• Fire Science and Engineering
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• v.28 no.3
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• pp.20-28
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• 2014

Effect of radiation models on the suppression limits in counterflow $CH_4$/air diffusion flame was numerically investigated with fundamental experiments for the numerical validation. $N_2$ and $CO_2$ were considered as extinguishing agents. The differences in extinguishing concentration between OTM and SNB radiation models which have different accuracy levels were examined. As a result, there is no considerable difference in extinguishing concentration for the $N_2$ dilution as the radiation models with different accuracy levels were used. As the $CO_2$ having strong radiative effect was diluted in the low strain flames, however, the radiation model with high predictive accuracy such as SNB should be used. In particular, the $CO_2$ dilution in fuel stream leads to the significant difference in extinguishing concentration between OTM and SNB models. Therefore, it is necessary that the radiation model should be reasonably chosen with the consideration of numerical accuracy and computational time for the prediction of extinguishing concentration.

• Fire Science and Engineering
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• v.26 no.4
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• pp.55-62
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• 2012

The suppression mechanisms of carbon dioxide ($CO_2$) as a representative fire suppression agent were revisited using a counterflow diffusion flame which could be applied the concept of a local application system. To end this, the low strain rate $CH_4$/air counterflow diffusions with $CO_2$ addition in either fuel or oxidizer stream were examined numerically using detailed-kinetic chemistry. Radiative heat loss due to radiating gas species including $CO_2$ added was considered by the optically thin model (OTM). As a result, the critical $CO_2$ volume fractions in the oxidizer stream required to extinguish the flame were in good agreement with the experimental data reported in the literature, while somewhat under-prediction was observed with $CO_2$ added in the fuel stream. The surrogate agents were adopted to estimate the quantitative contribution with changing in global strain rate ($a_g$) on the flame extinguishment among pure dilution effect, thermal effects including radiation heat loss and chemical effect due to the $CO_2$ fire suppression agent.

• Clean Technology
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• v.28 no.3
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• pp.238-248
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• 2022

The world is striving to transition to a carbon-neutral society. It is expected that using hydrogen instead of hydrocarbon fuel will contribute to this carbon neutrality. However, there is a need for combustion technology that controls the increased NOx emissions caused by hydrogen co-firing. Flameless combustion is one of the alternative technologies that resolves this problem. In this study, a numerical analysis was performed using the 1D opposed-flow diffusion flame model of Chemkin to analyze the characteristics of flameless combustion and the chemical reaction of methane-hydrogen fuel according to its hydrogen content and flue gas recirculation rate. In methane combustion, as the recirculation rate (K_v) increased, the temperature and heat release rate decreased due to an increase in inert gases. Also, increasing K_v from 2 to 3 achieved flameless combustion in which there was no endothermic region of heat release and the region of maximum heat release rate merged into one. In H₂ 100% at K_v 3, flameless combustion was achieved in terms of heat release, but it was difficult to determine whether flameless combustion was achieved in terms of flame structure. However, since the NOx formation of hydrogen flameless combustion was predicted to be similar to that of methane flameless combustion, complex considerations of flame structure, heat release, and NOx formation are needed to define hydrogen flameless combustion.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.129-136
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• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.65-72
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• 2006

Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.6
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• pp.768-773
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• 2014

In this study, experimental and numerical studies for the synthesis of carbon nanotube(CNT) in methane counterflow diffusion flame have been performed. Methane mixed with acetylene($C_2H_2$) was used as a fuel gas and ferrocene was used as a catalyst for synthesis of CNT. The major parameters was $C_2H_2$ mixing rate and mixing rates were 2 %, 6 %, and 10 %. Characteristics of CNT formation on grid were analyzed from SEM images. the chemical reaction mechanism adopted is GRI-MECH 3.0. Numerical results showed that flame temperature and CO mole fraction were increased with increasing acetylene mixing rate. Experimental results showed that the CNT synthesis in 2% acetylene mixture flame better than that of 6% and 10% acetylene mixture flames. It can be considered that 6% and 10% acetylene mixture flames generated the excessive carbon source and then it interrupted the supplement of the carbon source into ferrocene catalyst. It can be found that the supply of appropriate quantity of carbon source can make effect to synthesis of high purity of CNT.

• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.77-87
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• 1997

The axisymmetric Navier-Stokes model together with detailed chemical kinetics and variable transport properties has been applied to analyze the effects of the multidimensional flow on the flame characteristics in the nitrogen-diluted hydrogen counterflow nonpremixed flame. Computations are performed for two nozzle exit area-averaged velocities. Effects of multidimensional flow and strain rate on the near-extinction structure of the highly diluted hydrogen flames are discussed in detail.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.229-235
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• 2000

Soot formation characteristics in counterflow diffusion flames of ethylene/propane/nitrogen mixtures have been studied experimentally to investigate the soot formation mechanism. The effect of HACA reaction on PAH and soot growth has been experimentally investigated by using 2-D planar LII and PAH LIF techniques.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.323-324
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• 2012

Flammability limits of opposed flow diffusion flame in a narrow channel was investigated experimentally and theoretically. There were three different extinction modes corresponding to high strain rate (HSR), low strain rate (LSR) and dilution ratio (DR) limits. To investigate these limits, a theoretical study was followed by focusing on flow and heat transfer characteristics. Consequently, a dead space concept that has been used for premixed flames was important to reveal the heat loss mechanism in a narrow channel especially for LSR conditions even in the case of diffusion flames.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.10 s.253
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• pp.996-1002
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• 2006

Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified