• Title/Summary/Keyword: 단분자막

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Studies on Stability for the Quality of Ginseng Products -3. Determination of Sorption Properties and Optimum Moisture Contents in Extract, Extract Powder and Extract Tea of Red Ginseng- (인삼제품(人蔘製品)의 품질안정성(品質安定性)에 관한 연구(硏究) -3. 홍삼정(紅蔘精), 정분(精粉) 및 정차(精茶)의 흡습특성(吸濕特性)과 적정수분함량(適正水分含量) 기준설정(基準設定)-)

  • Choi, Jin-Ho;Byun, Dae-Seok;Park, Kil-Dang;Kim, Mu-Nam
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.13 no.2
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    • pp.215-221
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    • 1984
  • To investigate stability for the quality of selected ginseng products, their sorption properties were clarified in red ginseng extract(RGEP), and red ginseng extract powder(RGEP), and red ginseng extract tea(RGET). Simultaneously, the BET monolayer value of each product was determined in order to inquire out the possibility of establishment as a criterion for the optimum moisture content of the ginseng products. Based on the BET monolayer moisture level of spray dried RGEP which ranged from 4.08 to 4.65%, it would be desirable to establish the optimum moisture content of the products at 4.4${\pm}$0.3%. This is 1.3 to 1.9% lower than the criter on, "less than 6.0%". The optimum moisture level for RGET of which monolayer value ranged 0.93 to 1.37% would be 1.2${\pm}$0.17%. In this case, the maximum permissible limit of moisture content could presumably be raised up to 1.37% in place of current criterion, "less than l.2%". From the results of a study on the growth of molds, the optimum moisture content for RGE assumed to be extended up to 40.0${\pm}$1.07 despite 36.0${\pm}$1.0% of the present criterion. On the other hand, a storage study under the maltreated condition, $48{\pm}2^{\circ}C$ 75%RH, was also carried out in order to make it clear whether the BET monolayer values were able to be used as indices for optimum moisture level of the products. In all samples tested adsorption occurred at even higher levels of moisture than the monolayer values. However, since there are many other possible factors affecting the quality of products the optimum moisture content is preferable to be reduced to the monolayer value. As a result, it was proved that the optimum level of moisture for both RGEP and RGET could be established by the monolayer values.

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pH, Alkaline Earth Metal Ion Effects and Miscibility with Hexadecanol on the Monolayer of Palmitic Acid at the Air-Water Interface (기-액 계면에서 Palmitic Acid 단분자막에 대한 pH, 알칼리토금속 이온의 영향 및 Hexadecanol 분자와의 섞임성)

  • Jong-Jae Chung;Byung-Il Seo;Hai-Won Lee;Min-Young Ju
    • Journal of the Korean Chemical Society
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    • v.37 no.3
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    • pp.294-301
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    • 1993
  • ${\pi}$-A isotherms of the Palmitic acid(PA) with increasing pH shifted to the low area/molecule due to the dissociation of PA at the air-water interface. More condensation of PA monolayers occurred by the addition of Mg$^{2+}$, Ca$^{2+}$ and Ba$^{2+}$ ion in subphase. This condensing effect was increased with increasing the concentration of these ions. Due to the interaction with each ion, PA were formed Mg, Ca, Ba-Palmitate complex. The binding structure between alkaline earth ion and carboxylate ligand in PA has been identified by IR spectrometry. The order of condensing effect of alkaline earth ions at pH 8 was Ca$^{2+}$ > Ba$^{2+}$+ > Mg$^{2+}$. The condensing effect except for Mg$^{2+}$ decreased with increasing atomic number. Whereas, the condensing effect in pure water system decreased with decreasing atomic number in the sequence: Ba$^{2+}$ > Ca$^{2+}$ > Mg$^{2+}$. The miscibility of binary system of PA and hexadecanol in monolayer showed that the miscibility was good for the pure water system. But, in the buffered pH 8 system, bad miscibility was found.

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Surface Characteristics and Photoelectrochemical Properties of the Polyphridine LB films (폴리피리딘계 LB 단분자막의 표면측정과 전기화학적 감광특성)

  • 최인희;나재진;임기조;박수길;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.132-135
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    • 1995
  • This paper describes the electrochemical and photochemical behavior of amphiphilic Os bipyridine compelx adsorbed on SnO$_2$electrodes by the Langmuir-Blodgett(LB) film as monolayer state. Theoretical equation of cyclicvoltammetry for redox species were discussed. And the cyclic voltammogram were simulated taking account theinteraction parameters. From these obtained values, we could fit almost all measured voltammograms with these parameters.

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IETS of Au/Polyimide/1-layer organic film /Pb Structures (Au/Polyimide/유기 단분자막/Pb 구조의 IETS)

  • ;;;M.I wamoto
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.230-233
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    • 1995
  • Using Polyimide Langmuir-Blodgett(LB) films as a tunneling barrier, Current -Voltage(I-V) characteristics and inelastic electron tunneling spectroscoupy(IETS) of the junctions incorporating 1-layer orgainc monolayer were invesgated. Several peaks originating in vibrational modes of constituted molecules of 1-layer monolayers were clearly observed in the IET spectra.

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$\pi$-A Characteristics of Arachidic Acid Monolayer (Arachidic Acid 단분자막의 $\pi$-A 특성)

  • 이대일;최용성;장상묵;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.10-11
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    • 1991
  • In this paper, Arachidic Acid of long-chain fatty acid was soluted by chloroform and observed $\pi$-A curve in trough. In our experimental result, optimum pressure for fabricating the LB film was 30mN/m. In $\pi$-A curve measurment, temperature dependence was investigated between 20-50($^{\circ}C$). However, in this temperature range, the variation of solid phase pressure was not observed.

A Study on Displacement Current DMPC Monolayer (DMPC 단분자막의 변위전류 특성 연구)

  • Choi, Yong-Sung;Cho, Jang-Hoon;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.168-169
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    • 2006
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. The phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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나노 패턴 성형 공정기술

  • 강신일
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.9-9
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    • 2004
  • 나노 패턴 성형 기술은 반도체와 같은 정보전자 소자 기술과 정보저장매체 기술 분야 및 광통신 분야에서 그 기술의 필요도가 급속히 증가하고 있다. 정보저장 매체의 경우 저장밀도가 기하급수적으로 증가하고 있는 추세이며 향후 수년 내에 기존의 정보저장매체 제작방법으로는 더 이상의 저장밀도 증가가 불가능한 수준까지 기술의 발달이 이루어지리라 예상된다. 이에 따라 패턴드 미디어(patterned media) 및 초고밀도 광정보저장매체가 정보저장기술의 차세대 매체로서 제안되었으며 이의 실현을 위해 나노 패턴 성형기술의 시급한 개발이 요구되고 있다.(중략)

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The electrochemical desorption of an eicosanethiol monolayer by electrochemical quartz crystal microbalance (EQCM을 이용한 아이코산티올 단분자막의 전기화학적 탈착)

  • Chung, Chinkap
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.383-389
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    • 1995
  • A new approach for the measurement of the surface coverages of monomolecular films fabricated by spontaneous adsorption of thiol compounds on gold is described. It is based on the mass change measurement with EQCM for the reductive electrochemical desorption of thiol in aqueous KOH solution. The results were compared with that of charge calculation during electrochemical desorption. The surface coverage value for eicosanethiol agrees with that obtained by charge calculation of electrochemical reduction as well as that expected from a geometrical model of the compact monolayer.

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Development of Biomolecular Device Using Biomolecular Film Part 1: Optical Biosensor to Detect the Ethanol Using Langmuir-Blodgett Film of Eilzyme Molecules (생체분자막을 이용한 생물분자소자의 개발 제1부 :효소분자 LB막을 이용한 에탄올 측정용 광학 바이오센서)

  • 최정우;배주연지용이원홍
    • KSBB Journal
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    • v.10 no.1
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    • pp.105-112
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    • 1995
  • The fiber-optic biosensor using enzyme-immobilized Langmuir-Blodgett film is developed fort the measurement of ethanol. The enzyme, alcohol dehydrogenase, is immobilized at the molecular level on the arachidic acid monolayer using Langmuir-Blodgett film technique. Based on the ordered multisubstrate mechanism, the immobilized enzyme kinetics is investigated. The optical sensing system is proposed, and sensor signal is proportional to ethanol concentration and is related wish the number of enzyme layers. As the number of deposited LB film layer increases up to 20 1ayers, the high ethanol concentration of 45mM can be measured without the saturation of signal. Surface pressure-area isotherm is measured for the three-different charged-lipids. Arachidic acid is the most suitable for the adsorption of alcohol dehydrogenase based on electrostatic force.

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