• Title/Summary/Keyword: 독성지수

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A Study on Combustion Gases Toxicity Evaluation of Polymeric Material (고분자재료의 연소가스 독성평가에 관한 연구)

  • 박영근
    • Fire Science and Engineering
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    • v.15 no.3
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    • pp.7-13
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    • 2001
  • In this paper, we had analyzed comsbustion gases according to pyrolysis $600^{\circ}c$, $800^{\circ}c$ and $1000^{\circ}c$ for polymeric material using a GASTEC colorimetric gas detector tube in order to combustion gases toxicity evaluation for flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam of polymeric material. As a result, comsbustion gases producted from small specimens of polymeric material had reached fatal to man at a 30 minute exposure time that had possesed toxicity index. Toxicity index at pyrolysis $800^{\circ}c$ of flexible polyvinyl chloride was 31.74. Flexible polyvinyl chloride was the highest toxicity index of flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam. The comsbustion gases producted commonly no concern with pyrolysis temperature had analyzed carbon dioxide($CO_2$) and carbon monoxide(CO). Toxicity index had investigated differently according to pyrolysis temperature even a similar materal.

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A Study on the Flame Retardant Performance and Toxicity of the Painting Wood Painted with Flame Retardant Solution (방염처리된 단청목재의 방염성능 및 유독성에 관한 연구)

  • Kim, In-Beom;Hyun, Seong-Ho
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.66-71
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    • 2009
  • In this study, I evaluated toxicity that analyze performance of flame-retardant about flame-retardant painting wood and combustion gas that is based on the toxicity index. Processing condition of flame retardant solution and treatment method of samples didn't affect greatly to performance of flame retardant. Occurrence of combustion gas showed a almost similar result from the sample which spraying flame retardant solution and toxicity corresponds to high level, Hazard Class III, and the flame retardant solution saturation sample which makes put out Hazard Class II which is a low toxicity relatively.

The Combustion Gases Toxicity Evaluation of Plastics Material by Colorimetric Gas Detector Tubes (가스검지관법에 의한 플라스틱재료의 연소가스 독성평가)

  • 박영근;김동일;현성호
    • Fire Science and Engineering
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    • v.16 no.4
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    • pp.77-84
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    • 2002
  • In this paper, we had analyzed comsbustion gases using a GASTEC colorimetric gas detector tube according to the method of NES 713 in order to combustion gases toxicity evaluation for beads polystyrene foam, extruded polystyrene foam, rigid polyurethane foam, flexible polyurethane foam, flexible polyvinyl chloride pipe, vinyl floor cover, polyethyelene foam(flame retardant untreated) and polyethyelene foam (flame retardant treated) of plastics material. As results of gas analyses by using this method, comsbustion gases producted from small specimens of plastics material had reached fatal to man at 30 minutes exposure time that had possesed toxicity index of more than 1. Toxicity indexes of each specimen were estimated range of 4.3∼179.2, flexible polyvinyl chloride showed the hightest toxicity index at 179.2, and beads polystyrene foams showed the lowest toxicity index at 4.3.

A Study on the Toxic Gases and Smoke Hazard of PASCON Trough (파스콘 트로프의 연기유독성에 관한 연구)

  • Lee, Chang-Woo;Hyun, Seong-Ho;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.20 no.2 s.62
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    • pp.1-7
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    • 2006
  • The aim of the research is to estimate the effect of smoke and combustion gases on humane body indirectly through measuring the toxicity of those. For this purpose, the toxic index of smoke and combustion gases was investigated by smoke hazard test and analysis of smoke which were conducted by KS F 2271 and NES 713 method respectively. It i s proved by KS F 2271 method that PASCON trough is suitable to the testing standard of interior material and construction of building. In addition, it is identified by NES 713 method that combustion gases occurring in PASCON product were only carbon dioxide and carbon monoxide, and the smoke index of those was 0.944. This value means that the hazard effect of smoke gases on humane ! body can possibly happens when exposed to the smoke gases for more than 30 min. In aspect of the domestic situation that have not regulated the hazard estimation and the emissions of smoke when the flame retarding ability of the products have been requested, the toxic indexes of PASCON products are comparatively low.

A Study on the Fire Risk of Car Interior Materials (자동차 내장재의 화재위험성에 관한 연구)

  • Lee, Hae-Pyeong;Kim, Young-Tak
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.82-88
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    • 2010
  • In this study, we have performed several tests for composite plastic materials to be applied on interior materials of a vehicle to identify their combustion characteristics using cone calorimeter, smoke density chamber and toxicity index chamber. We have prepared a total of 12 samples for 4 major parts of a vehicle wherein each major part has 3 different materials. The results of cone calorimeter test showed ignition time of PVC sheet and PVC leather were 2s. The 8 samples showed under less than 10s of ignition time. The sample comprising Nylon and PE had the biggest maximum heat release rate of 635 $kW/m^2$. The sample comprising Rubber showed the smallest maximum heat release rate but with the biggest total heat release. The results of smoke density chamber test showed the sample that is made up with Rubber had the biggest specific optical smoke density. The sample comprising PVC leather and PUR showed the biggest VOF4 which enables the initial smoke production. The results of toxicity index test showed that all samples contained carbon dioxide content exceeding its lethal concentration. The sample comprising PVC showed high content of hydrogen chloride and hydrogen bromide. The PVC sheet showed the biggest toxicity index calculated by using lethal concentration and test results. Toxicity index of all sample wes over 1.

Toxicity Assessment of Nanopariticles Based on Seed Germination and Germination Index (씨앗발아 및 발아지수에 근거한 나노입자 독성평가)

  • Gu, Bonwoo;Kong, In Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.6
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    • pp.396-401
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    • 2014
  • Nanomaterials have been widely used in many fields. This study investigates the effects of metal oxide nanoparticles (CuO, NiO, $TiO_2$, $Fe_2O_3$, $Co_3O_4$, ZnO) on germination and germination index (G.I.) of seeds, Lactuca and Raphanus. Under aqueous exposure, CuO on Lactuca shows the most significant impacts on activities compared to others, showing $EC_{50s}$ for germination and G.I. as 0.46 mg/L and 0.37%, respectively. The effects of nanoparticle phytotoxicity on seed Lactuca was much higher than that of Raphanus. In general, the toxicities on seed germination and germination index were as following orders : CuO > ZnO > NiO ${\gg}$ $TiO_2$, $Fe_2O_3$, $Co_3O_4$. No measurable inhibition was observed at 1,000 mg/L (maximum exposure concentration) of $TiO_2$, $Fe_2O_3$, $Co_3O_4$.

Potential Human Health and Fish Risks Associated with Hypothetical Contaminated Sediments Using a Risk Assessment Model ($TrophicTrace^{(R)}$) (위험평가모형($TrophicTrace^{(R)}$)을 이용한 가상 해양오염퇴적물의 쥐노래미와 인체 영향 예비평가)

  • Yang, Dong-Beom;Hong, Gi-Hoon;Kim, Kyung-Ryon
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.1
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    • pp.60-70
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    • 2011
  • The sediment removal index derived from the chemical contaminants, $CI_{HC}$, is currently in use to identify and define the spatial extent of the contaminated sediments in the sea. In order to analyze the sensitivity of the ecological and human risk associated with contaminated sediment, we evaluated five hypothetical contaminated sediments, whose $CI_{HC}$ values are identical but consisted of different contaminant contents, using $TrophicTrace^{(R)}$ model dedicated to evaluate sediment risk, against the resident greenling (Hexagrammos otakii) and humans by calculating No-Observed-Adverse-Effect-Level based Toxicity Quotient (NOAEL TQ) and Lowest-Observed-Adverse-Effect-Level based Toxicity Quotient (LOAEL TQ), and cancer risks and hazard indices (HI), respectively, based on the site conceptual model and exposure assumptions of fish ingestion to human receptor populations. NOAEL and LOAEL TQ values varied as much as a factor of 2 among 5 hypothetical sediments. Chemical element specific contribution to the carcinogenic risk and HI varied also greatly in these sediments. The reason for this significant dissimilarity in ecological and human risk stems from the different risk of each contaminant to the resident fish and human receptor. When the conceptual food web model is constructed for the target biological species for a given site, the ecological and human risk analysis considering trophic transfer of contaminants will add a ecosystem based tool for the management of contaminated sediments.

A Study on the Improvement of Risk Assessment Items and Index for Sunken Ship (침몰선박 위해도 평가항목 및 평가지수 개선에 관한 연구)

  • Lee, Seung-Hyun;Choi, Hyuek-Jin;Suh, Jae-Joon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.6
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    • pp.704-711
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    • 2015
  • In this study, we have conducted a survey of AHP technique through the ocean experts to derive new items and revise assessment items and indices for risk of sunken ships based on the survey results. As a result of the survey, two new items such as accident cause and tidal current are derived. And it shows that existing items such as toxic liquid substance, remaining oil and explosive gas which were evaluated as one group are desirable to be evaluated respectively. Accordingly, we analyze the indices of the new eleven assessment items adjusted from the existing seven assessment items. As a result, the indices are ordered by toxic liquid substance, possibility of leaking, explosive gas, carrying capacity of fuel oil, sensitivity of sea environment, marine traffic environment, cause of accident, tidal current, keel clearance, ship type, and ship size. Especially, as compared with the indices of existing assessment items, the indices of sensitivity of sea environment and possibility of leaking are higher and the index of keel clearance is lower.