• Title/Summary/Keyword: 대기오염 물질

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Development of a Deep Learning-based Midterm PM2.5 Prediction Model Adapting to Trend Changes (경향성 변화에 대응하는 딥러닝 기반 초미세먼지 중기 예측 모델 개발)

  • Dong Jun Min;Hyerim Kim;Sangkyun Lee
    • The Transactions of the Korea Information Processing Society
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    • v.13 no.6
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    • pp.251-259
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    • 2024
  • Fine particulate matter, especially PM2.5 with a diameter of less than 2.5 micrometers, poses significant health and economic risks. This study focuses on the Seoul region of South Korea, aiming to analyze PM2.5 data and trends from 2017 to 2022 and develop a mid-term prediction model for PM2.5 concentrations. Utilizing collected and produced air quality and weather data, reanalysis data, and numerical model prediction data, this research proposes an ensemble evaluation method capable of adapting to trend changes. The ensemble method proposed in this study demonstrated superior performance in predicting PM2.5 concentrations, outperforming existing models by an average F1 Score of approximately 42.16% in 2019, 58.92% in 2021, and 34.79% in 2022 for future 3 to 6-day predictions. The model maintains performance under changing environmental conditions, offering stable predictions and presenting a mid-term prediction model that extends beyond the capabilities of existing deep learning-based short-term PM2.5 forecasts.

A Study on Application of Desulfurization Technology in Cement Production Process (시멘트 생산 공정 내 탈황기술 적용 가능성 연구)

  • Youmin Lee;Chae-wook Lim;Teawoo Lee;Hyung-Suhk Suh;Jun-Ho Kil
    • Resources Recycling
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    • v.33 no.2
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    • pp.3-15
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    • 2024
  • Environmental awareness is rising worldwide. however, cement manufacturing facilities use recycled resources to improve raw material and fuel substitution rates, contributing to environmental issues such as waste disposal. The emission of sulfur oxides (SOx), an air pollutant, has been regulated by limestone as raw material in cement manufacturing. However, the impact of increasing use of recycled resources on future facility processes and environmental changes is unclear. Therefore, the cement manufacturing facilities require desulfurization-related technologies and research. In this study, we investigated the applicability of desulfurization technology to cement manufacturing facilities and demonstrated various approaches to applying this technology using byproducts generated in cement manufacturing.

Exposure and Risk Assessments of Multimedia of Arsenic in the Environment (환경 중 비소의 매체통합 노출평가 및 위해성평가 연구)

  • Sim, Ki-Tae;Kim, Dong-Hoon;Lee, Jaewoo;Lee, Chae-Hong;Park, Soyeon;Seok, Kwang-Seol;Kim, Younghee
    • Journal of Environmental Impact Assessment
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    • v.28 no.2
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    • pp.152-168
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    • 2019
  • The element arsenic, which is abundant in the Earth's crust, is used for various industrial purposes including materials for disease treatment and household goods. Various human activities, such as the disposal of soil waste, metal mining and smelting, and combustion of fossil fuels, have caused the pollution of the environment with arsenic. Recently, guidelines for arsenic in rice have been adopted by the Korean ministry of food and drug safety to prevent health risks based on rice consumption. Because of the exposure to arsenic and its accumulation in the human body through various channels, such as air inhalation, skin contact, ingestion of drinking water, and food consumption, integrated multimedia risk assessment is required to adopt appropriate risk management policies. Therefore, integrated human health risk assessment was carried out in this study using integrated exposure assessment based on multimedia (e.g., air, water, and soil) and multi-route (e.g., oral, inhalation, and dermal) scenarios. The results show that oral uptake via drinking water is the most common pathway of arsenic into the human body, accounting for 57%-96% of the total arsenic exposure. Among various age groups, the highest exposures to arsenic were observed in infants because the body weight of infants is low and the surface areas of infant bodies are large. Based on the results of the exposure assessment, the cancer and non-cancer risks were calculated. The cancer risk for CTE and RME is in the range of 2.3E-05 to 6.7E-05 and thus is negligible because it does not exceed the cancer probability of 1.0E-04 for all age groups. On the other hand, the cancer risk for RME varies from 6.4E-05 to 1.8E-04 and from 1.3E-04 to 1.8E-04 for infants and preschool children, exceeding the excess cancer risk of 1.0E-04. The non-cancer risks range from 5.4E-02 to 1.9E-01 and from 1.5E-01 to 6.8E-01, respectively. They do not exceed the hazard index 1 for all scenarios and all ages.

Screening test of commercial catalysts for direct synthesis of Dimethyl ether from syngas produced using coal and waste (석탄 및 폐기물로부터 생산된 합성가스로부터 Dimethyl ether의 직접합성을 위한 상용촉매 스크린테스트)

  • Kim, Eun-Jin;Han, Gi-Bo;Park, No-Kuk;Ryu, Si-Ok;Lee, Tae-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.689-692
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    • 2005
  • 2020년까지 전 세계 수송에너지의 수요가 현재의 2배까지 증가할 것으로 예상되면서 석유 자원의 안정적 공급이 어려워지기 이전에 이를 대체할 수 있는 에너지원 개발이 시급하다. 이러한 노력의 일환으로 최근 들어 대두되고 있는 가스화용융 기술은 석탄 폐기물 등으로부터 합성가스를 생산하는 고청정 고효율 기술이다. 여기에서 생산되는 합성가스는 천연가스를 대체하여 전기 및 화학원료를 생산하기 위한 원료로 이용 가능하다. 폐기물로부터 가스화용융기술을 통하여 생산되는 합성가스로부터 DME(dimethyl ether)를 생산할 수 있다. 가스화용융기술로부터 생산되는 합성가스는 자체의 일산화탄소와 수소의 조성비가 DME를 합성하는데 적당하다고 알려져 있다. DME는 에너지원의 다원화와 대기오염 물질의 저감, 지구온난화 대응 등과 아울러 제 4세대 수송 연료로 부각되고 있다. DME를 합성하는 방법은 합성가스로부터 메탄올의 합성 단계를 거친 후 DME를 합성하는 간접법과 단일단계의 반응에서 합성가스로부터 직접적으로 DME를 합성하는 직접법이 있다. 현재는 화학 평형적 측면 경제적 측면에서 이점을 가지고 있는 직접법에 관한 연구가 활발히 이루어지고 있다. DME 직접합성법에서는 메탄올 합성 촉매와 메탄올 탈수촉매의 물리적 혼합에 의한 혼성촉매가 주로 이용되고 있는 것으로 알려져 있다 본 연구에서는 일산화탄소와 수소로 이루어진 합성 가스로부터 직접 DME를 생산할 수 있는 직접 합성 공정에 적용 가능한 고효율 촉매 기술을 개발하기 위해 상용촉매의 스크린 테스트를 수행하였다. 상용촉매로는 sud-chemi사에서 메탄을 합성 촉매와 탈수촉매를 각각 구입하였으며, 이들 촉매를 원하는 조성비로 물리적으로 혼합한 다음 반응온도 ($250-290^{\circ}C$) 압력 (30-50 atm), $H_2$/CO 몰비 (0.5-2.0) 등의 다양한 반응조건 하에서 스크린 테스트를 수행하였다.대장조영영상을 얻을 수 있어 대장암의 위치에 관한 정보를 삼차원적으로 제공하므로 대장암의 성상을 정확히 알 수 있는데 도움을 주었다.요인은 없는 것으로 사료된다. 이 중 2예의 CT에서 선상 혹은망상형의 음영을 보였다. 결론: 유방암 환자의 방사선 치료 후 CT 소견은 방사선 치료의 방법에 따라 폐첨부 혹은 폐의전면 흉막하 부위에 선상 혹은 망상형의 음영으로서 방사선 폐렴 혹은 섬유화 소견이다. CT는 단순 흉부 촬영보다 이상 소견의 발견이 쉽다.이러한 소견은 후에 합병될 수 있는 다른 폐질환의 감별 진단에 도움이 될 것으로 보인다.moembolization via the radial artery approach were involved in this study. All underwent Allen’s test to check ulnar arterial patency. In all cases, we used the radial approach hepatic artery (RHA) catheter designed by ourselves, evaluating t\ulcorner selec\ulcorneron ability of the hepatic artery using an RHA cathter, the number of punctures, the procedure time, and compression time at the puncture site as well as complications occurring during and after the procedure. Results: Except for three in which puncture failure, brachial artery variation or hepatic artery variation occurred, all procedures were successful. The mean number of punctures was 3.5, and the

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Evaluation on Indoor Air Quality by Statistical Analysis of Indoor Air Pollutants Concentration in a Seoul Metropolitan Underground Railway Station (서울시 지하역사 실내오염물질 농도자료의 통계분석을 통한 실내공기질 특성 평가)

  • Yim, Bongbeen;Lee, Kyusung;Kim, Jooin;Hong, Hyunsu;Kim, Jangwon;Jo, Kyung-Ho;Jung, Eulgyu;Kim, Inkyu;An, Yeonsun
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.3
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    • pp.233-244
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    • 2014
  • The objective of this study was to explore the characteristics of concentration of indoor air pollutants, such as $PM_{10}$, $CO_2$, and $NO_2$, measured by tele-monitoring system in a Seoul Metropolitan underground railway station from January 1, 2008 to December 31, 2012. The annual average concentration of indoor air pollutants actually varied over a wide range and was found to exhibit marked variation with time and measurement sites (tunnel inlet, platform, and concourse). After installing platform screen doors, the average $PM_{10}$ concentration on platform and concourse was decreased by 43.8% and 31.2%, respectively during the study periods. The relationship between the concentration of $PM_{10}$ and meteorological parameters (relative humidity and rainfall) or the Asian dust events was regarded as statistically significant. The correlations between the number of boarding/alighting passengers and $PM_{10}$, $CO_2$, and $NO_2$ were calculated. A p-value of less than 0.01 was regarded as significant except $NO_2$. The I/O ratio of $PM_{10}$ concentration was elevated after a congested time (about 08:00 am). The average I/O ratios of $NO_2$ were observed in concourse and platform on 03:00 am with $1.76{\pm}0.91$ and $1.50{\pm}0.51$, respectively. The average daily variation of standard excess rate of $PM_{10}$ and $NO_2$ concentration in concourse and platform was investigated. The highest standard excess rate was observed on 21:00 (09:00 pm).

Decomposition of Toluene over Transition Metal Oxide Catalysts (전이금속 산화물 촉매를 이용한 톨루엔 분해)

  • Cheon, Tae-Jin;Choi, Sung-Woo;Lee, Chang-Seop
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.651-656
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    • 2005
  • Toluene, which is emitted from textile process, is considered as an important hazardous air pollutant. In this study, the catalytic activity of transition metal oxides(Cu, Mn, V, Cr, Co, Ni, Ce, Sn, Fe, Sr, Cs, Mo, La, W, Zn)/${\gamma}-Al_2O_3$ catalysts was investigated to carry out the complete oxidation of toluene. The metal catalysts were characterized by XRD-ray diffraction), FE-SEM(Field Emission Scanning Electron Micrograph), BET(Brunauer Emmett Teller) method and TPR(Temperature Programmed Reduction). Among the catalysts, Cu/${\gamma}-Al_2O_3$ was highly promising catalyst for the oxidation of toluene. From the BET results, it seems that the catalytic activity is not correlated to the specific surface area. XRD results indicated that most of catalysts exist as amorphous phase. From the FE-SEM results, it was observed that copper on ${\gamma}-Al_2O_3$ surface was well dispersed among catalysts. The catalytic activity for the toluene oxidation could be explained with that metal oxide catalyst was dispersed well over supports and was attributed to reduction activity in surface of catalysts.

On-Road Investigation of PM Emissions of a City-Buses Fuelled by Diesel, CNG, and LPG Using a Mobile Emission Laboratory (이동형 배출가스 측정시스템(MEL)을 이용하여 디젤, CNG, LPG 시내버스에서 배출되는 입자상 물질 평가)

  • Lee, Seok-Hwan;Kim, Hong-Suk;Park, Jun-Hyuk;Yoon, Jun-Kyu
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.409-416
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    • 2011
  • A mobile emission laboratory (MEL) was designed to measure the amount of traffic pollutants with high temporal and spatial resolution under real conditions. Equipment for gas-phase measurements of quantity of CO, NOx, $CO_2$, and THC and for the measurement of the number density and size distribution of fine and ultra-fine particles by a FMPS and a CPC were placed in a mini-van. The exhaust of different type of vehicles can be sampled by MEL. This paper describes the construction and technical details of the MEL and presents data from the experiment in which a car chases city buses fuelled by diesel, CNG, and LPG. The diameters of most particles in the exhaust of the diesel city bus were less than 300 nm and most of the particles had a diameter of 30-60 nm. However, most particles in the exhaust of the CNG and LPG city buses were nanoparticles (diameter: less than 50 nm).

Fabrication of Electrospun PAN/FA Nanocomposites and Their Adsorption Effects for Reducing Volatile Organic Compounds (전기방사에 의한 PAN/FA 나노 복합재의 제조 및 휘발성 유기 화합물에 대한 흡착효과)

  • Ge, Jun Cong;Wang, Zi Jian;Yoon, Sam Ki;Choi, Nag Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.702-708
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    • 2018
  • Volatile organic compounds (VOCs), as a significant air pollutant, is generated mainly from the burning of fossil fuels, building materials using painting, etc. The inhalation of a certain amount of VOCs can be deleterious to human health, e.g., headaches, nausea and vomiting. In addition, it can also cause memory loss and even increase the rate of leukemia. Therefore, as one of the methods for reducing VOCs in air, polyacrylonitrile/fly ash (PAN/FA) composite nanofibrous membranes were fabricated by electrospinning. To observe their VOCs adsorption capacity, the morphological structure of PAN/FA nanofibrous mats was investigated by field emission scanning electron microscopy (FE-SEM), and the VOCs (chloroform, benzene, toluene, and xylene) adsorption capacity of PAN/FA membranes were tested by gas chromatography/mass spectrometry (GC/MS). The results indicated that the PAN nanofiber containing 40 wt. % FA powder had the smallest fiber diameter of 283 nm; they also showed the highest VOCs adsorption capacity compared to other composite membranes.

Characteristics of long-term behavior of VOC species in Korea - PAMS data analysis (우리나라 휘발성유기화합물 화학종의 장기 거동 특성 - 광화학오염물질 측정자료 분석)

  • Park, Ji Hoon;Kang, Soyoung;Song, In-Ho;Lee, Dong-Won;Cho, SeogYeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.56-75
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    • 2018
  • Korean Photochemical Assessment Monitoring Stations (PAMS) have been established since the late 2001 to monitor ambient air concentrations of VOC species, which would enhance understanding photo-chemical formation of ozone and subsequently contribute to developing efficient ozone control strategies. The present study aims at identifying major VOC species and examining their trends by analyzing PAMS monitoring data collected from the year 2006 to 2016. All the 18 PAMS sites operated by the Ministry of Environment were included in the study. PAMS monitored the 56 target VOC species, which are classified into four groups, alkenes, lower alkanes ($C{\leq}3$), higher alkanes ($C{\geq}4$), aromatics. The higher alkanes and aromatics dominated over the lower alkanes and alkenes in the type 2 and 3 PAMS sites except Joongheung site. N-butane was a major alkane species, toluene was a major aromatic species and most of VOCs showed decreasing trends in these sites. On the other hand, only the alkenes showed decreasing trends at the Joongheung site in Yeosu. Major sources of abundant species such as ethane, propane, n-butane, toluene were estimated by analyzing seasonal variations, correlation with other VOC species, and emission profiles. A major source of n-butane was identified as LPG cars, while major sources of toluene varied considerably from one site to another. The lower alkanes were composed of ethane and propane, both of which showed a strong seasonal variation, low in the summer and high in the winter, indicating that a major source might be the heating by gaseous fuels. Ozone formation potentials of VOC species were evaluated by applying MIR and POCP to the measured VOC species concentrations. Toluene contributed the most to total ozone forming potentials followed by m,p-xylene for all the type 2 and 3 PAMS sites except for two sites in Yeosu-Gwangyang. Ethylene and propylene were the first and second contributors to total ozone forming potentials at Joongheung site in Yeosu.

Statistical Analysis for Ozone Long-term Trend Stations in Seoul, Korea (통계적 기법을 적용한 서울의 오존 장기변동 대표측정소 선정)

  • Shin, Hyejung;Park, Jihoon;Son, Jungseok;Rho, Soona;Hong, Youdeong
    • Journal of Environmental Impact Assessment
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    • v.24 no.2
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    • pp.111-118
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    • 2015
  • This study was conducted for the establishment of statistical method to determine the representative air quality monitoring station representing long-term ozone trends of Seoul. In this study, hourly ozone concentrations from 2002 to 2011 were used for further analysis. KZ-filter, correlation matrix, cluster analysis, and Kriging method were applied to select the representative station. The analysis based on correlation matrix found that long-term trend of ozone concentrations measured at Sinjung, Sadang, and Bun-dong showed a high correlation. The cluster analysis found that the former three stations belonged to the same cluster. The analysis based on Kriging method also showed that the former three stations were highly correlated with other stations in spatial distribution. Considering these results and the highest correlation coefficient of Sinjung station, the Sinjung station was the most suitable as the representative station used to understand the long-term ozone trend of Seoul. This result could be applied to understand long-term trend of other pollutants. Furthermore, this result can also be used to assess the appropriacy of spatial distribution of national air quality monitoring stations.