• Title/Summary/Keyword: 대체석

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Janggunite, a New Mineral from the Janggun Mine, Bonghwa, Korea (경북(慶北) 봉화군(奉化郡) 장군광산산(將軍鑛山産) 신종광물(新種鑛物) 장군석(將軍石)에 대(對)한 광물학적(鑛物學的) 연구(硏究))

  • Kim, Soo Jin
    • Economic and Environmental Geology
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    • v.8 no.3
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    • pp.117-124
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    • 1975
  • Wet chemical analysis (for $MnO_2$, MnO, and $H_2O$(+)) and electron microprobe analysis (for $Fe_2O_3$ and PbO) give $MnO_2$ 74.91, MnO 11.33, $Fe_2O_3$ (total Fe) 4.19, PbO 0.03, $H_2O$ (+) 9.46, sum 99.92%. 'Available oxygen determined by oxalate titration method is allotted to $MnO_2$ from total Mn, and the remaining Mn is calculated as MnO. Traces of Ba, Ca, Mg, K, Cu, Zn, and Al were found. Li and Na were not found. The existence of (OH) is verified from the infrared absorption spectra. The analysis corresponds to the formula $Mn^{4+}{_{4.85}}(Mn^{2+}{_{0.90}}Fe^{3+}{_{0.30}})_{1.20}O_{8.09}(OH)_{5.91}$, on the basis of O=14, 'or ideally $Mn^{4+}{_{5-x}}(Mn^{2+},Fe^{3+})_{1+x}O_{8}(OH)_{6}$ ($x{\approx}0.2$). X-ray single crystal study could not be made because of the distortion of single crystals. But the x-ray powder pattern is satisfactorily indexed by an orthorhombic cell with a 9.324, b 14.05, c $7.956{\AA}$., Z=4. The indexed powder diffraction lines are 9.34(s) (100), 7.09(s) (020), 4.62(m) (200, 121), 4.17(m) (130), 3.547(s) (112), 3.212(vw) (041), 3.101(s) (300), 2.597(w) (013), 2.469(m) (331), 2.214(vw)(420), 2.098(vw) (260), 2.014 (vw) (402), 1.863(w) (500), 1.664(w) (314), 1.554(vw) (600), 1.525(m) (601), 1.405(m) (0.10.0). DTA curve shows the endothermic peaks at $250-370^{\circ}C$ and $955^{\circ}C$. The former is due to the dehydration: and oxidation forming$(Mn,\;Fe)_2O_3$(cubic, a $9.417{\AA}$), and the latter is interpreted as the formation of a hausmannite-type oxide (tetragonal, a 5.76, c $9.51{\AA}$) from $(Mn,\;Fe)_2O_3$. Infrared absorption spectral curve shows Mn-O stretching vibrations at $515cm^{-1}$ and $545cm^{-1}$, O-H bending vibration at $1025cm^{-1}$ and O-H stretching vibration at $3225cm^{-1}$. Opaque. Reflectance 13-15%. Bireflectance distinct in air and strong in oil. Reflection pleochroism changes from whitish to light grey. Between crossed nicols, color changes from yellowish brown with bluish tint to grey in air and yellowish brown to grey through bluish brown in oil. No internal reflections. Etching reactions: HCl(conc.) and $H_2SO_4+H_2O_2$-grey tarnish; $SnCl_2$(sat.)-dark color; $HNO_3$(conc.)-grey color; $H_2O_2$-tarnish with effervescence. It is black in color. Luster dull. Cleavage one direction perfect. Streak brownish black to dark brown. H. (Mohs) 2-3, very fragile. Specific gravity 3.59(obs.), 3.57(calc.). It occurs as radiating groups of flakes, flower-like aggregates, colloform bands, dendritic or arborescent masses composed of fine grains in the cementation zone of the supergene manganese oxide deposits of the Janggun mine, Bonghwa-gun, southeastern Korea. Associated minerals are calcite, nsutite, todorokite, and some undetermined manganese dioxide minerals. The name is for the mine, the first locality. The mineral and name were approved before publication by the Commission on New Minerals and Mineral Names, I.M.A.

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Memorials to the King and the Intellectual history in the Late Joseon Dynasty (상소(上疏)를 통해 본 조선후기 지식인의 재편 - 이경석·박세당 평가와 관련한 노론계의 상소를 중심으로 -)

  • Song, Hyok Key
    • (The)Study of the Eastern Classic
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    • no.59
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    • pp.121-156
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    • 2015
  • Memorials in Joseon Dynasty created a arena where the intellectual and political power met. This thesis traces the process of a certain political faction's rebuilding of the political structure of the elite groups by leading the intellectual controversies through memorials, especially those about the evaluations of Pak Setang(朴世堂) and I Gyeongseok(李景奭). This is what happened: Song Siyeol(宋時烈) submitted a memorial which disputed I Gyeongseok's petition, which provoked complete controversies around the memorials between Noron(老論) and Soron(少論). This led to the academic censorship against Sabyeonrok written by Pak Setang. The analysis of act of writing and submission of memorials by Noron and the role of the Kim Family of An-dong(安東 金門) specifically is the main topic here. The members of Soron ceaselessly criticized Song Siyeol, while the Kim Family strongly defended him. The trigger of the strife was a letter written by Kim Chang-Heup(金昌翕), a member of the Kim Family and the Kims played a significant role in the background during the process of political fights using memorials. The series of memorials criticized or supported certain political figure or his writings, but the opinions of Noron and Soron were directly opposite to each other. Even though the expressed difference was the result of the existing political factions, however, it also caused the new power structure of elite groups. The expressions and logics used in the arguments also have its significance. The Noron's memorials evaluated the contemporary people and their writings based on Chu-Hsi and Song Siyeol, who was regarded as a identical figure of Chu-Hsi. The arguments and writing strategies in this regard gained political strength enough to reorganize the intellectual society by changing alignment of political parties, and this led to the rebuilding of academic environment afterward.

A Study on the Elliptical Gear Design for Oval flowmeter (오발 유량계에 사용되는 타원형 기어 설계에 관한 연구)

  • Park, Jin Joo;Lee, Eung Seok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.8
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    • pp.1029-1033
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    • 2013
  • Elliptical gear is used as a rotor of oval flowmeter. The elliptical gear can assist water flow-rate measurement by the space of the elliptical shape. Presently, elliptical gears have been processed using hob tool imported from Japan. But if it were not for the technical cooperation with Japan company, the Elliptical gears can't be processed. The purpose of this study is developing a domestic technology for elliptical gears and overcoming the dependence of foreign technical skills. It will bring the import substitution effect. In case of pressure angle $20^{\circ}$, the elliptical gears have an interference of tooth. The increase of pressure angle makes the root of a tooth thick and the top of tooth thin. By results of this study, tooth of elliptical gear was designed and verified through the 2D and 3D simulation.

Development of Drought Vulnerability Index Using Trend Analysis (경향성 분석을 통한 가뭄취약성 지수의 개발)

  • Yang, Jeong-Seok;Park, Jin-Hyuck;Kim, Nam-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.3B
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    • pp.185-192
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    • 2012
  • Drought vulnerability index was developed by selecting drought-related indicators with trend test. Study areas were determined by considering the weir locations from the four major rivers restoration project in Nakdong and Geum river watersheds. Ten indicators were selected and they were categorized into three groups, water resources, precipitation pattern, and social aspects. Annual average surface water level, annual minimum surface water level, annual average groundwater level, and annual minimum groundwater level data sets were collected for water resources aspects. The number of non-rainy days, rainfall concentration ratio, and rainfall deviation were considered for precipitation pattern category. The amount of water available per capita, financial soundness for water resources, and water usage equity were related to social aspects. Mann-Kendall, Hotelling-Pabst, and Sen trend tests were performed for the ten indicator data sets and the results were scored for the drought vulnerability index. The results shows Gumi, Sangjoo, and Hapcheon weirs are relatively vulnerable to drought. The indices were relatively low for the regions in Geum river watershed compared to those in Nakdong river watershed.

Study on Pre-treatment & Saccharification of Rice straw for Bioethanol Production (볏짚으로부터 바이오에탄올 생산을 위한 전처리 및 당화 연구)

  • Lee, Joonpyo;Park, Jiyeon;Kim, Deogkeun;Lee, Jinsuk;Park, Soonchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.104.2-104.2
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    • 2010
  • 농산 부산물인 볏짚을 이용하여 수송연료인 휘발유를 대체할 수 있는 바이오에탄올을 생산하기 위한 전단계인 전처리와 당화에 대한 연구를 수행하였다. 볏짚은 농산 부산물 중에서 비교적 발생량이 많으며, 목질계 바이오매스에 비해 소프트하기 때문에 전처리가 용이하다는 장점이 있다. 전처리 방법으로는 여러 가지가 있으나, 본 연구에서는 증기폭쇄에 의한 전처리 방법을 채택하였다. 당화실험은 생물학적 방법인 효소당화를 하였다. 전처리 실험결과 온도가 낮고 처리 시간이 짧을수록 고형물 및 삼성분에 대한 수율이 높은 것으로 나타났다. 삼성분 중의 Glucan 수율은 $180^{\circ}C$ 실험에서 68-71%를 보였으며, $200^{\circ}C$ 실험에서는 59-64%를 보였다. Xylan은 거의 대부분이 소실되어 Xylan을 회수하는 전처리로써는 적합하지 않은 방법으로 나타났다. 반면 Lignin은 거의 제거가 되지 않았다. 당화 실험결과 $180^{\circ}C$에서 전처리한 폭쇄재는 당화 수율이 50%에도 미치지 못하였으나, $200^{\circ}C$에서 전처리한 폭쇄재는 70% 내외를 보여 주었다. 특히 분쇄 세척 멸균한 효소당화 수율은 90%가 넘는 높은 수율을 보였다. 전처리 수율과 당화수율을 종합하여 수율을 분석한 결과 $200^{\circ}C$ 전처리 실험조건에서 효소당화시 미처리 시료와 분쇄 세척 시료보다 멸균까지 실시한 조건에서 Glucan의 종합수율이 55% 내외로 월등히 높은 것으로 나타났다. 증기폭쇄에 의한 볏짚의 전처리는 Glucan의 수율이 낮아 손실이 많은 것으로 나타났으며, 이를 보완할 수 있는 전처리 조건 혹은 다른 전처리 방안이 요구된다.

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Irradiance Distribution Analysis of a Squid Jigging Vessel Using an LED Plus Metal Halide Fishing Lamp Combination Under Optimized Conditions (메탈할라이드와 엘이디 오징어 집어등의 겸용시 배치조건에 따른 수중조도분포 비교분석)

  • Jung, Mee Suk;Lee, Ki Dae;Ko, Jae Seok;Bae, Jae Hyun
    • Korean Journal of Optics and Photonics
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    • v.25 no.6
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    • pp.315-325
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    • 2014
  • A combination of MHL and LED fish-luring light is used in this study. Its yield, characteristics, and irradiance distribution are evaluated and analyzed. To obtain an irradiance distribution similar to that of an MHL, we suggest the optimal arrangement of MHL and LED.

The Correlation between the Precipitation considering Critical Infiltration and Groundwater Level in Ssangchun Watershed (한계침투링을 고려한 쌍천유역의 강수량과 지하수위의 상관관계)

  • Yang Jeong-Seok;Lim Chang-Hwa;Park Jae-Hyeon;Park Chang-Kun;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.3
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    • pp.303-307
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    • 2005
  • Severe drawdown of Groundwater level(CWL) is observed from the analysis of the relationship between precipitation and CWL data during dry seasons in Ssangchun watershed. For Ssangchun watershed, the correlation was the strongest when we apply 70 day Moving Average(MA) for Groundwater dam Operation Index(COI) calculation. To determine the critical infiltration, which is the spatially averaged maximum daily infiltration, a certain value is fixed as the maximum infiltration and precipitation data is modified. COI is recalculated after the data modification and the correlation between COI and GWL is checked. The critical infiltration is determined when the best correlation is obtained after we repeat the above procedure with different fixed values. The critical infiltration is 40m for Ssangchun watershed. The correlation between CWL and COI is higher when we consider critical infiltration than we neglected it.

Effect of the Pore Structure on the Anodic Property of SOFC (SOFC 음극의 기공구조가 음극특성에 미치는 영향)

  • 허장원;이동석;이종호;김재동;김주선;이해원;문주호
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.86-91
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    • 2002
  • Solid Oxide Fuel Cells (SOFC) are of great interest of next generation energy conversion system due to their high energy efficiency and environmental friendliness. The basic SOFC unit consists of anode, cathode and solid electrolyte. Among these components, anode plays the most important role for the oxidation of fuel to generate electricity and also behaves as a substrate of the whole cell. It is normally requested that the anode materials should have the high electrical conductivity and gas permeability to reduce the polarization loss of the cell. In this study, the effect of pore former on the microstructure of anode substrate was investigated and thus on the electrical conductivity and the gas permeability. According to the results, microstructure and electrical conductivity of anode substrate were greatly influenced by the shape of pore former and especially by the anisotrpy of the pore former. The use of anisotropic pore former is supposed to deteriorate the cell performance by which the electrical conduction path is disconnected but also the effective gas diffusion path for the fuel is reduced.

Procedural Model of XML Schema Framework for Digitalizing Disaster Information Management for Construction Facility (시설물 재해정보관리 전자화를 위한 XML스키마 구축 방법의 절차적 모형 구성)

  • Kang, Leen-Seok;Park, Seo-Young;Moon, Hyoun-Seok
    • Korean Journal of Construction Engineering and Management
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    • v.7 no.3 s.31
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    • pp.56-64
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    • 2006
  • The current disaster management manual is being utilized as a book or document-based type. It causes a low applicability and interoperability in practical business because each information has a different document format and it is difficult to recycle those information as common disaster information. The information reading by text type without electronic data and visual object also has a limitations in guaranteeing a quickness of disaster management business. Accordingly, the electronic document management system with visual information is necessary and the system needs to tie framed by XML schema because the electronic document standard will be changed from DTD to XML schema. This study attempts to develop a procedural methodology of an electronic document management system based on XML for disaster management. The applicability of the proposed results is verified by the simulated scenario.

Estimation of Cycle Time for Construction Process of NATM Tunnel by using RFID Technology (RFID기술을 이용한 NATM터널 작업 프로세스의 사이클타임 산정방안 연구)

  • Park, NamJin;Kim, HyounSeung;Moon, HyounSeok;Kang, LeenSeok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1D
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    • pp.41-49
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    • 2012
  • Radio Frequency Identification(RFID) technology, which replace BAR CODE technology that has been widely utilizing in the field of the manufacturing industry for a long time, has been proven in the whole industries including national defense, transportation, and construction as well as manufacturing industry. Recently, with this trend, researches for adapting the RFID technology have been attempting continually centering on the architectural project in the construction industry. However, those researches are mainly focusing on the experimental utilization such as simple activity and material management. To solve these issues, this study demonstrated methodologies for adapting the RFID technology by the construction steps aiming to analyze cycle time of five types of construction process to the NATM method of tunneling work. Besides, the application of RFID technology in civil engineering work was verified by demonstrating the suggested methodology to actual sites. Therefore, it is expected that the suggested methodology will be utilized for predicting the progress rate and establishing of follow-up work plans, and the site applicability of the RFID technology will be expanded to the civil engineering projects.