• Journal of Adhesion and Interface
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• v.15 no.1
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• pp.22-30
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• 2014

Self-photoinitiating acrylate (SPIA) which can undergo self-initiation under UV irradiation was synthesized by a Michael addition in the presence of a base catalyst. The SPIA polymerizations were investigated by photo-differential scanning calorimeter (photo-DSC) and surface physical properties such as pendulum hardness and pencil hardness. The results showed that the SPIA can cure upon UV irradiation by itself without a photoinitiator. But we found out that both the curing rate and the conversion were too low for the self-curing reaction of SPIA. In order to improve the SPIA curing properties, we introduced the SPIA/cationic hybrid system and observed the effects of the addition of commercial free radical type monomer and photoinitiator on the curing behaviors. SPIA/cationic hybrid system was the best suitable to improve the SPIA curing properties. The kinetic analysis indicated that the cationic monomer and photoinitiator apparently accelerated the cure reaction and rate of the hybrid SPIA system, mostly due to the synergistic effect of cationic monomer and photoinitiator increasing the mobility of active species and the generation of reactive species (free radical, cation) during the photopolymerization process. The physical properties showed that, unlike typical free radical system, the hybrid systems did not show oxygen inhibition effect because of cationic reaction on the coating surface.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.5D
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• pp.483-492
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• 2012

The early setting time of concrete is an important factor determining the slip up velocity of the slip-form system. Accordingly, need is for a technique evaluating the early setting time in order to secure the safety of the slip-form system and the construction quality of concrete. This paper intends to estimate the early setting time by evaluating the setting degree of concrete using surface wave velocity so as to determine the slip up time of the slip-form system. Penetration resistance test and compressive strength test are performed first to clarify the relationship between the early setting time of concrete and the compressive strength. Then, compressive strength test and ultrasonic wave test are conducted to examine the relation between the compressive strength and the surface wave velocity. Continuous wavelet transform is adopted to measure the surface wave velocity. Numerical analysis is carried out to demonstrate the appropriateness of the application of continuous wavelet transform. Based on these results, the propagation velocity of the surface wave required for the slip up of slip-form system is suggested. Finally, a reduced model test of the slip-form system is conducted to verify the feasibility of the proposed surface wave velocity for the determination of th slip up velocity.

• Polymer(Korea)
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• v.33 no.4
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• pp.284-289
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• 2009

The morphology and mechanical properties of epoxy/polyamide/MPD reactive blends with various amount of polyamide were investigated. The cure behaviors, mechanical strengths, and morphological changes of the epoxy blend systems were analyzed by using DSC, UTM, and SEM, respectively. The amount of high soluble polyamide in epoxy ranged from 0 to 30 phr, and the cure reaction occurred at $170^{\circ}$ for 30 min. The start and maximum exothermic temperature in heat flows during cure reactions appeared at almost same temperature, indicating that soluble polyamide could rarely hinder the cure reactions. From the SEM images, it was found that the size of separated-phase was very fine about 100-300 nm, and at 20 phr of polyamide the boundary of separated-phase was unclear and the phase revealed co-continuous. By AP plasma treatment of specimen surface, the adhesion strength was increased by 20% due to enhanced surface free energy. By blending 20 phr of polyamide with epoxy, the adhesion strength was increased by 50% due to co-continuous phase in morphology. By considering the surface treatment of specimen and morphological tuning of the blends, it can be expected that the improvement in toughness and excellent adhesion strength can be achieved in structural adhesive systems.

• Journal of Korea Foundry Society
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• v.28 no.1
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• pp.41-44
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• 2008

레오다이캐스팅 공정은 용탕상태의 원소재로부터 최종형상에 가장 가까운 정형제품(near-net shape)을 원하는 기계적 성질과 동시에 경제적으로 생산할 수 있는 제조방법으로 개발되어 왔다. 본 논문에서는 전자교반 시스템을 이용하여 결정립이 제어된 반용융 상태의 소재를 수직형 다이캐스팅기를 사용하여 리어파트(rear parts) 자동차 부품을 성형실험 하였다. 성형된 시제품들은 성형조건에 따른 조직 및 인장강도를 관찰하였으며, 시효경화 시간에 따른 T6 최적 열처리 조건을 조사하였다.

• Proceedings of the Korean Society of Fisheries Technology Conference
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• 2001.10a
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• pp.339-340
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• 2001

이매패류의 의투막은 외부의 자극에 생물학적으로 처음 반응하는 기관계로서 자극을 외투강 기관계와 내장 기관계에 전달함과 동시에 외투강내의 모든 기관계를 이차적으로 보호하는 구조이다. 이매패류의 외투막은 자극수용, 외투강내 물질수송 및 패각형성 등 중요 기능을 가지고 있다 (Neff, 1972b; Wilbur, 1972, 1985; Machin,1977; Crrenshaw, 1980). 이매패류 외투막의 구조에 관해서는 Lyonsiidae의 일부 종(Prezant, 1981)과 Crassostrea (Morrison, 1993)등에 관한 일부 보고가 있을 뿐이다. (중략)

• Proceedings of the Korean Society of Fisheries Technology Conference
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• 2001.10a
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• pp.341-342
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• 2001

이매패류의 아가미는 호흡기능과 함께 점액분비 및 섬모운동 등을 통하여 먹이의 포획, 수송, 소화 기능을 동시에 수행하며 (Beninger et al., 1988). 외부의 물리ㆍ화학적 자극에 빠르게 반응하는 중요한 외투강 기관계이다. 따라서 이매패류 아가미의 구조, 점액분비세포와 섬모운동의 특성은 서식생태와 섭이생태에 따라 다양하므로 이들 아가미에 관한 연구는 주로 다양한 측면의 환경변화 및 섭이생태와 연관하여 수행되어져 왔다. (중략)

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.183-186
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• 2003

Long shafts for power transmission should transmit torsional load with vibrational stability. Hybrid shafts made of unidirectional fiber-reinforced composite and metal have high fundamental bending natural frequency as well as high torque transmission capability. However, thermal residual stresses due to the coefficient difference of thermal expansion of the composite and metal are developed so that the high residual stresses decrease fatigue resistance of the hybrid shafts, especially at low operating temperatures. In this work, axial compressive preload was given to the shaft in order to change the residual stresses. Static and fatigue torsional tests were performed and correlated with stress analyses with respect to the preload and service temperature.

• International Journal of Highway Engineering
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• v.8 no.1 s.27
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• pp.45-54
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• 2006

The Construction policy of government ever since 1970s have brought the economical growth, but has been causing environmental problems. Most roads were paved either asphalt concrete or portland cement concrete. These types of pavements has caused to rise temperature by making local heat islands in urban during summer time. Recently the wet-mixing solidified soil pavement, a kind of soil-cement, has developed and has been applied to the environment-oriented pavement. The solidified soil wet-mixed is placed on the subgrade along with asphalt concrete and portland cement concrete. Thermistors are laid in these field test pavements. The temperature gradients of these pavements are automatically measured with time. As the results of this test, the equation estimating surface temperature of pavement is proposed by analyzing measured temperature data. It is shown that the temperature change within the surface layer due to the change of air temperature is the greatest in the asphalt mixture and the least in the solidified soil mixture. Since it is proven that this wet-mixing solidified soil pavement emit less radiant heat than other existed pavements. Therefore this type of pavement can be successfully applied to the roads, such as walks, parkways, and bikeways, which are required to be human-friendly and environment-oriented.

• Composites Research
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• v.23 no.2
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• pp.31-39
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• 2010

In this paper, composite panels with hat-shaped stiffeners were made using the co-curing, co-bonding and secondary bonding methods. Co-curing is a manufacturing method in which the hat part and the plate are cured simultaneously in a manner that is more cost effective than other methods. Co-bonding is a method in which the stacked prepregs are cured with other cured parts, and secondary bonding is a method in which cured parts are bonded together using an adhesive. A rubber mold was manufactured for co-curing of composite panel with hat-shaped stiffeners, and finite element analyses were done to evaluate the expanding pressure of the rubber mold consistent with the curing temperature. The manufactured panels were also evaluated using a 3-D measurement tester and an ultrasonic tester. Pull-off tests were performed to evaluate their mechanical properties.

• Journal of Chest Surgery
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• v.36 no.5
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• pp.371-374
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• 2003

Atherosclerosis has more than 60% of the causes of arterial occlusive diseases. The abdominal aorta and lower extremity arteries are the most common sites of occlusion. We have treated surgically 2 cases who had intermittent claudication and were diagnosed as simultaneous aortobifemoral and bilateral femoropopliteal obstruction by angiography, but had ineffective results from medical treatment or angioplasty. Simultaneously aortobifemoral bypass using Hemashield Y graft and bilateral femoropopliteal bypass using autologous greater saphenous vein were done. After operations, the symptom disappeared and there were no specific post-operative complications except abdominal wound dehiscence. In postoperative angiography, we had obtained good patency of bypass graft. We are following up patients through the out patient department without recurrence up to 16 months.