• Title/Summary/Keyword: 등급법

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Investigation of Nonylphenols Contamination in Solvents and Solid-phase Extraction Cartridge, and its Removal Protocols (정밀분석용 용매 및 SPE의 Nonylphenols 오염평가 및 제거)

  • Park, Jong-Min;Choi, Geun-Hyonng;Kim, Jung-Im;Hong, Su-Myeong;Kwon, Oh-Kyung;Im, Geon-Jae;Kim, Jin-Hyo
    • The Korean Journal of Pesticide Science
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    • v.15 no.1
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    • pp.22-27
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    • 2011
  • Nonylphenols are toxic compounds classified as endocrine disruptors. We investigated the nonylphenols clean-up procedures for the contamination control in the quantitative analysis. In this research we analyzed the residual nonylphenols in the solvent and the SPE cartridges. First, at the analysis of HPLC grade solvents (n-hexane, diethyl ether, ethyl acetate and its mixture), diethyl ether was confirmed the residue as 0.963 ${\mu}g/mL$, and we eliminated the contaminant through the distillation with $CaH_2$, Second, at the analysis of SPE cartridges (silica gel and Florisil), all products were showed the residue at 0.046~13.0 ${\mu}g/mL$, but unfortunately the residue in the cartridge were not easily removed with referenced methods in all tested SPE cartridges except in silica gel SPE cartridge with glass ware.

Suggestion for Determination of Minimum $S_D$ for Rut-Resistable Asphalt Concretes (고온 내변형 아스팔트혼합물 선정을 위한 변형강도 임계치 결정 방안)

  • Kim, Kwang-W.;Cho, Byung-J.;Lee, Soon-Jae;Doh, Young-S.
    • International Journal of Highway Engineering
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    • v.9 no.4
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    • pp.193-204
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    • 2007
  • Deformation strength($S_D$) is a property which shows relatively good correlation with rut resistance of asphalt mixtures at high temperature. The Asphalt Pavement Analyzer (APA) is widely used as an equipment for estimating rut resistance of asphalt mixtures. The APA was used as corresponding property of the $S_D$ to estimate rutting resistance of asphalt mixtures. Many data were collected to establish the correlation of $S_D$ with APA. For $S_D$ test, the specimen is submerged into the $60^{\circ}C$ water for 30 minutes before applying a vertical load at the speed of 50mm/min to obtain peak load (P) and deformation (y) for $S_D$ calculation. For the same materials, APA test was performed. Relation of the $S_D$ with APA rut depth was evaluated using regression analysis. The $R^2$ value was 0.76, indicating this simple test procedure being a possible method for predicting deformation resistance of asphalt concretes at high temperature. It was also shown that, using the regression model, minimum value(s) of $S_D$ of surface course asphalt mixture or binder course for a particular road level can be determined. The limit values may be possible to use as cut-off value(s) of asphalt mixtures for the layer after further elaborated studies.

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Clinical Significance of Hydronephrosis in Febrile Urinary Tract Infection (발열성 요로 감염 환아에서 발견된 수신증의 임상적 의의)

  • Oh, Jung-Min;Lee, Na-Ra;Yim, Hyung-Eun;Yoo, Kee-Hwan;Hong, Young-Sook;Lee, Joo-Won
    • Childhood Kidney Diseases
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    • v.14 no.1
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    • pp.71-78
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    • 2010
  • Purpose : Hydronephrosis is found about 30% of children with urinary tract infection (UTI). It can be caused by various conditions, although most childhood hydronephrosis is congenital. This study was performed to investigate the relationship between febrile UTI and hydronephrosis. Methods : We retrospectively reviewed the medical charts of 183 patients diagnosed as UTI between January 2007 and May 2009 at Korea University Guro Hospital. Inclusion criteria were as followings; 1) fever more than $37.5^{\circ}C$ measured in the axilla, 2) positive urine culture, 3) no history of urinary tract anomaly on antenatal sonography and urinary tract infection. We classified the enrolled children into two groups of patients with hydronephrosis (HN) and those without hydronephrosis (NHN). Results : The 80 patients were HN and 103 patients NHN. Hydronephrosis was found in 58 patients with left kidney, 8 right and 14 both kidneys. Most of hydronephrosis were of low grade. Compared with NHN group, initial renal cortical defects on DMSA scan significantly increased in HN group (HN 37.5%, NHN 16.5%, P<0.05). The incidence of VUR was not different between the two groups (HN 22%, NHN 12.1%). White blood cell counts and C-reactive protein were not different between the two groups. Follow-up DMSA scan (about 6 months later after UTI) showed no difference of renal scarring in both two groups. Conclusion : Our data suggests that hydronephrosis in febrile UTI patients is clinically useful for detecting renal cortical defects, but is not associated with follow-up renal scar.

Determination of Dietary Fiber Content in Some Fruits and Vegetables (과일.채소중 식이섬유의 분석법 검토 및 함량 분석)

  • Lee, Kyung-Sook;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.19 no.4
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    • pp.317-323
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    • 1987
  • This study was undertaken to examine the applicability of domestic enzymes in the quantitative determination of dietary fibers according to the official enzymatic-gravimetric method of AOAC and to apply it to 4 kinds of fruits (apple, pear, peach and persimmon) and 4 kinds of vegetables (Korean radish, lettuce, Korean cabbage and cabbage Kimchi). With domestic enzymes, an optimum condition was selected to use 1/10 units of enzyme activity and to extent the reaction time two-fold as compared with the recommended method, in the case of fruits and vegetables. On a dry matter basis, fiber contents of fruits were in the range of 9.4-28.8% total dietary fiber, 1.8-7.8% non-cellulosic polysaccharides, 3.7-5.8% cellulose and 1.3-21.3% lignin. Fiber contents of vegetables were 26.0-35.7% total dietary fiber, 11.3-14.4% non-cellulosic polysac-charides, 12.3-19.7% cellulose and 1.4-7.4% lignin. On a dry matter basis, crude fiber contents were 3.5-6.7%in fruits and 9.1-13.8% in vegetables. Therefore, crude fiber contents of fruits and vegetables accounted for only 12-50% of total dietary fibers.

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A Value Evaluation Research of the Old-growth and Giant Tree - Focus on Gyeongju Gyerim's Zelkova Serrata - (노거수의 가치 평가 연구 - 경주 계림숲 느티나무를 대상으로 -)

  • Son, Hee-Jun;Xia, Tian-Tian;Kim, Young-Hun;Kang, Tai-Ho
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.34 no.4
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    • pp.51-56
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    • 2016
  • Old-growth and giant tree is a nonrenewable resource with great value. The purpose of this study is to provide scientific and reasonable evaluations for the preservation and management of the old-growth and giant tree. Until now the research of old-growth and giant tree's value evaluation and authoritative index is so insufficient and imperfection. Combining with the particularity of the old-growth and giant tree, this study analyzed the main value factors of the old-growth and giant tree and objectively selected the evaluation indicators. According to the actual situation value appraisal model of the old-growth and giant tree was builded. The main value factors can be divided into economic value, cultural history, growing place, tree state, tree form, tree vigor, protection level, growth environment, tree species, tree canopy, and so on. The evaluate indicators can be selected and the indicators' weight can be calculate using analytic hierarchy process methods(AHP). Based on economic value and indicators' weight, tree's total value can be revealed. After calculation and analysis, Gyeongju Gyerim Zelkova serrata's value evaluation results is 491,503,300 won. The research results of this study can provide scientific basis and reference to the old-growth and giant trees' value appraisal and loss compensation, and arouse people's environmental awareness.

Smart Synthetic Path Search System for Prevention of Hazardous Chemical Accidents and Analysis of Reaction Risk (반응 위험성분석 및 사고방지를 위한 스마트 합성경로 탐색시스템)

  • Jeong, Joonsoo;Kim, Chang Won;Kwak, Dongho;Shin, Dongil
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.781-789
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    • 2019
  • There are frequent accidents by chemicals during laboratory experiments and pilot plant and reactor operations. It is necessary to find and comprehend relevant information to prevent accidents before starting synthesis experiments. In the process design stage, reaction information is also necessary to prevent runaway reactions. Although there are various sources available for synthesis information, including the Internet, it takes long time to search and is difficult to choose the right path because the substances used in each synthesis method are different. In order to solve these problems, we propose an intelligent synthetic path search system to help researchers shorten the search time for synthetic paths and identify hazardous intermediates that may exist on paths. The system proposed in this study automatically updates the database by collecting information existing on the Internet through Web scraping and crawling using Selenium, a Python package. Based on the depth-first search, the path search performs searches based on the target substance, distinguishes hazardous chemical grades and yields, etc., and suggests all synthetic paths within a defined limit of path steps. For the benefit of each research institution, researchers can register their private data and expand the database according to the format type. The system is being released as open source for free use. The system is expected to find a safer way and help prevent accidents by supporting researchers referring to the suggested paths.

Groundwater level behavior analysis using kernel density estimation (비모수 핵밀도 함수를 이용한 지하수위 거동분석)

  • Jeong, Ji Hye;Kim, Jong Wook;Lee, Jeong Ju;Chun, Gun Il
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.381-381
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    • 2017
  • 수자원 분야에 대한 기후변화의 영향은 홍수, 가뭄 등 극치 수문사상의 증가와 변동성 확대를 초래하는 것으로 알려져 있으며, 이에 따라 예년에 비해 발생빈도 및 심도가 증가한 가뭄에 대한 모니터링 및 피해경감을 위해 정부에서는 국민안전처를 비롯한 관계기관 합동으로 생활 공업 농업용수 등 분야별 가뭄정보를 제공하고 있다. 국토교통부와 환경부는 생활 및 공업용수 분야의 가뭄정보 제공을 위해 광역 지방 상수도를 이용하는 급수 지역과 마을상수도, 소규모급수시설 등 미급수지역의 용수수급 정보를 분석하여 가뭄 분석정보를 제공 중에 있다. 하지만, 미급수지역에 대한 가뭄 예?경보는 기준이 되는 수원정보의 부재로 기상 가뭄지수인 SPI6를 이용하여 정보를 생산하고 있다. 기상학적 가뭄 상황과 물부족에 의한 체감 가뭄은 차이가 있으며, 미급수 지역의 경우 지하수를 주 수원으로 사용하는 지역이 대부분으로 기상학적 가뭄지수인 SPI6를 이용한 가뭄정보로 실제 물수급 상황을 반영하기는 부족한 실정이다. 따라서 본 연구에서는 미급수지역의 주요 수원인 지하수의 수위 상황을 반영한 가뭄모니터링 기법을 개발하고자 하였으며, 가용량 분석이 현실적으로 어려운 지하수의 특성을 고려하여 수위 거동의 통계적 분석을 통해 가뭄을 모니터링 할 수 있는 방법으로 접근하였다. 국가지하수관측소 중 관측기간이 10년 이상이고 강우와의 상관성이 높은 관측소들을 선정한 후, 일수위 관측자료를 월별로 분리하여 1월~12월 각 월에 대해 핵밀도 함수 추정기법(kernel densitiy estimation)을 적용하여 월별 지하수위 분포 특성을 도출하였다. 각 관측소별 관측수위 분포에 대해 백분위수(percentile)를 이용하여, 25%~100% 사이는 정상, 10%~25% 사이는 주의단계, 5%~10% 사이는 심한가뭄, 5% 이하는 매우심함으로 가뭄의 단계를 구분하였다. 각 백분위수에 해당하는 수위 값은 추정된 Kernel Density와 Quantile Function을 이용하여 산정하였고, 최근 10일 평균수위를 현재의 수위로 설정하여 가뭄의 정도를 분류하였다. 분석된 결과는 관측소를 기점으로 역거리가중법(inverse distance weighting)을 통해 공간 분포를 시켰으며, 수문학적, 지질학적 동질성을 반영하기 위하여 유역도 및 수문지질도를 중첩한 공간연산을 통해 전국 지하수 가뭄상태를 나타내는 지하수위 등급분포도를 작성하였다. 실제 가뭄상황과의 상관성을 분석하기 위해 언론기사를 통해 확인된 가뭄시기와 백문위수 25%이하로 분석된 지하수 가뭄시기를 ROC(receiver operation characteristics) 분석을 통해 비교 검증하였다.

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Comparison of the CO2 Emission Estimation Methods in a LNG Power Plant Based on the Mass Balance Approach (물질수지 방법을 고려한 액화천연가스 발전소에서의 온실기체 배출량 산정 방법 비교)

  • Kim, Hee-Jin;Yeo, Min Ju;Kim, Yong Pyo;Jang, Geon Woo;Shin, Won Geun;Lee, Myung Hwoon;Choi, Hyung Wook
    • Journal of Climate Change Research
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    • v.4 no.3
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    • pp.235-244
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    • 2013
  • Carbon dioxide emission estimation methods consist of four tiers according to the IPCC guideline. In this study, estimated results by tier 3 and tier 4 were compared with the theoretically calculated $CO_2$ emissions based on the mass balance approach for a gas fired power plant between March and May 2011. It was found that the relative differences were upto 17% between the measured emissions by tier 4 and theoretically estimated emissions, while the results of tier 3 were similar to those from theoretically estimated ones. The comparisons suggested the possibility of misestimation due to replacing missing, abnormal, or invalid data in continuous emissions monitoring system. When using only the data without those missing, abnormal, or invalid data, the relative differences decreased somewhat but still showed consistent differences depending on the stack. It is suggested that this differences might be due to the accuracy of the measurement instruments for the tier 4, especially, for the flow rate measurement instrument.

A Study on the Application of GOCI to Analyzing Phytoplankton Community Distribution in the East Sea (동해에서 식물플랑크톤 군집 분포 분석을 위한 GOCI 활용 연구)

  • Choi, Jong-kuk;Noh, Jae Hoon;Brewin, Robert J.W.;Sun, Xuerong;Lee, Charity M.
    • Korean Journal of Remote Sensing
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    • v.36 no.6_1
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    • pp.1339-1348
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    • 2020
  • Phytoplankton controls marine ecosystems in terms of nutrients, photosynthetic rate, carbon cycle, etc. and the degree of its influence on the marine environment depends on their physical size. Many studies have been attempted to identify marine phytoplankton size classes using the remote sensing techniques. One of successful approach was the three-component model which estimates the chlorophyll concentrations of three phytoplankton size classes (micro-phytoplankton; >20 ㎛, nano-; 2-20 ㎛ and pico-; <2 ㎛) as a function of total chlorophyll. Here, we examined the applicability of Geostationary Ocean Colour Imager (GOCI) to the mapping of the phytoplankton size class distribution in the East Sea. A fit of the three-component model to a biomarker pigment dataset collected in the study area for some years including a large harmful algal bloom period has been carried out to derive size-fractioned chlorophyll concentration (CHL). The tuned three-component model was applied to the hourly GOCI images to identify the fractions of each phytoplankton size class for the entire CHL. Then, we investigated the distribution of phytoplankton community in terms of the size structure in the East Sea during the harmful Cochlodinium polykrikoides blooms in the summer of 2013.

Analysis of Surface Contaminants and Physical Properties of the Daejanggakgibi Stele of Silleuksa Temple using Non-destructive Technology (비파괴 기술을 활용한 여주 신륵사 대장각기비의 표면오염물 분석과 물성진단)

  • KIM, Jiyoung;LEE, Myeongseong
    • Korean Journal of Heritage: History & Science
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    • v.55 no.2
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    • pp.186-197
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    • 2022
  • The Daejanggakgibi Stele of Silleuksa Temple in Yeoju is a stone stele from the Goryeo Dynasty that is inscribed with various stories about the construction of Daejanggak, a place where Buddhist scriptures were kept. This stele has been maintained for a long time in a state in which discoloration of the body has occurred, and the inscription has been partially damaged due to dozens of cracks. Using non-destructive analysis methods for stone artifacts, material investigation, portable X-ray fluorescence analysis, and ultrasonic velocity analysis for the stele were performed. It was confirmed that the stele body was composed of light gray crystalline limestone, and the base stone, support stone, and cover stone were medium-grained biotite granite. Portable X-ray fluorescence analysis confirmed that iron(Fe) was an original coloring element of the stele surface. From the distribution pattern of the coloration, it can be inferred that iron-containing materials flew down from between the stele body and the cover stone. Thereafter, living organisms or organic contaminants attached to it so that yellow and black contaminants were formed. Ultrasonic diagnosis revealed that the physical property of both the front and back surfaces ranged from fresh rocks(FR) to completely weathered rocks(CW), and the average weathering index was grade 3(intermediate). However, the point where cracks developed intensively was judged to be the completely weathered stage(CW), and some cracks located in the upper and lower parts of the stele bear potentially very high risk. It is necessary to monitor the movement of these cracks and establish reinforcement measures for conservation in the future.