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The Synthesis of Sodium (2-(2,6-Dichlorophenyl)Amino)Phenyl Acetate ((2-(2,6-디클로로페닐)아미노)페닐 아세트산나트륨의 합성)

  • Hwang, Sean-Won;Jeong, No-Hee;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.413-418
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    • 1994
  • The synthetic steps of sodium(2-(2, 6-dichlorophenyl)amino)phenylacetate were reduced and increased the yield in each steps. The synthetic process was composed to four steps and 2, 6-dichloroaniline and per catalyst in three lots in 80% yield. The steps of acylation and Friedel-Craft reaction were simplified successfully. The final product, diclofenac was obtained in 97% yield by hydrolyzing 1-(2,6-dichlorophenyl)-2-indolinone which was gained in third step with Claisen-solution.

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Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames (동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측)

  • 이정기;김상수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.8
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    • pp.1583-1594
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    • 1992
  • A numerical calculation on the flame structure and soot particle distribution in a coannular laminar diffusion flame was performed. Flame analysis model utilized basically flame sheet concepts, Shvab-Zel'dovich assumption, and one step overall irreversible reaction. It was also considered the variation of thermodynamics and transport properties, and the stagnation enthalpy was used for solving temperature field. Radiation was taken into account, since it has been found to be important in determining the flame temperature in sooty flames. For soot particle analysis, we adopted the coagulation, suface condensation, and the oxidation model in addition to tesner's two-step formation model. Equations for primary soot particle excluding the agglomeration process were solved. Based on the results, the regions of soot generation, growth, and oxidation in the flame have been observed and radiation strongly influenced flame temperature and soot distribution.

A Model of Pupil's Change with Luminance (Luminance에 의한 Pupil의 변화에 대한 모델)

  • Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.1 no.2
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    • pp.7-11
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    • 1996
  • The size of pupil with pupillary light reflex is determined by the amount of a luminance. and it is dependent with the distribution function of the retinal illuminance which is the amount of transmittance for the external light due to the size of pupil, and the detector of cone and rod due to the amount of the luminance. The change of the pupil size with the luminance can be expressed with the mathematical model $$y(x)={\alpha}+{\beta}\frac{1}{1+{e}{x}{p}(x-x_0)/{\theta}}$$ where ${\alpha}$ is the size of the pupil diameter in a maximum value of the luminance, ${\beta}$ is the deviation of the pupil's diameter between maximum and minimum, ${\theta}$ is the parameter showed the degree of a sensitivity. Comparing with the experimental value of P.Moon et al, We known that the equation of the model is very compatible.

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Inverse Model Parameter Estimation Based on Sensitivity Analysis for Improvement of PM10 Forecasting (PM10 예보 향상을 위한 민감도 분석에 의한 역모델 파라메터 추정)

  • Yu, Suk Hyun;Koo, Youn Seo;Kwon, Hee Yong
    • Journal of Korea Multimedia Society
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    • v.18 no.7
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    • pp.886-894
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    • 2015
  • In this paper, we conduct sensitivity analysis of parameters used for inverse modeling in order to estimate the PM10 emissions from the 16 areas in East Asia accurately. Parameters used in sensitivity analysis are R, the observational error covariance matrix, and B, a priori (background) error covariance matrix. In previous studies, it was used with the predetermined parameter empirically. Such a method, however, has difficulties in estimating an accurate emissions. Therefore, an automatically determining method for the most suitable value of R and B with an error measurement criteria and posteriori emissions accuracy is required. We determined the parameters through a sensitivity analysis, and improved the accuracy of posteriori emissions estimation. Inverse modeling methods used in the emissions estimation are pseudo inverse, NNLS (Nonnegative Least Square), and BA(Bayesian Approach). Pseudo inverse has a small error, but has negative values of emissions. In order to resolve the problem, NNLS is used. It has a unrealistic emissions, too. The problems are resolved with BA(Bayesian Approach). We showed the effectiveness and the accuracy of three methods through case studies.

A Study on the Effects of the Filter on Flow Pattern of the Traditional Gating System by the Water Modeling Experiment (수모델 실험을 이용한 전통 탕구계의 유동 양상에 미치는 필터의 영향 연구)

  • Hwang, Ho-Young;Nam, Cheol-Hee;Choi, Young-Sim;Hong, Jun-Ho
    • Journal of Korea Foundry Society
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    • v.36 no.6
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    • pp.208-214
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    • 2016
  • Casting defects, which are closely related to entrapped air bubbles and metallic oxides, occur very frequently in the casting process. Many researchers have shown that these defects can be reduced by adopting an appropriate gating system design. But, it is difficult for field engineers to identify a specific gating system that is more appropriate for their products. In this study, we tried to draw a comparison of gating system designs with and without ceramic foam filters. A ceramic foam filter was added to the horizontal runner just after the sprue to prevent air bubble generation and to reduce turbulence without change of the gating system design. To verify the effects of initial pouring velocity, the experiment was conducted with four different amounts of water volume in the reservoir. Results of the water modeling experiment applying the filter showed remarkably changed flow characteristics. Although the study confirmed that use of the filter may change the flow characteristics, it needs to be noted that only filter use alone cannot solve all the problems caused by a poorly designed gating system.

A study on the adaptive control of process parameters using torque for end milling operation in machining center (Machining Center에서 End Millirh할 때 Torgue에 의한 가공변수의 적응제어에 관한 연구)

  • 박천령;윤문철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.6
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    • pp.889-897
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    • 1986
  • The purpose of this study is to describe the strategy of machining process suitable for developing adaptive control with constraint of NC-machine tool. The algorithm that controls machining process parameters of every sampling time is established for the constraint of torque in machinig center. To prove this AC algorithm, manual AC-unit control test is used for simulating the on-line AC strategy control. Also machining tests are carried out on a CNC-machining center fitted with the ACC system and compared with the simulated results. The practical effectiveness of the ACC systems so discussed and the reduction of machining time are demonstrated with reference to typical models of cutting workpieces. As a typical model, taper and step geometry model are selected. The computer simulation results have a good agreement with the experimental observation and make it possible to develope a NC-machine tool with an on-line ACC system.

Appearance Pattern of Resin Canals in Pinus koraiensis and Larix kaempferi (잣나무와 일본잎갈나무 수지구의 출현형태)

  • Kim, Nam-Hun;Kwon, Sung-Min
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.1
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    • pp.1-6
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    • 2006
  • Radial variations of resin canals in Pinus koraicnsis and Larix kaempferi which were cultivated-commercial trees in Korea, were examined to understand the characteristics of wood with light microscopy. Both species showed significant differences in the number of vertical resin canals along the radial direction from pith to bark. In Larix kaempferi, the diameters of horizontal resin canals and the number of epithelial cells showed a clear variation in radial direction. Namely, significant differences in the characteristics of the resin canals and epithelial cells were found in juvenile and adult woods. Consequently, it was concluded that the characteristics of resin canals can he used to estimate the wood quality.

Design of Neural Network Controller Using RTDNN and FLC (RTDNN과 FLC를 사용한 신경망제어기 설계)

  • Shin, Wee-Jae
    • Journal of the Institute of Convergence Signal Processing
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    • v.13 no.4
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    • pp.233-237
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    • 2012
  • In this paper, We propose a control system which compensate a output of a main Neual Network using a RTDNN(Recurrent Time Delayed Neural Network) with a FLC(Fuzzy Logic Controller)After a learn of main neural network, it can occur a Over shoot or Under shoot from a disturbance or a load variations. In order to adjust above case, we used the fuzzy compensator to get an expected results. And the weight of main neural network can be changed with the result of learning a inverse model neural network of plant, so a expected dynamic characteristics of plant can be got. We can confirm good response characteristics of proposed neural network controller by the results of simulation.

Occurrence and Mineralogical Properties of Clay Minerals in the Gosari Pottery Stones Mine in Taebek, Kangweon-do (강원도 태백시 고사리도석광산에 산출하는 점토광물의 산상 및 특성)

  • 황진연;정윤영
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.2
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    • pp.97-110
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    • 1994
  • 고사리광산의 도석에는 다량의 석영과 함께 녹니석/스멕타이트 혼합층광물, 운도/스멕타이트 혼합층광물, 카오리나이트와 같은 점토광물이 산출한다. 이들 점토광물에 대해 주로 X-선회전분석과 화학분석 등을 이용하여 광물학적 특성을 검토하였다. 이 광산의 도석은 녹니석/스멕타이트 혼합층광물을 다량 함유하는 것이 특징으로 나타났다. 이 녹니석/스멕타이트 혼합층광물은 Li을 함유하는 돈바싸이트로 된 녹니석층과 바이델라이트에 가까운 스apr타이트층으로 구성된 혼합층구조를 이룬다. 이 곳에 산출하는 운모/스멕타이트 혼합층광물은 모두 약 15% 이하의 팽윤층을 포함하는 것으로 되어 있다.이 광산의 도석은 백악기의 유문암 및 유문암질 응회암이 열수변질작용을 받아 형성된 것으로 나타났다. 점토광물조합의 분포상태에 의해 대략적인 변질분대가 나누어진다. 중심부인 강변질대에서는 다량의 녹니석/스텍타이트 혼합층광물이 나타나며 카오리나이트가 수받되기도 한다. 그 외곽지역의 약변질대에서는 점토광물로서 운모/스멕타이트 혼합층광물이 주로 나타난다. 카오리나이트는 주로 열극이나 그 주위에 국부적으로 산출되는 경향이 있다. 이와 같은 변질광물의 산출상태로 볼 때 변질작용의 진행에 따라 운모/스멕타이트 혼합층광물이 먼저 형성된 후 이것의 일부가 녹니석/스맥타이트 혼합층광물 및 카오리나이트로 변화된 것으로 생각된다. 도 카오리나이트는 열수의 공급이 많은 열극부에서 녹니석/스멕타이트 혼합층 광물과 거의 동시기에 침전된 것으로 생각된다. 이 광산에서 산출하는 일부 운모/스멕타이트 혼합층광물은 후기의 변질작용에 의해 형성된 것도 포함된다.

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새로운 데이지 월드를 통한 생태계 변화에 관한 연구

  • Jo, Byeong-Gil;Gang, Sun-Yeong
    • 한국지구과학회:학술대회논문집
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    • 2010.04a
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    • pp.81-87
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    • 2010
  • This research aimed to find out the homeostatic temperature when there are various organisms. Also, this studies on the impacts the variety of organisms would make on the ecosystem when a species or a number of the species drastically decreases. For this, a new 'Daisyworld' was made. It had a greater variety of plants; and animals and microorganisms were added. This model had a circular ecosystem. It showed the temperature is well maintained when there are various organisms and that the restoration is faster when there are changes in the ecosystem.

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