• Journal of the Korean Chemical Society
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• v.37 no.2
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• pp.191-198
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• 1993

The crystal structures of $Cd_{6-}A$ evacuated at $2{\times}10^{-6}$ torr and $750^{\circ}C$ (a = 12.204(1) $\AA$) and dehydrated $Cd_{6-}A$ reacted with 0.1 torr of Cs vapor at $250^{\circ}C$ for 12 hours (a = 12.279(1) $\AA$) have been determined by single crystal X-ray diffraction techniques in the cubic space group Pm3m at $21(1)^{\circ}C.$ Their structures were refined to final error indices, $R_1=$ 0.081 and $R_2=$ 0.091 with 151 reflections and $R_1=$ 0.095 and $R_2=$ 0.089 with 82 reflections, respectively, for which I > $3\sigma(I).$ In vacuum dehydrated $Cd_{6-}A$, six $Cd^{2+}$ ions occupy threefold-axis positions near 6-ring, recessed 0.460(3) $\AA$ into the sodalite cavity from the (111) plane at O(3) : Cd-O(3) = 2.18(2) $\AA$ and O(3)-Cd-O(3) = $115.7(4)^{\circ}.$ Upon treating it with 0.1 torr of Cs vapor at $250^{\circ}C$, all 6 $Cd^{2+}$ ions in dehydrated $Cd_{6-}A$ are reduced by Cs vapor and Cs species are found at 4 crystallographic sites : 3.0 $Cs^+$ ions lie at the centers of the 8-rings at sites of $D_{4h}$ symmetry; ca. 9.0 Cs+ ions lie on the threefold axes of unit cell, ca. 7 in the large cavity and ca. 2 in the sodalite cavity; ca. 0.5 $Cs^+$ ion is found near a 4-ring. In this structure, ca. 12.5 Cs species are found per unit cell, more than the twelve $Cs^+$ ions needed to balance the anionic charge of zeolite framework, indicating that sorption of Cs0 has occurred. The occupancies observed are simply explained by two unit cell arrangements, $Cs_{12}-A$ and $Cs_{13}-A$. About 50% of unit cells may have two $Cs^+$ ions in sodalite unit near opposite 6-rings, six in the large cavity near 6-ring and one in the large cavity near a 4-ring. The remaining 50% of unit cells may have two Cs species in the sodalite unit which are closely associated with two out of 8 $Cs^+$ ions in the large cavity to form linear $(Cs_4)^{3+}$ clusters. These clusters lie on threefold axes and extend through the centers of sodalite units. In all unit cells, three $Cs^+$ ions fill equipoints of symmetry $D_{4h}$ at the centers of 8-rings.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.9
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• pp.685-692
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• 2018

Using Babinet's principle and generalized sheet transition conditions(GSTCs), an analysis method for metascreens is proposed. First, the relation of a complementary screen between a metafilm and metascreen with the same dimensions was confirmed using Babinet's principle. These properties were verified by comparing the reflection coefficient of the patch and the transmission coefficient of the mesh. The patch and mesh are the basic structures of metafilms and metascreens, respectively. Based on these findings, it is also confirmed that the reflection coefficient of the patch surface calculated by GSTCs has the same value as the transmission coefficient of the mesh surface. It is expected that the proposed analysis methods can be applied to the magnitude, phase, and polarization of electromagnetic waves in the various unit structures of a given metasurface.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.25 no.6
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• pp.664-670
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• 2014

Generally, the properties of metamaterials are analyzed based on the infinite array of the unit cells. In real application of the metamaterial, however, the array has to be finite. Hence, it is important that a method can analyze the effect of the finite array of the metamaterial. In this paper, a model is proposed which can calculate the scattering by a large-size finite array of an I-shaped metamaterial without a full-wave simulation. The proposed model is based on the surface current estimation of each unit cells. The ratio of the current distribution on a finite array of the metamaterial to that of the infinite array of the same metamaterial for a TM polarized incident wave is approximated as a quartic polynomial. The coefficients of the polynomial are a function of the physical dimension of the metallic patch. Hence, the current distribution of the finite metamaterial can be estimated based on the proposed polynomial and the current of the infinite array. The scattered field is calculated by using the surface current model. The proposed model is numerically and experimentally verified by comparing calculated and measured RCS(Radar Cross Section) data.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.492-498
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• 2021

In this paper, the electromagnetic wave transmittance of the reinforced concrete structure wall was analyzed using the performance measurement system of electromagnetic wave shielding. Recently, electromagnetic wave shielding technologies on the reinforced concrete wall conditions have been studied, and the shielding effectiveness have been tested on unit cell size. However, the unit cell size tests have problems on that the measurement range for shielding performance is insufficient and it is difficult to reflect the real conditions of the concrete wall. Therefore, we constructed a shielding performance measurement system using a large sample of 2.2m × 2.2m like a real wall. To verify the measurement system, general reinforced concrete test samples were selected, and real shielding performance measurements and numerical analysis were proceeded. Test and numerical analysis results showed similar tendencies in the evaluation frequency range of 75MHz to 2GHz. Thus we validated the effectiveness of this shielding performance measurement system.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.29 no.6
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• pp.315-325
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• 2017

This study aims to provide information for the design and use of structural lightweight concrete (SLWC) for floating concrete structures in a marine environment. An experimental program was set up and comprehensive experimental campaign were carried out to determine SLWC mix proportions that can satisfy specified concrete strength, density, and slump values all of them were determined from previous research. Comparisons with previous SLWC mix designs that have been utilized for actual floating concrete structures were made. Key aspects needed to be considered regarding to the use of SLWC for floating marine concrete structures were discussed.

• Korean Journal of Crystallography
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• v.4 no.2
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• pp.54-62
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• 1993

The crystal shnture of dehydrated fully Cd2+-exchanged zeolite A evacuated at 2 × 10-6 Torr and 650℃ (a:12.189(2) A) and of its iodine sorption corrplex (a:12.168(2)A) have been netsmlmn by single uystal x-ray diffraction techliques in the cubic space group hkTn at 21(1)℃. The strutures were refined to final error indices, Ri:0.057 and R2 =0.063 with 186 reflections and Rl:0.082 and R2:0.085 with 181 reflections, respectively, for which 1>3σ(In both structure, six lie at two distinguished threefold axes of unit cell ten the crystal structure of an iodine sorption complex of Cd6-A four Cd2+ ions are recessed 0.69(1) A into the large cavity to complex each with from the (111) plane of 0(3), whereas two Cd2+ ions recessed 0.68(1) A into the sodalite unit Awximately 4.0 l3ions per nit cell are sorbed. Each bridge between a Cd2+ ion and 8-ring oxygens ((I-I-I)= 117(1) ˚ and 0(1)-I(1)-I(2)=172(1)). The near linear I-I-0 angle and its interatomic distance (I-0=3.57(3) A) are indicative of a weak charge transfer interacticn between the frarrework oxygen and iodine. The existence of In3 inside the large cavity indicates that the If ions and H ions may be produced by reaction of In vapor with water molecules which maybe associated with Cd2+ ions in partially dehydrated Cd6-A In3- ions may be produced by the combination of I- and I2.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.4
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• pp.217-226
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• 1993

This study is related to the surface subsidence due to the collapse of a underground void during earthquakes. The amount of the settlement due to the collapse of a underground void will depend on the depth of the void, the initial condition of unit weight of sand, the size and type of foundation, the strength of earthquake, the size of a void, etc. The purpose of the paper is to estimate the amount of the subsidence, analyse the factors affecting the subsidence, and develop a program determining the probability of the damages to structures in terms of absolute and differential settlement and rotational settlement. On the base of the results obtained in this study, when the depth of a void is constant and the width of the void increases, the change of the subsidence factor due to the angle of internal friction and the actual effective factor of the void become smaller than that due to the unit weight of sand deposits. In the same condition, the probabilities of damages due to the absolute and differential settlement increase, and those due to the rotational settlement decrease.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.6
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• pp.707-714
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• 2011

The inter-story drift ratio is used to evaluate the damage of buildings by the earthquake. This is known that as the inter-story drift ratio decreases, the seismic damage decreases. Although to reduce the inter-story drift ratio is the important issue in the seismic design, no practical inter-story drift design method has bean developed. This study presents an optimal inter-story drift design method to improve the seismic performance of the steel moment frames using the resizing algorithm. The objective function of the proposed method is to minimize the differences of the inter-story drift ratios so that the inter-story drift ratios of the building could be distributed evenly and be reduced. Because this method redesigns the sectional properties of structural members base on the displacement participation factor calculated by the unit-load method, this can improve the seismic performance of the structure without the iterative structural analysis. The efficiency of this algorithm was demonstrated by the application to steel moment frames.

• Journal of the Mineralogical Society of Korea
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• v.16 no.3
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• pp.215-222
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• 2003

The Rietveld structure refinement for the natural trioctahedral mica, phlogopite-1M (Parker Mine, Quebec, Canada) has been done by high resolution neutron powder diffraction at $25^{\circ}C$ and -263$^{\circ}C$. The structural formula of phlogopite determined by electron probe microanalysis is $K_2$(M $g_{4.46}$F $e_{0.83}$A $l_{0.34}$ $Ti_{0.22}$)(S $i_{5.51}$A $l_{2.49}$) $O_{20}$(O $H_{3.59}$ $F_{0.41}$). Cell parameters are a=5.30∼5.31 $\AA$, b=9.18∼9.20 $\AA$, c=10.18∼10.21 $\AA$, $\beta$=100.06∼100.08$^{\circ}$. Refinements converged to R values in the range of $R_{p}$=2.35%, $R_{wp}$=3.01%, respectively. In this study, the OH bond length is calculated to 0.93 $\AA$ at room temperature and 1.03 $\AA$ at -263$^{\circ}C$, and the angles between OH vector and (001) plane are obtained 93.4$^{\circ}$∼93.6$^{\circ}$. The decrease in the length of OH with the increase in temperature should be due to the hydrogen bonding in the structure of phogopite.e.e.f phogopite.e.e.

• The Korean Journal of Applied Statistics
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• v.1 no.2
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• pp.82-90
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• 1987

모든 과학기술지식은 객관성을 지닌 관찰과 실험과 측정에 의해서 이루어진다. 이렇게함으로써 과학기술지식은 재현성과 영구성을 가져오게 되며, 올바른 전승과 누적적 발전을 가져오는데 이 과학기술지식의 질서체계를 유지하는데 근본적인 역할을 하는 것이 표준이다. 시간, 길이, 온도, 무게 등의 기본 측정단위와 광속, 중력 등의 물리화학적 상수, 법정계량단위, 각종 공업 규격, 안정 규정 등 수 없이 많은 표준은 효과적인 공동 인식과 객관적 판단의 기준으로 활용되고 있다. 현대의 과학기술이 다양하게 발전하고 이에 따라 우리의 생활도 더욱 복잡한 구조를 이루면서 표준에 대한 필요성도 더욱 높아가고 있다. 표준에 대한 깊은 생각없이도 우리는 자동차에 주유할때 표준단위를 통해 원하는 분량을 말하며, 카메라의 필름 종류를 선택할 때도 국제표준기구(ISO: International Standards Organization)의 규격을 사용하는데 익숙해져 있다. 이렇게 표준은 우리 일상생활과 밀접한 관계에 있으나 소비자 입장에서는 그 가치를 절실히 느끼지 못한 것이 사실이며 표준이 없음으로 해서 일어나는 불편과 혼란에 대해서는 무관심한 것이 사실이다. 일상생활에서 일어나는 표준의 역할을 우리가 잘 이해한다면 표준이 왜 필요한가를 쉽게 인식하게 될 것이다. 최근 정보산업이 새로운 물결로 사회전반에 영향을 미치고 있으며 이에 따라 정보의 수집, 가공, 저장 및 배포의 처리 과정에서도 제반 표준화의 필요성이 크게 대두되었다. 그 결과로 최근 10여년간에 수백종의 기술기준, 지침서 및 기본/기능 표준규격이 제정되어 왔다. 이와 같이 어떤 특별한 영역에서의 표준에 대한 요구가 있을 때 관련 규격이 제정되게 된다. 표준의 제정을 위한 다음 단계는 그 주제에 관한 표준(또는 규격)개발에 관심을 가진 사람들이 모이는 일일 것이다. 통계분야에서도 몇가지 표준화 활동이 ISO 를 중심으로 진행되고 있다. 예를 들면 실험과 검증 결과의 표현과 해석, 표본추출 방법 등에 관한 것으로 이들은 통계의 응용분야에서 꼭 필요한 표준이다. 구체적인 예로서 우리나라 국민의 표준체위값을 설정하기 위하여 측정조사할 때 측정방법 뿐 아니라 표본추출 방법과 통계자료 처리과정의 표준화가 이루어 지지 않는다면 각 기관에서 조사 발표하는 체위관계 자료가 상이하여 국가기관의 통계자료에 대한 신뢰성이 저하되고 통계값을 이용하여 의류, 신발 등의 제품을 제조하는 산업계에 혼란을 야기시킬 수 있다. 본 고에서는 ISO의 활동을 정보처리 분야에 초점을 맞춰 간략하게 설명하고 통계분야의 국제 활동을 비전문가인 필자들이 아는대로 소개하는 한편 국내활동의 필요성을 강조하여 관련 기관, 학계 및 산업계 관련전문가들의 ISO 국내활동 참여를 제의하고자 한다.