• Title/Summary/Keyword: 다중분해속도 상수

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Determination of Ultimate Biodegradability and Multiple Decay Rate Coefficients in Anaerobic Batch Degradation of Organic Wastes (유기성폐기물의 회분식 혐기성 최종생분해도와 다중분해속도 해석)

  • Kang, Ho;Shin, Kyung-Suk;Richards, Brian
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.555-561
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    • 2005
  • A new graphical method was developed to separate two distinctive decay rate coefficients($k_1$ and $k_2$) at their respective degradable substrate fractions($S_1 and $S_2$). The mesophilic batch reactor showed $k_1$ of $0.151\;day^{-1}$ for wasted activated sludge(WAS), $0.123\;day^{-1}$ for thickened sludge(T-S), $0.248{\sim}0.358\;day^{-1}$ at S/I ratio of $1{\sim}3$ for sorghum and $0.155{\sim}0.209\;day^{-1}$ at S/I ratio $0.2{\sim}1.0$ for swine waste, whereas their long term batch decay rate coefficients($k_2$) were $0.021\;day^{-1}$, $0.001\;day^{-1}$, $0.03\;day^{-1}$ and $0.04\;day^{-1}$ respectively. At least an order of magnitude difference between $k_1$ and $k_2$ was routinely observed in the batch tests. The portion of $S_1$, which degrades with each $k_1$ appeared 71% for WAS, 39% for T-S, 90% for sorghum, and $84{\sim}91%$ at S/I ratio of $0.2{\sim}1.0$ for swine waste. Ultimate biodegradabilities of 50% for WAS, 40% of T-S, $82{\sim}92%$ for sorghum, and $81{\sim}89%$ for swine waste were observed.

Sonolysis of Trichloroethylene in the Multi Ultrasound Irradiation Reactor (다중 초음파 조사 반응조에서의 TCE의 초음파 분해)

  • Lee, Min-Ju;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.873-882
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    • 2009
  • Sonolysis of TCE (Trichloroethylene) was performed in 584 kHz rectangular reactor. At first, the effect of acoustic power and aqueous temperature which are both important factors to operate ultrasound system on sonolysis of TCE were examined under one side irradiation condition. First degradation rate constants of TCE and chloride yields were increased with increasing acoustic power from 100 to 300 W. And increasing the aqeuous temperature resulted in the increase of first degradation rate constants of TCE and the decrease of chloride yield. Sonolysis of TCE was performed under multi ultrasound irradiation conditions that total acoustic power of 300 W was distributed according to the number of irradiation sides. First degradation rate constants of TCE followed the order 4 sides > 3 sides > 1 side > 2 sides (parallel) > 2 sides (orthogonal). When comparing the experimental results under parallel and orthogonal irradiation conditions of 2 sides with 300 and 450 W, first degradation rate constants of TCE were similar, while production rate constants of hydrogen peroxide were more higher at parallel conditions compared to orthogonal conditions.

Effect of the Salt Concentration in Seafood Processing Wastewater on the Anaerobic Ultimate Biodegradability and Multiple Decay Rate of Organic Matter (해산물 가공폐수내 염분농도가 혐기성 최종생분해도와 유기물 다중분해속도에 미치는 영향)

  • Choi, Yong-Bum;Kwon, Jae-Hyouk;Rim, Jay-Myung
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1038-1045
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    • 2010
  • In this study, the anaerobic ultimate biodegradability and multiple decay rate of organic matter were evaluated according to various salt concentrations in seafood processing wastewater. The evaluation was also performed with various types of anaerobic bacteria and S/I (substrate/inoculum) ratios. After the S/I ratio was fixed at 0.9, the ultimate biodegradability values of the anaerobic digested sludge and granular sludge were became 72.0% and 92.0%, respectively. The multiple decay rate coefficients ($k_1$) coefficients of the anaerobic digested sludge and granular sludge were $0.0478{\sim}0.1252\;day^{-1}$ and $0.0667{\sim}0.1709\;day^{-1}$, respectively. The optimum S/I ratio of the seafood wastewater, which was determined based on the ultimate anaerobic biodegradability and gas production, was 0.9. The organic matter removal rate never became less than 85.0% under a 3,000 mg/L chloride concentration. The multiple decay rate coefficients ($k_1$) were $0.1603{\sim}0.1709\;day^{-1}$ under $3,000\;mgCl^-/L$, and $0.0492{\sim}0.0760\;day^{-1}$ in more than $6,000\;mgCl^-/L$. The multiple decay rate coefficients ($k_2$) were $0.0183{\sim}0.0348\;day^{-1}$ under $6,000\;mgCl^-/L$, and $0.0154\;day^{-1}$ at $9,000\;mgCl^-/L$. With increasing chloride concentrations, the reaction rate ($k_1$, $k_2$) and ratio of the rapidly degraded organic matter ($S_1$) decreased.

Sonolysis of Trichloroethylene in a Continuous Flow Reactor with the Multi Ultrasound Irradiation (연속식 다중 초음파 반응조에서 TCE의 초음파 분해)

  • Lee, Min-Ju;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.6
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    • pp.419-427
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    • 2009
  • To test applicability for continuous flow treatment of ultrasound technology, sonolysis of TCE aqueous solution using 584 kHz multi irradiation reactor was performed under batch and continuous flow conditions. Under batch condition (3 and 4 sides irradiation, 600 W), first order degradation rate constant of TCE was higher under 4 sides than 3 sides irradiation conditions, while the generation of $H_2O_2$ and chloride was similar under both irradiation conditions. Under continuous flow condition with 4 sides irradiation, removal efficiencies of TCE in steady-state were decreased from 83 to 48% with increasing flow rate from 67 to 300 mL/min at 600 W, and were increased from 14 to 75% with increasing acoustic power from 100 to 600 W at 100 mL/min. Removal efficiency of TCE in groundwater was decreased 10% compared to in distilled water at 100 mL/min and 600 W.

Kinetic Modelling for the Prediction of Shelf-life of Kimchi Based on Total Acidity as a Quility Index (총산도를 기준한 김치의 품질수명 예측모델 연구)

  • Lee, Kwang-Hyuck;Cho, Hyung-Yong;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.306-310
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    • 1991
  • A simplified mathematical model to estimate changes in total acidity of Chinese cabbage kimchi during fermentation was developed as a function of temperature and salt concentration. Assuming that tolerable acceptability reached at 0.75% total acidity, the shelf-life of kimchi was predicted by the model. The predicted value was in good agreement with the actual shelf-life measured by organoleptic tests.

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