secondary battery technologies that rely on more earth-abundant elements to replace lithium, whose production is limited to specific regions. Specifically, we focus on the technological status and issues of sodium-ion, zinc-air, and redox-flow batteries. In addition, research trends in post-lithium secondary batteries are examined. Post-lithium secondary batteries seem promising for large-capacity energy storage systems while reducing the costs of raw materials compared with existing lithium-based technologies.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.2
• /
• pp.81-87
• /
• 1999

Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

• Journal of the Korean Electrochemical Society
• /
• v.17 no.3
• /
• pp.187-192
• /
• 2014

In this article, we report the fabrication and characterization of $CNT/Co_3O_4$ nanocomposite for lithium ion batteries. We expected that the composition with CNT is effective method to compensate for the low electronic conductivity of $Co_3O_4$ and suppress the stress from phase transition of $Co_3O_4$ during cycling. $CNT/Co_3O_4$ nanocomposites were composed of nano-sized $Co_3O_4$ particles, which were homogeneously distributed on the surface of CNTs. The $CNT/Co_3O_4$ electrode presented higher capacity than commercial graphite, good rate capability and stable cyclic performance. This implies that the $CNT/Co_3O_4$ could be a promising anode material for lithium ion batteries.

• Electrical & Electronic Materials
• /
• v.22 no.7
• /
• pp.12-23
• /
• 2009

• Proceedings of the Korean Fiber Society Conference
• /
• 1998.10a
• /
• pp.512-516
• /
• 1998

탄소재료는 높은 전기전도도 및 기계적 강도, 화학적 안정성, 큰 비표면적(1000~3000$m^2$/g) 등의 특성 때문에 연료전지, 리튬이온 이차전지, 전기 이중층 캐패시터(electric double layer capacitor, EDLC).의 전극 활물질로 주목받고 있다[1]. 탄소섬유는 보통 특성과 전구체 핏치에 따라서 두 가지 종류로 분류된다[2]. 하나는 메조페이스 핏치로부터 제조된 고성능 탄소섬유(HPCF)이다. (중략)

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.38 no.7
• /
• pp.589-594
• /
• 2014

Recently, higher capacity and energy density of lithium ion batteries are increasingly demanded for enhancing their performance in view of the rise in the commercial distribution of electric and hybrid vehicles. Computational analysis of a porous structure of vanadium pentoxide cathode was performed, employing a phase field model. The incipient model was designed as a spherical structure with cylindrical-shaped pores. Modifying the diameters and lengths of the pore cylinder and the number of pores, we considered different conditions for the porous vanadium pentoxide cathodes for analyzing their effect on the amount of lithium ion intercalated to them. Subsequently, we optimized the porous structure to contain the largest amount of intercalated lithium ion during discharge.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.9
• /
• pp.326-332
• /
• 2018

Korea faces major changes in energy policy, which include eco-friendly and zero-nuclear power. On the other hand, there are very few policies for the waste-management of mid- to large-sized lithium-ion batteries, such as electric car batteries and energy storage systems, which are expected to increase explosively due to such energy policy changes. Therefore, this study estimated the amount of mid- to large-sized lithium ion batteries waste and performed economics analysis of a middle and large sized secondary battery recycling project. Based on the results, a policy alternative for the revitalization of the related lithium-ion battery recycling industry is suggested. As a result, the B / C ratio of a domestic mid - to large - sized lithium ion battery recycling project is 1.06, in which the benefit is higher than the cost, so the business is economic feasible. Although the recycling project's economic efficiency is high, the recycling industry has not been activated in Korea because the domestic demand for rechargeable batteries recycling is very low. To solve this problem, this study proposes a plan to activate the industry by adding lithium secondary batteries to the EPR (Extended Producer Responsibility) items.

• Proceedings of the KIPE Conference
• /
• 2016.07a
• /
• pp.411-412
• /
• 2016

최근 퍼스널 모빌리티에 대한 관심과 수요가 증대됨에 따라 전기에너지를 구동원으로 하는 소형 이동형 제품을 생활속에서 쉽게 접할 수 있게 되었다. 이러한 퍼스널 모빌리티 제품은 자이로센서 기술이 접복된 바퀴가 하나인 외발 전동휠과 세그웨이류의 제품, 전동퀵보드, 전동스쿠터 등 다양한 제품이 출시되고 있다. 또한 이들 제품의 구동전원은 대부분 리튬이차전지가 사용되고 있다. 본 논문에서는 충전과 방전을 반복하는 다셀이 직렬로 구성된 리튬 이차전지 배터리팩에서 발생되는 셀간 편차와 이로 인해 배터리팩의 전체적인 효율성이 저하되는 것을 방지하는 셀 밸런싱에 관한 기술로 과거 완속형의 표준충전에 적합한 1단 밸런싱의 문제점을 보완하기 위해 표준충전과 급속충전을 임의로 선택하여 사용하는 경우에도 정상적인 셀 밸런싱 수행은 물론 빠른 셀 밸런싱을 수행하기 위한 기법에 대해 살펴보았다.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2018.06a
• /
• pp.71-71
• /
• 2018

현재 상용화된 Graphite 음극활물질의 경우 낮은 부피당, 무게당 용량을 가지며 이는 다양한 분야에 활용하는데 제약이 있다. $SiO_2$는 Si에 비해서는 낮은 용량이지만 metal oxide 계열 중 가장 높은 이론용량을 가지고 있으며, 리튬 이온과 반응 시 큰 부피팽창을 하며, 절연체로 전기전도도가 낮아 리튬이 차전지의 음극재로 상용화가 어려운 단점이 있다. 본 연구에서는 TEOS를 이용하여 탄소와 $SiO_2$를 동시에 $TiO_2$ microcone 구조에 코팅하여 3가지 물질의 복합체를 형성하여 용량을 증대시키고 구조적 안전성을 향상시키는 방법을 소개 한다. 음극재의 특성은 고분해능 주사전자현미경 (HR-SEM), 고분해능 엑스선 회절분석기 (XRD), 를 통해 조사하였으며, 순환전류법 (CV), 충 방전 싸이클 분석을 통해 리튬이차전지의 작동원리와 보다 향상된 성능을 규명하였다.