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Electrochemical Characteristics of Fine Soils in the Application of Electrokinetic Remediation (동전기력 복원공정 적용에 따른 세립토양의 전기화학적 특성 변화)

고석오
- Journal of Soil and Groundwater Environment
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- v.7 no.3
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- pp.85-94
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- 2002
Overall objective of this study was to evaluate the electrochemical characteristics of fine soils during the electrokinetic(EK) remediation. Zeta potential of kaolinite as a function of solution pH and surfactant concentration was investigated to make a relationship with electroosmotic flow direction and rate. During the EK experiments, pH of pore solution, electroosmotic permeability($k_e$), electric conductivity($\delta_e$) and voltage distribution was measured, respectively, The point of zero charge(PZC) of kaolinite was estimated to be about 4.2 and the zeta potential of kaolinite above PZC was more negative as solution pH increased. Sorption of surfactants on the kaolinite altered the zeta potential of kaolinite. resulting from the variation of electrochemical characteristics of kaolinite surface. hs the EK experiment progressed, low pH was predominant over most of the kaolinite specimen and thus resulted in very low mass and charge flow. The $k_e$ and $\delta_e$ was also affected by the variation of voltage drop across the EK column with time. Results from this study implied that zeta potential of kaolinite affected by the pH variation of pore solution and voltage distribution in soil column played important role in the determination of mass and charge flow during EK process. It was also suggested that pH adjustment or addition of suitable sorbates could alter the electrochemical characteristics of soil surface and thus maintain high mass and charge flow rate with time.
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Kaolin 토양에 대한 동전기적 제염기술 적용 연구

원휘준;안병길;김계남;이철용;이병직;오원진
- Proceedings of the Korean Nuclear Society Conference
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- 1998.05b
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- pp.802-807
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- 1998
Cs$^{+}$ 이온으로 오염된 kaolin 토양에 대한 동전기적 토양제염 연구를 수행하였다. 실험실 규모의 제염장치를 제작하여 계의 pH, 전류 및 전압 변화를 측정하였으며 전압 변화에 따른 전기삼투 흐름속도의 변화와 산 전선의 이동속도 변화를 조사하였다. 일정시간에서, Cs$^{+}$ 이온의 제거량은 계에 걸어준 전압에 비례하여 증가하였고 실험으로부터 구한 본 계의 electroosmotic permeability coefficient (K$_{e}$)는 4.27 x $10^{-6}$ $\textrm{cm}^2$/V.S 이다.
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A Evaluation of Penny-shaped Flaw by Analyzing a Ultrasonic spectrum (초음파 스펙트럼분석에 의한 동전형 결함 탐상)

김흥기;전계석
- The Journal of the Acoustical Society of Korea
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- v.10 no.5
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- pp.46-50
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- 1991
고체내부에 존재하는 결함의 에이지에서 회절되는 반사신호의 스페그럼을 해석하여 결함의 크기 를 결정하는 방법을 연구하였다. 실험을 위하여 순도 99.99%의 알루미늄 재료를 샘플로서선택하고 표면 에서 20mm 깊이에 반경 3500μm, 높이 1000μm 의 동전형 결함을 제작하였다. 결함의 탐상은 피치-캐 치법으로 하였으며, 스펙트럼분석에 의한 결함의 기존의 펄스 반사법에 의한 측정값과 비교하였다.
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