• Title/Summary/Keyword: 동전기

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펄스동전기를 이용한 토양의 중금속 제거 기술 연구

  • Choi Chang-Sik;Kim Ho;On Ji-Won
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.128-130
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    • 2006
  • 충남 청양군에 위치한 삼광광산의 광미장에서 채취한 것을 사용하여 펄스전원을 이용한 동전기실험 결과 실험경과시간 약 200시간 안에 약 50%의 제거효율을 보여 직류전원을 이용한 동전기 실험보다 빠른 제거속도를 보였다. 또한 직류전원을 이용한 동전기 실험과 펄스전원을 이용한 동전기 실험의 시간당 투입된 전력량을 비교해 보면 각각 5.97W와 1.94W으로 이는 직류전원의 약 30%수준이어서 에너지 절약효과를 기대할 수 있다.

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Characteristics of Electrokinetic Remediation of Unsaturated Soil I : Experimental Study (불포화토의 동전기 정화 특성 I : 실험적 연구)

  • Kim, Byung Il;Han, Sang Jae;Kim, Soo Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1C
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    • pp.1-8
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    • 2006
  • The purpose of this study is to experimentally analysis the eletrokinetic phenomena and remediation characteristics developed during the application of electrokinetic remediation technique to unsaturated soils contaminated by heavy metals. In the laboratory a series of column tests are performed on degree of saturation for shooting range soil. The test results indicated that Pb is mainly removed under unsaturated conditions by electromigration within diffuse double layer, and if the initial containment concentration is below cation exchange capacity and equals to adsorption per unit soil solid weight, the remedial efficiency decreases with the decreasing of transport efficiency due to the changes in the degree of saturation in the electric gradient of 1V/cm.

Removal of Heavy Metal and Organic Substance in Contaminated Soils by Electrokinetic and Ultrasonic Remediation (동전기 및 초음파 복원기술에 의한 오염지반내의 중금속 및 유기오염물질 제거)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
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    • v.19 no.3
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    • pp.83-91
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    • 2003
  • The electrokinetic technique has been applied to remove mainly the heavy metal and the ultrasonic technique to remove mainly organic substance in contaminated soil. In this study, the combined electrokinetic and ultrasonic remediation technique was studied far the removal of heavy metal and organic substance in contaminated soils. This study emphasized the coupled effects of electrokinetic and ultrasonic techniques on migration as well as remediation of contaminants in soils. The laboratory soil flushing tests combining electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of both of these techniques. A series of laboratory experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants of heavy metal and organic substance. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of electrokinetic ultrasonic remediation technique.

A New Circulation Method for Electrokinetic Remediation of Soil Contaminated with Lead (새로운 순환방식을 적용한 동전기 정화기술에 의한 오염토양내의 납제거)

  • 이현호;백기태;양지원
    • Journal of Soil and Groundwater Environment
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    • v.8 no.1
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    • pp.9-16
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    • 2003
  • A new method has been proposed and developed that solves the problem of decreasing electroosmotic flow rate by excess $H^{+}$ and precipitation of heavy metal by $OH^{-}$. An electrolytic solution was circulated between the anode and cathode compartments that enabled the pH at the anode and cathode to be controlled. The change of the soil pH by circulation systems affects the operation time, by lowering the rate of increase of the electric potential gradient, and the removal efficiency of heavy metals, by affecting the soil pH. Since there was no effluent from the cathode compartment in circulation system, there was no need to treat the wastewater after the experiment, which resulted in the reduction of influent electrolyte volume.

Electrokinetic Extraction of Heavy Metal from Clayey Soil : Desorption Characteristics During Electrical Treatment (중금속으로 오염된 점성토에서 동전기프로세스에 의한 탈착 특성)

  • Lee, Myung-Ho;Jang, Yeon-Soo
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.23-28
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    • 2007
  • A number of batch isotherm and electrokinetic experiments were conducted in order to investigate the migration of zinc and its removal efficiency during electrokinetic soil processing. Sorption and desorption characteristics of zinc spiked kaolin clay have been examined by comparison with electrically induced desorption and precipitation occurring in the anode and cathode regions, respectively. The removal efficiency of zinc under the applied voltage gradient of 300 V/m was found to be up to approximately 80 % within 4 hours of the electrokinetic treatment. The study is significant with respect to the remediation of contaminated areas.

The Variation of Density and Settlement for Contaminated Sediments During Electrokinetic Sedimentation and Remediation Processes (오염퇴적토에 대한 동전기적 침전 및 정화 공정에서의 시료 밀도 및 침하 변화 특성)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
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    • v.22 no.9
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    • pp.5-14
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    • 2006
  • Generally, the sediments contain significant water, clay, colloidal fraction and contaminants, and can result in soft strata with high initial void, and its potential hazards in subsurface environments exist. Electrokinetic technique has been used in sedimentation for volume reduction of slurry tailing wastes and in remediation for extraction of contaminants from contaminated soils. In this research, the coupled effects of sedimentation and remediation of contaminated sediments are focused using electrokinetic sedimentation and remediation techniques from experimental aspects. A series of laboratory experiments including variable conditions such as initial solid content of the specimen, concentration level of the contaminant, and magnitude of applied voltage are performed with the contaminated sediment specimens mixed with ethylene glycol. Commercially available high specification Kaolin was used to simulate slurried sediment. From the test results, the settlement of specimen increases with increasing of applied voltage and decreasing of solid content and contamination level. The density of specimen increases due to settlement of specimen in the process of electrokinetic sedimentation and decreases due to extraction of organic contaminant in the process of electrokinetic remediation.

Feasibility Study on Acid-enhanced Electrokintic Remediation of Zn and Ni-contaminated Soil (Zn와 Ni로 오염된 토양의 산을 이용한 전처리 및 산순환 동전기 정화의 타당성 연구)

  • Park, Sung-Woo;Cho, Jung-Min;Ryu, Byung-Gon;Kim, Kyung-Jo;Baek, Ki-Tae;Yang, Jung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.17-22
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    • 2008
  • The feasibility of acid-enhanced electrokinetic remediation on zinc and nickel-contaminated soil was investigated in the laboratory. Simple extraction efficiency using 1M HCl was 24% for Zn and 9% for Ni, as a result, the acid washing is not effective to remove Zn and Ni from the soil. The effiencey of normal electrokinetic treatment during 28 days was less than simple soil washing. Catholyte circulation with a strong acid enhanced dramatically the removal of Zn and Ni and pretreatment of soil with acid increased more the removal. Based on the result, acid-enhanced electrokinetic remediation is effective to remove Zn and Ni from the contaminated soil.

Parametric Design of Contact-Free Transportation System Using The Repulsive Electrodynamic Wheels (반발식 동전기 휠을 이용한 비접촉 반송 시스템의 변수 설계)

  • Jung, Kwang Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.310-316
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    • 2016
  • We propose a novel contact-free transportation system in which an axial electrodynamic wheel is applied as an actuator. When the electrodynamic wheel is partially overlapped by a fixed conductive plate and rotates over it, three-axis magnetic forces are generated on the wheel. Among these forces, those in the gravitational direction and the lateral direction are inherently stable. Therefore, only the force in the longitudinal direction needs to be controlled to guarantee spatial stability of the wheel. The electrodynamic wheel consists of permanent magnets that are repeated and polarized periodically along the circumferential direction. The basic geometric configuration and the pole number of the wheel influence the stability margin of a transportation system, which would include several wheels. The overlap region between the wheel and the conductive plate is a dominant factor affecting the stiffness in the lateral direction. Therefore, sensitivity analysis for the major parameters of the wheel mechanism was performed using a finite element tool. The system was manufactured based on the obtained design values, and the passive stability of a moving object with the wheels was verified experimentally.

EDTA-Enhanced Electrokinetic Removal of Cu and Zn from Contaminated Sandy Soil (동전기 기술과 세척제 EDTA를 이용한 모래 토양으로부터 구리 및 아연의 제거)

  • Lee, Hyo-Sang;Hong, Soon-Myong;Ko, Sung-Hwan;Lee, Ki-Say
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.37-45
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    • 2002
  • EDTA-enhanced electrokinetic removal of copper and zinc from contaminated sandy soil was carried out. In desorption equilibrium tests, the required mass ratio of EDTA to metal was 10:1 to obtain over 90% of desorption from soil. The removal of heavy metals with chelating agent EDTA below pH 3 was limited because of EDTA precipitation. In electrokinetic experiments, the pH control at anode chamber was essential and 38% Cu and 56% Zn were removed under 30 mA for 1.5 days. Heavy metal removal was greatly improved by controlling anode and soil pH with circulation of anolyte with NaOH solution, in which >50% heavy metal was removed for 4 days and >70% for 9 days.

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Electrokinetic-Fenton Process for Removal of Phenanthrene (동전기-펜턴 공정을 이용한 phenanthrene 오염토양의 정화)

  • 양지원;박지연;김상준;이유진;기대정
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.47-53
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    • 2004
  • Feasibility of electrokinetic process combined with Fenton-like reaction was investigated for the removal of phenanthrene from contaminated soil. Transport of hydrogen peroxide by electroosmosis and decomposition of phenanthrene by Fenton-like reaction were observed in a model system. Electrical potential gradient and electroosmotic flow (EOF) at 10 mA were higher than those at 5 mA. High accumulated EOF resulted in high removal efficiency of phenanthrene because the large amount of hydrogen peroxide was transfered through the soil. Removal efficiency of phenanthrene by water washing was 8.5% for 7 days. The highest removal efficiency including phenanthrene decomposition was 95.6% for 14 days. After the operation, soil samples with removal efficiency of 95.6% showed low concentrations of phenanthrene and its intermediates. From this result, it was presumed that phenanthrene was decomposed to small molecules or mineralized to water and carbon dioxide due to continuous supply of hydrogen peroxide by electroosmotic flow.