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Effects of Intra-particle Composition on the Adhesive Properties and Water Dispersity of Water Dispersible Acrylic Emulsion Pressure Sensitive Adhesive (입자 내 조성 변화가 수분산성 아크릴 에멀젼 점착제의 점착 물성과 수분산성에 미치는 영향)

  • Seo, In Seon;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.444-448
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    • 2007
  • The effects of intra-particle composition on the adhesive properties and water dispersity of acrylic emulsion type pressure sensitive adhesives (PSAs) were investigated. In the case of PSA having uniform intra-particle composition, the higher holding strength made the water dispersity lower. By changing the intra-particle composition in hard core/soft shell type, however, it was possible to get PSAs showing both high holding strength and water dispersity. When the weight ratio of MAA/AA is 4/1, high holding strength, but low initial tack and very low water dispersity were observed in both cases of higher contents of (AA+MAA) in core and shell area. When the weight ratio of MAA/AA is 1/4, however, higher water dispersity and lower holding strength were indicated in the case of higher contents of (AA+MAA) in shell area.

Preparation Of Composite particles with planarized $SiO_2$ Particles (평탄면을 갖는 $SiO_2$미립자의 제조와 이를 이용한 $SiO_2/TiO_2$복합입자의 제조)

  • 신달식;김광수;이옥섭;이성호
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.1
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    • pp.37-54
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    • 1999
  • Planarized SiO$_2$ particles were prepared by two-step reduction method of making much smaller particles, micron-sized ones, to improve spreadability, adherence, and smoothness. Various pigments known as flaky extender usually have terrace layers on their surfaces, but SiO$_2$ Particles in this study exhibit a smooth surface structure. These single SiO$_2$ particles were used for core particles to prepare the composite particles coated with ultra fine TiO$_2$ particles by a homogeneous precipitation method. The thickness and the morphology of the deposited TiO$_2$ layer could be altered by adjusting the reactant concentrations, reaction time and temperature. The characteristics of SiO$_2$/TiO$_2$composite in the field of color cosmetics is to give a UV-cut effect and to enhance the chroma of human skin color, one of optical properties.

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Morphology of Poly(butyl acrylaye)/Poly(methyl methacrylate) Composite Latex Prepared by 2-stage Dispersion Polymerization (중합공정에 따른 PBA/PMMA Composite Latex 모폴로지의 연구)

  • Lee, Ki-Chang;Choe, Hyeon-Seong
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.60-69
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    • 2011
  • The various types of PBA/PMMA composite latexes were prepared by $2.1\;{\mu}m$ PBA seeded batch and seeded semi-continuous dispersion polymerization. The morphology of the PBA/PMMA composite latexes by seeded batch process was found to be closely dependant on the weight ratios of methanol/water in polymerization medium and of PBA seed/MMA at the second stage. In general, egg, snowman, confetti, peanut-like nonspherical composite latex particles were formed with increasing amount of water and MMA as a result of the occurrence of the phase separation between PBA seed and PMMA. The morphology of the PBA/PMMA composite latexes by seeded semi-continuous process was controlled by the addition time of MMA, especially, spherical shaped core(PBA)/shell(PMMA) composite latex particles were prepared under the monomer-starved condition at the second stage.

HS-PSO Hybrid Optimization Algorithm for HS Performance Improvement (HS 성능 향상을 위한 HS-PSO 하이브리드 최적화 알고리즘)

  • Tae-Bong Lee
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.4
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    • pp.203-209
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    • 2023
  • Harmony search(HS) does not use the evaluation of individual harmony when referring to HM when constructing a new harmony, but particle swarm optimization(PSO), on the contrary, uses the evaluation value of individual particles and the evaluation value of the population to find a solution. However, in this study, we tried to improve the performance of the algorithm by finding and identifying similarities between HS and PSO and applying the particle improvement process of PSO to HS. To apply the PSO algorithm, the local best of individual particles and the global best of the swam are required. In this study, the process of HS improving the worst harmony in harmony memory(HM) was viewed as a process very similar to that of PSO. Therefore, the worst harmony of HM was regarded as the local best of a particle, and the best harmony was regarded as the global best of swam. In this way, the performance of the HS was improved by introducing the particle improvement process of the PSO into the HS harmony improvement process. The results of this study were confirmed by comparing examples of optimization values for various functions. As a result, it was found that the suggested HS-PSO was much better than the existing HS in terms of accuracy and consistency.

Metatitanic Acid를 광전극으로 적용한 페로브스카이트 태양전지

  • Pyo, Se-Yeong;Jeong, Seung-Gyu;Sin, Hyeon-Ho;Jeong, Hyeon-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.471.1-471.1
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    • 2014
  • 염료감응형 태양전지(DSSC)는 다양한 태양전지 중, 가장 환경친화적이고, 생산단가도 낮을 뿐만 아니라 다양한 색상과 투광성을 확보할 수 있어 많은 연구가 진행되어왔다. 하지만 액체전해질을 사용하는 기존 염료감응형 태양전지는 높은 휘발성과 열 팽창 수축에 따른 전해질 누액의 문제점으로 인하여 최근에는 고체전해질을 이용한 염료감응형 태양전지의 개발이 활발히 이루어지고 있다. 또한 기존 염료보다 높은 흡광계수와 넓은 흡수스펙트럼을 지닌 페로브스카이트가 개발되어 현재 많은 관심이 주목되고 있다. 본 연구에서는 $TiO_2$ 제조상의 중간생성물인 Metatitanic acid (MTA)를 이용하여 광전극을 형성하고 열처리 온도에 따른 나노입자의 소성거동평가을 평가하였고 시차열중량 분석, 결정상 확인을 하고 염료감응 태양전지에 적용하였다. MTA 나노입자를 Field Emission Transmission Electron Microscopy (FE-TEM), Barrett-Joyner-Halenda (BJH pore size distribution)과 Brunauer-Emmet-Teller (BET) 분석을 통해 소성거동을 평가하고, Thermogravimetry and differential thermal analysis (TG-DTA)를 통해 열중량 측정을 하였으며, X-ray Diffraction (XRD) 분석을 통해 결정상을 확인하였다. 또한 Fourier-transform infrared (FT-IR) spectroscopy를 통해 MTA 나노입자의 표면분석을 하였다. 형성된 MTA 광전극을 페로브스카이트 염료에 적용하여 5%의 효율을 달성하였다.

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Development of the hi-speed composite cohesive device for reduction of particulate pollutants in storm water runoff (초기강우 유출수의 입자성 오염물질 처리를 위한 고속복합응집장치 개발)

  • Choi, Sunhwa;Lee, Jinkyung;Lee, Seungheon;Kim, Heungseop
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.197-197
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    • 2017
  • 본 연구에서는 입자성 오염물질을 다량 함유하고 있는 초기강우 유출수를 처리하기 위한 수처리 시설로 고속복합응집장치를 개발하였다. 고속응집복합장치의 요소기술은 마이크로 버블, 급속교반장치(인라인믹서), 전기촉매를 이용한 부상촉진장치, 볼텍스 흐름 등으로 구성되며, 기술 원리는 응집제에 의해 오염물질을 응결, 응집, 부상시켜 스컴을 제거하는 일반 응집 원리와 유사하다. 본 기술의 특징은 교반, 혼화조, 응집제를 1개의 조에 컴팩트하게 구성하여 체류시간을 10분 이내로 단축하였고, 볼텍스(voltex) 흐름을 이용한 선회류와 루버홀 형태의 스크린을 적용하여 응집효과를 극대화하였으며, 플럭에 의한 막힘이 없이 스크리닝이 이루어질 수 있도록 하였다. 또한, 부상촉진장치(전기유도)를 이용해 응집 플럭의 부상효과를 상승시켰고, 감속기와 일체화된 내통스크린이 선회류와 반대 방향으로 회전하면서 볼텍스 흐름의 가속효과에 의한 스크린 폐색 방지 및 응집부상 효율을 향상시킬 수 있도록 설계하였다. 부상슬러지는 별도의 플럭 제거 설비 없이 스크린 내통 회전에 이용되는 감속기에 부착된 스컴 제거기에 의해 동시 제거가 가능하며, 응집부상 처리수는 장치 가장 바깥 외곽에 충진된 필터층에서 최종 여과되어 방류되도록 구성함으로서 모든 처리공정이 단일 장치 내에서 이루어지도록 구성하였다. 본 고속복합응집장치는 전체 규격 ¢ $1000{\times}2,000mmH$의 시제품이 제작되어 현재 시흥소재 매화저수지에서 성능평가를 실시하고 있다.

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Flow Visualization of Magnetic Particles under the external magnetic field in bubbly flow using Single Plane Illumination Microscopy - MicroPIV (Single Plane Illumination Microscopy - MicroPIV를 이용한 버블 유동에서 외부 자계 영향을 받는 자성입자 가시화)

  • Lee, Changje;Cho, Gyeong-rae;Lee, Sangyoup
    • Journal of the Korean Society of Visualization
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    • v.19 no.1
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    • pp.36-42
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    • 2021
  • This study measured the velocity of magnetic particles inside the power generation using external heat sources. Single Plane Illumination Microscopy (SPIM) was used to measure magnetic particles that are simultaneously affected by bubbly flow and magnetic field. It has the advantage of reducing errors due to particle superposition by illuminating the thin light sheet. The hydraulic diameter of the power generation is 3mm. Its surface is covered with a coil with a diameter of 0.3 mm. The average diameter of a magnetic particle is 200nm. The excitation and emission wavelengths are 530 and 650nm, respectively. In order to find out the flow characteristics, a total of four velocity fields were calculated in wide and narrow gap air bubbles, between the wall and the air bubble and just below the air bubble. Magnetic particles showed up to 8.59% velocity reduction in the wide gap between air bubbles due to external magnetic field.

Development of PM10/2.5/1/TSP Separator (PM10/2.5/1/TSP 포집을 위한 다단임팩터 개발)

  • Kwon, Sun-Bak;Song, Chang-Byung;Lee, Chang;Lee, Gyu-Won;Jung, Hyun-Rok;Ryu, Sung-Woon;Kim, Young-Jun;Lee, Jong-Deok
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.285-286
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    • 2003
  • 다단임팩터(cascade impactor)는 대기환경 연구에 있어 입자상물질의 물리ㆍ화학적 분석에 유용하게 사용되고 있는 입자상물질 포집장치이다. 본 연구그룹에서는 분리입경이 각각 10.07, 4.92, 2.49, 1.02, 0.7$\mu\textrm{m}$인 5단 다단임팩터를 이미 개발하여 성능평가를 수행하였으며, 그 연구결과를 발표하였다(Kwon et al., 2003). 또한 개발된 임팩터를 2002년 4월 8일 부터 29일까지 제주도 고산지역에서 실시된 ACE-Asia 측정 기간동안 설치 운영하여 대기 중 에어로졸 샘플링을 하였다(Park et al., 2003). 본 연구에서는 다단임팩터 사용자의 불편을 최소화하고, 장치의 상용화가 가능하도록 최적 설계에 주안점을 두었다. (중략)

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On the Measurement Technique of Void Fraction by Single Camera Two Phase PIV (단일 카메라 입자영상유속계를 이용한 이상유동 기포율 측정방법)

  • Choi, Dong-Whan;Sung, Jae-Yong;Yoo, Jung-Yul
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1558-1563
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    • 2004
  • A measurement technique for the void fraction and the bubble dynamics in gas-liquid two-phase flows has been proposed using a time-resolved two-phase PIV system. For the three-dimensional evaluation of the bubble information, both the images from the front and side views are simultaneously recorded into a high speed CCD camera by reflecting the side image into the front view with the help of a $45^{\circ}$ oriented mirror. Then, a stereo-matching technique is applied to calculate the void fraction, bubble size and shape. To obtain the rising bubble velocities, the 2-frame PTV method was applied. Consequently, the present technique shows good feasibility for the measurements of the volume fractions, mean diameters, aspect ratios and velocities of the bubbles at the three-dimensional point of view.

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Red-tide Prevention and Killing Treatment of Seaweed and Algae (적조방재와 해조류 사멸 처리)

  • Soh, Dea-Wha;Bai, Mingdong;Bai, Xiyao
    • Journal of the Speleological Society of Korea
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    • no.75
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    • pp.9-13
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    • 2006
  • 자유수산기는 단분자 제조공정으로 분자, 원자 층에서 가공되어 기타 활성입자와 함께 얻어지며, 20% 이상의 고 밀도 질량 비는 양산공정에 중요한 의미를 부여한다. 자유수산기가 선박안정수의 외래침입 생물과 적조처리 및 양식수체 정화에도 효과적인 새로운 처리기술로 선박 안정수에 포함되어 타 지역으로부터 옮겨지는 외래침입생물 처리 방안의 하나로, 강 전리방전 기술을 적용하여 고 밀집 산소와 물분자로부터 고농도 수사자유기(OH: hydroxyl radical)를 전리, 발생시켜서 활성입자를 신속히 확산시켜 비교적 낮은 수산기농도 하에서 유해성침입생물을 사멸 처리하는 환경 친화적 녹색 청정처리방법을 제안하였다.