• Title/Summary/Keyword: 다성분

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Modeling of Multicomponent Mixture Separation Processes Using Hollowfiber Membrane (중공사막을 이용하는 다성분 혼합물 분리공정의 모델링)

  • Kim, Sin-Ah;Kim, Jin-Kuk;Lee, Young Moo;Yeo, Yeong-Koo
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.22-30
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    • 2015
  • So far, most of research activities on modeling of membrane separation processes have been focused on binary feed mixture. But, in actual separation operations, binary feed is hard to find and most separation processes involve multicomponent feed mixture. In this work models for membrane separation processes treating multicomponent feed mixture are developed. Various model types are investigated and validity of proposed models are analysed based on experimental data obtained using hollowfiber membranes. The proposed separation models show quick convergence and exhibit good tracking performance.

Establishment of Simultaneous Analysis Method for the Detection of Multi-Pesticide Residue Used in Golf Courses (골프장 농약 검사를 위한 다성분 동시분석방법 확립에 관한 연구)

  • Yun, Jeong-Ki;Lee, Min-Hyo;Noh, Hoe-Jung;Park, Jong-Gyum;Kim, Hyuk;Kim, Chan-Sub
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.18-24
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    • 2006
  • The possibility of multiresidue analysis of 24 pesticides out of 30 residual pesticides which are subjected to test in the golf courses was examined. The utility of multiresidue method for pesticide residue test was evaluated by recovery test through a standard addition method of pesticides in water, soil, and lawn grass. The experimental results of the recovery test for individual pesticides are as follows : The number of pesticide of which average recovery rate was over 70% regardless of media was 16 pesticides. These pesticides were composed of 8 organophosphorus pesticides (chlorpyrifos, chlorpyrifosmethyl, diazinon, EPN, fenitrothion, phenthoate, phosalone, and toclofos-methyl). 4-organochlorinated pesticides (daconil, captan, endosulfan, and tetradifon), 2-pyrethroid pesticides(fenpropathrin, lambda-cyhalothrin) and 2 other pesticides (bromopropylate, pendimethalin). On the other hand, in case of dicofol, average recovery rate was over 70% for water and lawn grass but only 53.3% for soil. Therefore, the multiresidue method applied in this experiment is not appropriate for analysis of dicofol in soil. Furthermore, among 7 pesticides, 2 pesticides(amitraz and pyraclofos) showed that theirs average recovery rate deviated from criteria($70{\sim}130%$) in almost ail media, while 5 pesticides(bensulide, deltamethrin, iprodione, phosphamidon and tralomethlin) were not detected from all media by GC/NPD or GC/ECD.

Polarization Filters Using the Multicomponent Complex Trace Analysis (다성분 복소트레이스를 이용한 분극필터)

  • Kim, Ki-Young;Lee, So-Young
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.89-94
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    • 2006
  • In order to increase the signal-to-noise ratio in multi-component seismic data, we developed new polarization filters based on the method of multicomponent complex trace analysis. Unlike the previous polarization filters, the present filters separately compute linear and elliptic components at each time sample using amplitude ratio of horizontal and vertical components of body waves and ellipticity of Rayleigh waves. The polarization filters work ideally even with low S/N data. Application of the filters to both synthetic and real seismic data shows that Rayleigh waves of elliptic motions are effectively eliminated and both P and S waves of linear motions are well separated each other.

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Effective Wavefield Separation of Reflected P- and PS-Waves in Multicomponent Seismic Data by Using Rotation Transform with Stacking (다성분 탄성파탐사자료에서 회전 변환과 중합을 이용한 효과적인 P파 반사파와 PS파 반사파의 분리)

  • Jeong, Soocheol;Byun, Joongmoo;Seol, Soon Jee
    • Geophysics and Geophysical Exploration
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    • v.16 no.1
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    • pp.6-17
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    • 2013
  • Multicomponent seismic data including both P- and PS-waves have advantages in discriminating the type of pore fluid, characterizing the lithologic attributes and producing the high resolution image. However, multicomponent seismic data recorded at the vertical and horizontal component receivers contain both P- and PS-waves which have different features, simultaneously. Therefore, the wavefield separation of P- and PS-waves as a preprocessing is inevitable in order to use the multicomponent seismic data successfully. In this study, we analyzed the previous study of the wavefield separation method suggested by Jeong and Byun in 2011, where the approximated reflection angle calculated only from one refernce depth is used in rotation transform, and showed its limitation for seismic data containing various reflected events from the multi-layered structure. In order to overcome its limitation, we suggested a new effective wavefield separation method of P- and PS-waves. In new method, we calculate the reflection angles with various reference depths and apply rotation transforms to the data with those reflection angles. Then we stack all results to obtain the final separated data. To verify our new method, we applied it to the synthetic data sets from a multi-layered model, a fault model, and the Marmousi-2 model. The results showed that the proposed method separated successfully P- and PS-reflection events from the multicomponent data from mild dipping layered model as long as the dip is not too steep.

Development of Multi-residue Analysis of 320 Pesticides in Apple and Rice Using LC-MS/MS and GC-MS/MS (LC-MS/MS와 GC-MS/MS를 이용한 사과와 쌀 시료에서 320종 농약의 다성분 분석)

  • Kim, Jong-Hwan;Kim, Yeong-Jin;Kwon, Young-Sang;Seo, Jong-Su
    • The Korean Journal of Pesticide Science
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    • v.20 no.2
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    • pp.104-127
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    • 2016
  • A new analytical method has been developed to determine 320 pesticides in apple and rice. The extraction of pesticides was carried out based on QuEChERS sample extraction, and determination was performed using LC-MS/MS and GC-MS/MS. 320 pesticides were selected for experiments. 251 and 110 pesticides among them were analysed by LC-MS/MS and GC-MS/MS, respectively. 41 pesticides of them were analyzed by both GC-MS/MS and LC-MS/MS. Among pesticides analysed by LC, 242 pesticides (96% of total number) in apple and 237 pesticides (94% of total number) in rice showed recoveries in the range of 70~120% with RSD ${\leq}20%$. In case of pesticides analyzed by GC-MS/MS, 103 pesticides (94% of total number) in apple and 83 pesticides (76% of total number) in rice were successfully validated. These results indicated that LC-MS/MS and GC-MS/MS analysis with the QuEChERS sample preparation can be partly applied to multi-residue pesticides in agricultural products.

Separation of Seismic Signals using a Polarization Filter based on the Complex Trace Analysis Method (복소트레이스 분극필터를 이용한 다성분 탄성파자료 신호분리)

  • Kim, Ki-Young;Lee, So-Young
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.233-236
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    • 2005
  • Polarization filtering based on the multicomponent complex trace analysis method is performed to reject Rayleigh waves and to enhance S waves. To test the polarization filter, synthetic seismic data were constructed for a simple two-layer model based on the finite difference method. Rayleigh waves with elliptic motion are eliminated effectively and P and S waves with linear motions are well separated each other.

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Separation of Seismic Signals using a Polarization Filter based on the Complex Trace Analysis Method (복소트레이스 분극필터를 이용한 다성분 탄성파자료 신호분리)

  • Kim, Ki-Young;Lee, So-Young
    • Journal of the Korean Geophysical Society
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    • v.8 no.1
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    • pp.35-38
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    • 2005
  • Polarization filtering based on the multicomponent complex trace analysis method is performed to reject Rayleigh waves and to enhance S waves. To test the polarization filter, synthetic seismic data were constructed for a simple two-layer model based on the finite difference method. Rayleigh waves with elliptic motion are eliminated effectively and P and S waves with linear motions are well separated each other.

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차세대 나노 박막 다원계 모물질 설계, 합성 기술

  • Mun, Gyeong-Il;Sin, Seung-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.121-121
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    • 2012
  • 산업이 고도화, 다원화, 세계화되고 있는 현대사회는 다기능성, 고물성, 극한 내구성을 가지며 환경 친화적이면서 에너지 효율을 극대화시킬 수 있는 다기능 소재의 개발을 요구하고 있다. 이러한 시점에서 다양한 물성을 동시에 발현이 가능한 코팅 소재는 향후 미래에 중요한 원천 소재로서 주목되고 있다. 특히, 환경에 의해 쉽게 물성 및 구조의 변화가 쉬운 종래의 코팅소재와는 달리, 다양한 외부환경에서도 미세 구조 및 물성을 안정적으로 유지할 수 있는 신개념의 코팅 소재의 개발이 절실히 요구되고 있다. 이를 위해서는 코팅소재의 다 성분화가 필수적이다. 최근의 코팅 기술은 2가지 이상의 물성, 특히 서로 상반되는 물성을 동시에 구현할 수 있는 소재의 개발을 요구하고 있다. 이러한 물성의 구현을 위하여 더 많은 성분으로 구성되며 더욱 복잡한 조직으로 구성된 코팅층에 대한 개발이 진행이 필요하다. 본 연구에서 목표로 하는 신 개념의 원천소재기술은 4성분계 이상의 원료 물질을 단일 타겟으로 제조하여, 단순한 공정으로서 단일 코팅층 내에 다양한 성분과 10 nm 미만 크기의 나노 결정립/나노 비정질로 구성된 나노 복합 구조의 형성이 가능하도록 하는 기술을 개발하고자 한다. 이를 통해 복합기능 3 이상의 다기능성 부여는 물론, 그림 1에 정리된 기존 코팅재에서 결여된 특성을 포함한 극한 기능성(광대역 윤활성, 전자 이동 제어에 의한 온도 저항 계수 및 전기 저항 조절, 고온 열적 안정성, 내산화성, 고열전도율, 초저마찰/내구성/초고경도성 등)의 구현이 가능한 복잡한 형태의 나노 복합 코팅층 소재 개발이 가능하도록 하는 기술이다. 또한 기존 코팅재의 구조적 결함을 통해 발생하는 내식성 문제를 방지할 수 있는 기술이다. 다성분계 모물질의 개발이 중요한 이유는 다수의 성분 원소를 합금 상태로 형성시킴으로서, 단일 소스에 의해 다양한 원소를 동시에 스퍼터링 및 증착이 가능하도록 할 수 있다는 장점을 가지기 때문이다. 특히, 타겟의 미세구조를 나노구조화 하는것을 통해, 스퍼터링 yield의 차이가 큰 원소일지라도 균일하게 증착시킬 수 있는 방법을 개발하고자한다. 또한 다수의 타겟을 이용하여 균일한 다성분 코팅층 형성하는 기존의 PVD 코팅방법으로는 다수의 성분타겟을 사용함으로서 장비의 복잡성, 코팅의 재현성, 대형화 등의 문제점을 본질적으로 갖고 있다. 이를 위한 해결방법으로 본 발표에서는 3가지 이상의 다기능성 구현을 위한 가장 중요한 원천기술이라 할 수 있는 다성분계 타겟 모물질 제조 기술의 개발 진행 사항에 대해 소개하고자 한다.

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A Comparative Analysis on characteristics and Manufacture of Methane/Natural Gas Hydrates (메탄/천연가스 하이드레이트의 제조 및 특성 비교 분석)

  • Lee Young-Chul;Cho Byoung-Hak;Baek Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.7 no.3 s.20
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    • pp.32-43
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    • 2003
  • As this paper is observed the phase equilibrium diagram of mono- (methane) and multi-component(natural gas) hydrates, and the hydrate growth behavior is analysed and compared by the experiments during the reaction. The difference of mono and multi-component hydrates is an induction delay time and a plateau region. And the concentration of component of gases is changed during the reaction in multi-component hydrates and the concentration of components is changed during the decomposition of hydrate according to each decomposing rates of gases. At 6 MPa, 276.65 K and 600 rpm, the induction delay time of multi-component hydrate formation is observed shorter than that of mono-component hydrate formation because the hydrate nuclei of gases except methane form faster than those of methane. And the plateau region of mono-component hydrate is observed distinctly at 0.055 mole of $CH_4$/mole of water and that of multi-component hydrate is observed at 0.04 mole of $CH_4$/mole of water.

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