• Title/Summary/Keyword: 뒤틀림 운동

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EDISON 양자화학 솔버를 이용하여 2-C3H5Br의 ZEKE/MATI 스펙트럼 이해하기

  • Park, Jeong-Bin;Hwang, Ji-Ye
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.15-22
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    • 2016
  • 분자의 진동(특히, 뒤틀림 운동)은 분자의 반응성과 동역학적 특성을 결정하는 중요한 요인이다. 특히, 분자내 메틸기의 뒤틀림 운동은 매우 흔히 관찰되지만, 이 운동을 분광학 실험으로 관찰하고 이론적으로 설명하는 것은 여전히 어려운 과제이다. 여러 양자화학 소프트웨어가 상용화되어 있지만, 뒤틀림 운동과 같은 주기적인 퍼텐셜 에너지를 갖는 운동을 기술하기 위해서는 뒤틀림 운동을 위한 양자화학 솔버가 필요하다. 따라서, 우리는 EDISON의 양자화학 솔버(1차원 슈레딩거 방정식(LagChem), 작은 유기 분자의 분광스펙트럼 분석을 위한 양자 소프트웨어(SGU-QASSO))들을 이용하여 $2-C_3H_5Br$의 ZEKE/MATI (J.Chem.Phys.119,12351(2003),Zero kinetic energy/mass-analyzed threshold ionization)스펙트럼을 이해하고 해석해보았다. $2-C_3H_5Br$ 분자는 메틸기의 강한 뒤틀림 운동을 관찰 할 수 있는 비교적 간단한 분자이기 때문에 뒤틀림 운동 분석을 위한 실험대상으로 적절하다(J.Chem.Phys.119,12352(2003)). $2-C_3H_5Br$ 분자의ZEKE/MATI스펙트럼의 결과는 EDISON양자화학 솔버를 통해 성공적으로 재현되었다. 각 진동 전이의 진동수와 세기는 실험 결과와 일치했으며, 진동 상태에 따른 파동 함수도 구할수 있었다. 이를 바탕으로 thietane 분자와 같은 고리분자의 ring-puckering운동에 대해 이해하려 한다.

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Effect of Golf Shoe Design on Kinematic Variables During Driver Swing (골프화의 구조적 특성 및 내부형태에 따른 스윙의 운동학적 변인에 미치는 영향)

  • Park, Jong-Jin
    • Korean Journal of Applied Biomechanics
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    • v.19 no.1
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    • pp.167-177
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    • 2009
  • The purpose of this study was to investigate effect of golf shoe design on kinematic variables during golf swing. Five professional male golfers with shoe size 270mm were recruited for the study. Swing motion was collected using 8 high speed camera motion analysis at a sampling of 180Hz. Kinematic variables were calculated by EVaRT 4.2 software. Driver swing was divided into four events; El(adress), E2(top), E3(impact) and E4(finish). Time, peak velocity, velocity of center of mass, velocity of the foot and ankle angle during Phase 1(El-E2), Phase 2(E2-E3), and Phase 3(E3-E4) were analyzed in order to investigate the relationship between golf shoe design and swing performance. The findings indicated that type C golf shoes would be beneficial for stability and control of movement during address and swing performance. Furthermore, faster speed of golf shoes, center of mass, and both feet were observed with Type C golf shoes. It is expected that golfers with Type C golf Shoes provide greater force as they control the center of mass faster and increase rotational force during impact compared to other golf shoes.

Arthroscopic Pull-out Wire Fixation Using Cannulated Screw of Tibial Eminence Fractures (도관 나사못을 이용한 경골 과간 융기 골절의 관절경적 견인 봉합술)

  • Kim, Jong-Min;Kim, Hyung-Gyu;Park, Byeong-Mun;Song, Kyeong-Seop;Jung, Sung-Hoon;Noh, Haeng-Kee;Yoon, Jong-Joo
    • Journal of the Korean Arthroscopy Society
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    • v.13 no.3
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    • pp.254-258
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    • 2009
  • Tibial eminence fracture is caused by distortion, excessive flexion and extension, varus and valgus injury of the knee joint in the form of avulsion fracture. A failure over the exact anatomical reduction of fragment can lead to instability and limitation of joint motion. Recently, a variety of arthroscopic assisted reduction and fixation technique have been used. In the tibial eminence fracture, we created an arthroscopic pull-out wire fixation technique using a cannulated screw that is easy and more convenient than in the conventional technique. So we report this technique with a review of current literatures.

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