• 상하수도학회지
• /
• 제25권4호
• /
• pp.527-534
• /
• 2011

In this research, the photocatalytic degradation of dibenzothiophene (DBT) in $TiO_2$ aqueous suspension has been studied. $TiO_2$ photocatalysts are prepared by a sol-gel method. The dominant anatase-structure on $TiO_2$ particles is observed after calcining the $TiO_2$ gel at $500^{\circ}C$ for 1hr. Photocatalysts with various transition metals (Nd, Pd and Pt) loading are tested to evaluate the effect of transition metal impurities on photodegradation. The photodegradation efficiencies with $TiO_2$ including Pt and Pd are higher than pure $TiO_2$ powder. Also we investigated the applicability of $H_2O_2$ to increase the efficiency of the $TiO_2$ photocatalytic degradation of dibenzothiophene. The degradation efficiency increases with increasing dosage of $H_2O_2$ in the range of 0.01M to 0.1M . The effect of pH is investigated; we obtained the maximum photodegradation efficiency at pH 5. In addition, the intermediate analysis found dihydroxyl -dibenzothiophene as a reaction intermediate of dibenzothiophene during the photodegradation.