• Title/Summary/Keyword: 동결특성

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Rheological Properties of Rehydrated Freeze Dried Instant Rice (동결건조 즉석미반의 리올로지적 성질)

  • Kim, Kwan-Yu;Lee, Shin-Young;Joo, Hyun-Kyu
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.332-337
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    • 1989
  • Rheological properties of rehydrated freeze dried instant rice were investigated in comparison with that of cooked rice. The time changes in reciprocal hardness of instant rice grains at various rehydration temperatures$(60{\sim}90^{\circ}C)$ could be expressed by the first order reaction rate equation regardless of rehydration temperature and reaction rate constant increased as the rehydration temperature increased. Activation energy for rehydrating instant rice was 6.1 kcal/g-mol. Analysis of compressive stress relaxation test showed that the viscoelastic properties of both rehydrated instant rice and cooked rice grains could be expressed by 6-elements generalized Maxwell model. Rehydrated instant rice revealed higher relaxation decay than that of cooked rice and showed the elastic property increased by increasing the rehydration temperature.

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PROPERTY CHANGES OF POLYMER ELECTROLYTE MEMBRANES WITH FREEZE/THAW CYCLES (동결/해동 조건에서 고분자막의 특성 변화 연구)

  • Park Gu-Gon;Lim Nam-Yun;Sohn Young-Jun;Park Jin-Soo;Lee Won-Yong;Kim Sae-Hoon;Lim Tae-Won;Kim Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.281-283
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    • 2005
  • Water management in polymer electrolyte membrane fuel cells(PEMFCs) is one of the most challenging issues. Freeze start-up in the automotive applications is also important research topic in the PEMFC field. Transportation of proton and separation of reactant gases are main roles of polymer electrolyte membranes. It has been known that water in the membrane conducts as a vehicle for the proton transportation. At sub-zero temperature, the frozen water blocks the access of reactant gases to the active sites of electrode as well as occurs the physical destruction of fuel cell structures. In this study, property changes of electrolyte membranes in the freeze conditions $(at\;-25^{\circ}C)$ were investigated. For the various amount of water contained membranes, the property changes, especially for the proton conductivity, were observed after several times of freeze/thaw$(-25\~80^{\circ}C)$ cycle.

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The Evaluation for Quality Characteristics of Drying Flowering Plant by Vacuum-Freeze (진공 동결에 의한 건조 화훼류의 품질특성 평가에 관한 연구)

  • Kim, J.D.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.5-10
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    • 2011
  • In case of using rapid vacuum-freeze drying for high quality dry flower of flowering plant, the morphological and physiological characteristics of dry rose showed as the following. The dry ratio of about 82% presented after 1 day in case of using rapid vacuum-freeze drying and it was reached that the optimum storage water content of general dry products was 18%. The dry ratio of about 89% presented after 4 days. This result indicates very short dry time comparing with natural dry time of 12 days. Also, the morphological characteristics of flowering plant in case of vacuum-freeze drying showed similar shape with real flower. The contraction decreased about 9% comparing with real flower under dry time of 72 hours. But the contraction in case of natural dry decreased 36% and showed noticeable difference. The brightness which affects physiological characteristics of dry flowering plant showed lower values according to the dry process and chromaticity was thick. After 4 days, natural dry was thick with about 2 times comparing with vacuum-freeze drying. In case of vacuum-freeze drying, the quantity of anthocyanin and chlorophyl which affect discoloration and bleaching of dry flowering plant showed the clear difference comparing with natural dry method due to the sublimation by vacuum after rapid freeze with short initial time.

A Study on the Heat and Mass Transfer Characteristics of Vacuum Freeze Drying Process for Porous Media (다공성 물길의 진공동결건조과정에서 얼 및 물질전달 특성에 관한 연구)

  • c. s. song
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.6
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    • pp.1341-1352
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    • 2001
  • Vacuum freeze drying process by which frozen water in a drying material is removed sublimation under vacuum condition, is now applied to various industrial field such as the manufacturing and packaging of pharmaceuticals in pharmaceutical industry, the drying of bio- products in bio-technology industry, the treatment of various quality food stuff in food technology, and so on. The Knowledge about the heat and mass transfer characteristics related with the vacuum freeze drying process is crucial to improve the efficiency of the process as well as the quality of dried products. In spite of increasing needs for understanding of the process, the research efforts in this fields are still insufficient. In this paper, a numerical code that can predict primary drying in a vial is developed based on the finite volume method with a moving grid system. The calculation program can handle the axis- symmetric and multi-dimensional characteristics of heat and mass transfer of the vial freeze drying process. To demonstrated the usefulness of the present analysis, a practical freeze drying of skim Milk solution in a vial is simulated and various calculation results are presented.

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Effect of Solidification Condition of Sublimable Vehicles on the Pore Characteristics in Freeze Drying Process (동결건조 공정에서 동결제의 응고조건이 기공특성에 미치는 영향)

  • Suk, Myung-Jin;Kim, Ji Soon;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.366-370
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    • 2014
  • The present study demonstrates the effect of solidification condition on the pore structure in freeze drying process using the slurries of CuO/sublimable vehicles. Camphene and Camphor-45 wt% naphthalene based slurries with 14 vol% CuO powder were frozen into a mold at $-25^{\circ}C$, followed by sublimation at room temperature. The green bodies were hydrogen-reduced and sintered at $500^{\circ}C$ for 1 h. The porous Cu specimen, frozen the CuO/camphene slurry into the heated mold of the upper part, showed large pores with unidirectional pore channels and small pores in their internal wall. Also, it was observed that the size of large pores was decreasing near the bottom part of specimen. The change of pore structure depending on the freezing condition was explained by the nucleation behavior of camphene crystals and rearrangement of solid powders during solidification. In case of porous Cu prepared from CuO/Camphor-naphthalene system, the pore structure exhibited plate shape as a replica of the original structure of crystallized vehicles with hypereutectic composition.

Analysis of the Phase Change Temperatures and the Latent Heat Characteristics of $H_2O$-NaCl Mixtures for the Cold thermal Energy Storage (냉축열을 위한 $H_2O$-NaCl 혼합물의 상변화 온도와 잠열 특성분석)

  • Song, H.K.;Ro, J.G.
    • Solar Energy
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    • v.19 no.2
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    • pp.57-65
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    • 1999
  • In this study $H_2O$-NaCl mixture was selected as a cold thermal storage material and its phase change temperature($liquid{\Leftrightarrow}solid$) was controlled with the molar concentration of NaCl. Ion dipole interaction mechanism and the fusion and crystallization structure of $H_2O$-NaCl were visualized with the low and high concentration of NaCl in the heating and cooling processes. In this study, the original cause of the appearance of two steps phase change period in heating and cooing processes were found by the visualization of the ion dipole interaction mechanism of $H_2O$-NaCl, and the theoretical equation of the phase change temperature variation in the NaCl high molar concentration was rearranged.

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Freeze-thaw of Durability for Premixed Fly Ash Concrete (프리믹스 플라이애시 콘크리트 동결-융해 특성)

  • Hong, Seung-Ho;Han, Seung-Hwan;Lee, Byung-Duk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.261-262
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    • 2009
  • The prevent methods of Alkali-Silica Reaction (ASR) are studying after the failure cases by ASR were reported in Korea. In this study, the freeze-thaw test and scaling test for premixed fly ash cement were performed. The ratio of fly ash and cement is 20 percent and 80 percent by weight of total cementious material. The results show that the dynamic modulus after 300 cycles the freeze-thaw test for most of specimen except the specimen have less 3% air was more than 90 % and the loss of weigh the specimen after 50 cycles scaling test was less than 1kg/$m^3$.

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Evaluation on Basic Properties of Crushed Sand Mortar in Freezing-Thawing and Sulfate Attack (동결융해와 황산염의 복합작용을 받는 부순모래 모르타르의 기초 특성 평가)

  • Kim, Myeong-Sik;Baek, Dong-Il;Choi, Kang-Seok
    • Journal of Ocean Engineering and Technology
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    • v.23 no.5
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    • pp.54-60
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    • 2009
  • Exposed to various environments, concrete confronts degradation by a lot of physical and chemical reaction. Though so many experiments and theorizations on the single condition of concrete degradation have been carried out by constant studies, the truth for now is that there are few studies on the compound phenomenon of degradation related with marine environments. Accordingly, this study measured the degree of degradation in the change of external shape, the change of unit weight and compressive strength, ultrasonic velocity test, and the change of length, etc. after exposing the specimen of cement mortar to the environment between 0 cycle and the maximum of 300 cycles under the condition of aquatic curing, freezing and thawing, and compound degradation, using mineral admixture effective for concrete degradation as a binder. The result indicated that the case of adding mineral admixture showed greater resistance than that of using OPC only, and specifically, the specimen with the additive of slag powder and three component system showed very excellent resistance to freezing and thawing, and compound degradation.

Non-Dimensional Analysis on the Ice-on-coil as a Static Ice Making Type (정적제빙형인 관외 제빙에 관한 무차원 정리)

  • Yu, Jik-Su;Kim, Myoung-Jun;Kim, Sung-Yong;Jang, Hyeon
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2011.06a
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    • pp.322-322
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    • 2011
  • 본 연구는 동관의 관외착빙형 특성을 조사하기 위한 기초적인 연구로써, 실험의 파라메터와 범위는 브라인의 온도는 -10[$^{\circ}C$], -8[$^{\circ}C$], -6[$^{\circ}C$], 브라인의 유속은1.0[m/s], 1.4[m/s], 1.8[m/s] 그리고물의 초기온도는6[$^{\circ}C$], 9[$^{\circ}C$], 12[$^{\circ}C$] 등으로 설정하였다. 본 논문에서는 무차원 얼음 두께와 무차원 동결 시간의 관계에 대하여 실험적으로 정리 하였다. 브라인온도, 물의 온도, 브라인 유속, 물의 초기온도, 동관의 직경사이즈에 대한 무차원 상관 방정식은 다음과 같이 얻어진다. r+3 = $0.063{\bullet}(t+)+0.206$ [적용범위: R+T+=2.1~4.7].

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Chemical Equilbrium Analysis of the $30\;ton_f$ - class KARI LRE Nozzle Flow (KARI 30톤급 액체 로켓 엔진 노즐 유동 화학 평형 해석)

  • Lee, Dae-Sung;Kang, Ki-Ha;Cho, D.R.;Choi, Jeong-Yeol;Choi, H.S.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.3
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    • pp.9-15
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    • 2008
  • Nozzle flow analyses of $30\;ton_f$-class KARI liquid rocket engine for high altitude propulsion are carried out using a chemically frozen and equilibrium flow analysis code developed previously. It is considered that the combined frozen- and shifting- equilibrium analysis is cost-effective regarding the convergence characteristics and modeling uncertainties, though the non-equilibrium analysis is most reliable approach. A dependable performance prediction could be attainable through the present analyses that account for the recombination process and thermal and kinetic energy recovery during the expansion process with viscous effects.