• Title/Summary/Keyword: 단일 성분

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Morphology and Thermal Properties of PPS/ABS Blends (PPS/ABS 블렌드의 형태학적/열적 특성)

  • 이영관;김준명;남재도;박찬석;장승필
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.366-373
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    • 2000
  • In this study, the PPS/ABS blend system was investigated in order to collectively identify the relationship among blend morphology, chemical compatibilization and thermal property. ABS resin was chemically modified by the incorporation of maleic anhydride through reactive extrusion for enhanced compatibilization, and PPS, ABS and the modified ABS were blend by a sing twin screw extruder. The effect of chemical modification of ABS on the morphological, mechanical, and thermal properities of the resulting blend was examined. A strong interaction was observed between PPS and MABS by optical microsopy as well as scanning electron microscopy, exhibiting a well-dispersed morphological feature. The PPS/MABS blend showing a single glass transition temperature was observed in dynamic mechanical analysis, demonstrating a pseudo-homogeneous phase morphology induced by chemical compatibilization. PPS/MABS blend also exhibited an enhanced thermal stability and heat distortion temperature compared with modified PPS/ABS blend.

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A Laser Pointer Detection Algorithm Based on Conditional Test in Color Model and Differential Image (색상 조건 검사와 차영상을 이용한 레이저 포인터의 좌표 검출)

  • Lee, Doo-Hee;Kim, Yoon;Choi, Chang-Yeol
    • Proceedings of the Korea Information Processing Society Conference
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    • 2010.11a
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    • pp.617-620
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    • 2010
  • 최근 고성능 모바일 단말기와 다양한 컨텐츠가 등장하면서 유비쿼터스 환경에서의 사용자 인터페이스에 대한 관심이 높아지고 있다. 특히 모바일 프로젝터는 장소의 제한을 받지 않고 큰 화면을 다른 사람과 공유할 수 있는 장점이 있는 반면에 단말기를 직접 제어해야 하는 불편함이 있다. 본 논문에서는 모바일 환경에서 카메라를 통해 입력된 영상 정보만으로 사용자가 스크린에 비추는 레이저 포인터를 실시간으로 검출하는 알고리즘을 제안한다. 제안하는 알고리즘은 색상 감지와 움직임 감지로 나뉜다. 단일 프레임에서 영상 성분의 평균을 이용한 조건을 검사하여 레이저 포인터 색상 영역을 검출하고, 인접한 프레임과 현재 프레임과의 차를 구하며 그 차이가 임계값보다 큰 영역을 움직임 영역으로 검출한다. 마지막으로 색상 검출 영역과 움직임 검출 영역을 동시에 만족하는 영역을 최종적으로 레이저 포인터 영역으로 인식한다. 본 기법은 영상 정보만 사용하기 때문에 센서나 불필요한 장비를 착용할 필요가 없고 영상 성분 평균을 이용하므로 프로젝터 성능에 따른 조도의 변화에 강건하여 효과적인 레이저 포인터 검출이 가능하다. 실험결과는 주변 조명의 밝기에 따라 차이가 있지만 대부분 80% 이상의 검출률과 16% 미만의 오검출률의 성능으로 나타났고, 이 같은 결과는 사용자의 주관적인 만족을 보장하였다.

Effects of Fining Treatments on Color and Clearness of Apple Wine (청징방법에 따른 사과와인의 색과 투명도에 미치는 영향)

  • Bang, Byung-Ho;Jeong, Eun-Ja;Kang, Hyeran;Rhee, Moon-Soo;Yi, Dong-Heui;Paik, Jean Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.3
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    • pp.368-373
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    • 2017
  • Comparative fining trials were conducted in a laboratory to study the effects of fining treatments including polyvinylpolypyrrolidone (PVPP) and bentonite on the color and clearness of apple wine. The wines were subjected to three different fining treatments: PVPP, PVPP+bentonite (applied at the same time), and PVPP+bentonite (24 h later). Based on the results, all treatments induced noticeable decreases in wine color (APHA value) and turbidity. The treatment including PVPP and bentonite at the same time provided the best results in relation to wine color and clearness. PVPP was the most effective in the reduction of phenolic compounds, which means it helped wine obtain a paler color. Organic acids and aromatic profile were not altered by the fining treatments.

Determination of Natural Gas Components by Gas Chromatographic Multicolumn System (기체 크로마토그래피 복합컬럼 시스템에 의한 천연가스 성분의 정량)

  • Choi, Yong-Wook;Choe, Kun-Hyung
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.339-347
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    • 1994
  • A multicolumn system consisted of two valve(10-port and 6-port valve)-three column (28% DC 200, SP 1700 and Chromosorb 102 column) was developed. Nine natural gas components composed of $N_2$, $CH_4$, $CO_2$, $C_2H_6$, $C_3H_8$, $i-C_4H_{10}$, $n-C_4H_{10}$, $i-C_5H_{12}$$n-C_5H_{12}$ completed all the baseline separation within 18 minutes. The accuracy and the precision of this system was tested. The retention times and the peak areas were determined with a repeatability between 0.02 and 0.16%, and less than 1%, respectively. Calibration curves for natural-gas components were plotted by the partial pressure injection method of pure gases, and good linear relationships for each component were presented. By using these calibration curves the accuracy of the multicolumn system compaired with that of the single column system for a certified standard gas of natural gas. As a result, relative error in the single and the multicolumn system was less than 0.5% and 0.04%, respectively. The result of application of this system in the analysis of importing LNG composition showed that the heating values calculated by the multicolum system were estimated lower compared with those calculated by the single column system and consequently, the importing price of LNG was able to be cut down.

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Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

A study on antioxidant and anti-inflammatory effects of domestic blended essential oils (국내산 블렌딩 정유의 항산화 및 항염 효과 연구)

  • Jung, Sook Heui;Lee, Eun Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1370-1382
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    • 2021
  • Previous studies have been conducted on domestic materials as a single extract. Research on complex mixtures for maximizing plant characteristics by individual extraction and potential interference with effects is insufficient. Therefore, this study confirmed the GC-MSD according to the extraction of essential oils for Agastache rugosa O. Kuntze(AR), Pinus densiflora Sieb. et Zuccarini(PD), Curcuma longa, Curcuma domestica(CC), Zingiber officinale Roscoe(ZR), Foeniculum vulgare Miller(FV), and Citrus medica L. var. sarcodactylis Swingle(CS). The cytotoxicity, antioxidant, and anti-inflammatory properties of the blending oil were confirmed to confirm its potential as a cosmetic material. As a result of analyzing GC-MSD aroma components, the main components were estragole of AR, à-Pinene for PD, Zingiberene for CC and ZR, Anethole from FV, and D-Limonene for CS. At a concentration of 100 uL/mL with no confirmed cytotoxicity, NO production was inhibited by 70.62%, DPPH radical scavenging activity was 64.03%, and ABTS radical scavenging activity was 89.55%. Through this, blended essential oil suggests the possibility of useful application as a raw material with antioxidant and anti-inflammatory effects in the cosmetic and food industries.

Changes in Major Chemical Constituents of Green Coffee Beans during the Roasting (커피 원두의 배전공정중 변화되는 주요 화학성분에 대한 연구)

  • Kim, Kwan-Jung;Park, Seung-Kook
    • Korean Journal of Food Science and Technology
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    • v.38 no.2
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    • pp.153-158
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    • 2006
  • Changes in contents of amino acids, caffeine, trigonelline, chlorogenic acid, and monosaccharides in green coffee beans during roasting were investigated. During roasting, amino acid contents of Arabica and Robusta coffees decreased by 30%, among which cysteine, serine, lysine, and arginine contents markedly decreased, whereas those of glutamic acid, glycine, alanine, valine, isoleucine, leucine, and phenylalanine slightly decreased or increased. Caffeine contents of Arabica and Robusta were 1 and 2%, respectively, and remained unchanged during roasting. Trigonellin content of Arabica (0.87%-0.90%) was slightly higher than that of Robusta (0.74%), and 50 to 65% trigonellin degraded when green beans were heavily roasted. Chlorogenic acid levels of Robusta and Arabica were 4.82, and 4.38-4.66%, respectively. About 90% chIorogenic acid degraded with heavy roating. Total monosaccharide contents of Arabica and Robusta were 38.1-38.7 and 37.7%, respectively, and gradually decreased with roasting.

A Study on Preparation of Colloidal Gas Aphrons and Stability (Colloidal Gas Aphrons의 제조와 안정성에 대한 연구)

  • Yoon, Mi-Hae;Cho, Dae-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.670-677
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    • 2007
  • The stability of CGAs(colloidal gas aphrons) prepared from non-ionic and ionic surfactants was investigated. Those surfactants were sodium dodecyl sulfate(SDS), Triton X-100, Tween 80 and Quillaja Saponin. The stability of CGAs prepared from single surfactants or mixed surfactants(two components) using a CGA generate. was investigated as functions of temperature, surfactant concentration and stirring time. Saponin among the single surfactants has shown the longest duration time(143 min) and then, Triton X-100, SDS, and Tween 80 were followed by at room temperature. In case of CGAs heated up to $70^{\circ}C$, SDS endured for 116 min but Saponin lasted for only 105 mit which was a considerable reduction of the duration time of CGAs at room temperature. For mixed surfactant pairs, stability of any one pairs stood between the two. That meant no synergic effect for surfactant blending. At the higher temperature, Saponin+Triton X-100 was disclosed to be the lowest, 53 min meanwhile Saponin+SDS was the highest at ambient temperature. The CGAs, initially about 140 ${\mu}m$ in diameter, began to grow right after the agitation to be about 190 ${\mu}m$ owing to coalescence of the bubbles and then became to collapse. When heated, CGAs including Saponin tended to be smaller while the others to be larger. In summary, we found that the stability of CGAs or the duration time was greater for single surfactants and at room temperature rather than for mixed surfactants that caused substantial intermolecular interactions in the CGA structure and at the higher temperature.

Mixed Lanthanide Shift Reagents (혼합 란탄족 Shift Reagents)

  • Man-Ho Lee;Charles N. Reilley
    • Journal of the Korean Chemical Society
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    • v.26 no.1
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    • pp.24-30
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    • 1982
  • Contact-only (COM) and dipolar-only (DOM) mixtures of the lanthanide shift reagents were prepared based on the Fi and Gi values deduced using individual Ln$(fod)_3$ (Ln = Pr, Nd, Eu, and Yb) and 4-picoline. The $F_i$ and $G_i$ values obtained directly by COM 1 and by DOM 1, which were appropriate mixture of Pr$(fod)_3$ and Eu$(fod)_3$, agreed well with those values obtained by experiments using individual Ln$(fod)_3$ shift reagents. Ei and Gi values obtained directly by COM 2 and by DOM 2, which were mixtures of Nd$(fod)_3$ and Yb$(fod)_3$, deviated from the expected values. The error was traced to the behavior of the ytterbium complexes.

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DSC and FTIR Studies of Miscible Poly(butylene 2,6-naphthalate)/Poly(4-vinylphenol) Blends (DSC와 FTIR을 이용한 상용성 (폴리부틸렌나프탈레이트/폴리비닐페놀) 블렌드의 연구)

  • 이준열;한지영
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.737-744
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    • 2002
  • Thermodynamic miscibility of the binary blends composed of semi-crystalline poly (butylene 2,6-naphthalate) (PBN) and amorphous poly (4-vinylphenol) (PVPh) was investigated using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. DSC scan results showed that there was a single glass transition temperature (T$\_$g/) for each blend. Crystalline melting temperature (T$\_$m/) depression of the PBN in the blends was also observed with the increase of PVPh content. Both results of the single T$\_$g/ and the depression of T$\_$m/ for the PBN/PVPh blends indicate that the blends are thermodynamically miscible at the molecular level. FTIR spectroscopic analysis confirmed that strong intermolecular hydrogen bonding interactions between the ester carbonyl groups of the PBN and the hydroxyl groups of the PVPh are occurred.