• Title/Summary/Keyword: 다단 반응

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Nitrogen Removal from Wastewater by a Multi-stage Bio-reactor (다단 생물반응기에 의한 질소제거)

  • 최규철;정일현
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.91-103
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    • 1998
  • Design data for COD and nitrogen removal from wastewater were collected from Pilot's Multi-stage Bio-reactor. Hyraulic conditions and pollutant loadings were varied in order to optimize the biological and operational parameters. Pilot's experimental results summarize as followings. 1. T-N removal efficiency in the organic volumetric loading 0.2 kgCOD/m$^{3}$·d was obtained as maxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.. 2. Nitrification reaction was shown as maxium in the SCOD$_{cr}$/NH$^{+}$-N ratio of 6.5 and in more ratio than this it was decreased. Denitrification rate was the maxium as 85% in more than 7.5 of SCOD$_{cr}$/NO$_{x}$-N ratio and in the ratio over this ratio it becomes constant. 3. By utilizing an applied new model of Stover-Kincannon from Monod's kinetic model, concentration of T-N in the effluent according to flow quanity in the influent was estimated as 8.74 and -67.5 respectively. The formula for estimating T-N concentration of effluent was obtained like this: N$_e$=N$_0$(1- $\frac{8.74}{(QN$_0$/A)-67.05}$)

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Decomposition and Leaching of Bastnasite by Sulfation and Recovery of Cerium Hydroxide from Leached Solution (황산화반응에 의한 불탄산염 희토류광(Bastnasite)의 분해, 침출 및 세륨수산화물의 회수)

  • Yoon, Ho-Sung;Kim, Sung-Don;Kim, Chul-Joo;Kim, Jun-Soo;Han, Choon
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.407-412
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    • 1998
  • This study was carried out to investigate the optimum leaching conditions for the sulfation and water leaching, and separation of cerium from rare earth elements in leached solution by acid-adjusting method. The optimum conditions for the sulfation and water leaching from bastnasite concentrates are that the equivalent ration of sulfuric acid to concentrates is 2.5, calcination temperature and time are $600^{\circ}C$ and 2 hrs respectively, and the pulp density in the water leaching is 9.1%. The yield of rare earth oxide is about 93% at the above condition. The process of recovery of cerium hydroxide from leached solution by acid-adjusting method was carried out as following steps. The first step is the oxidation of the solution at pH 5 by using twice the equivalent of $H_2O_2$ solution as an oxidant. The second step is the precipitation to obtain cerium complex salt and cerium hydroxide after lowering the solution to pH 2. The last step is the oxidation-precipitation by using equivalent of $H_2O_2$ solution. From these results, it was possible to prepare cerium hydroxide with the yield of 60% and the quality of 80%.

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Reduction of Dehydrated Cake by the Optimization of Flocculation Factors and the Single Flocculant/Dual Flocculation System (응집인자 최적화 및 다단응집 시스템을 이용한 탈수 케이크 감량)

  • Kim, Hyung-Jun;Bae, Young-Han;Lee, Sang-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.839-846
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    • 2008
  • The flocculation characteristics of polyacrylamide base flocculants were estimated to reduce the moisture content of the dehydrated cakes. The dewaterability for sewage sludge was found to have a marked effect depending on the flocculant type, agitating speed and time, kind of dissolution water, etc. The optimal agitating speed and time were 700 rpm and 3 sec, respectively, in this experimental condition. and the dewaterability was proportion to the agitating speed upto 700rpm. When recycle water as the dissolution water was used, the solution viscosity of all kind of flocculants was decreased. However, the change of its viscosity are not proportioned to the dewaterabilities for each flocculant. Flocculation system of combinations of the first and sencond flocculation using single flocculant was investigated. Effects of the ratio of first and second dosage for dual flocculation on the dewaterability were also investigated. The optimum conditions of dual flocculation system are 75% and 50% as first dosages for low and high viscous flocculant for total dosage of common flocculation, respectively. Based on the results, an overall mechanism of dual flocculation system is proposed and it is envisaged that optimization of flocculation processes in this way can result in considerable savings in cost.

Comparison of Removal Characteristics of Organic Matter, Nitrogen and Phosphorus Between Suspended-Growth and Attached-Growth Biological Processes (부유 및 부착성장 미생물을 이용하는 공정의 유기물, 질소 및 인 제거 특성 비교)

  • Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.206-214
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    • 2005
  • This study was initiated to evaluate efficiencies of suspenced-growth processes(CAS; Conventional Activated Sludge, MLE; Modified Ludzack-Ettinger) and hybrid process(Modified-Dephanox) on removal of organic matter(C), nitrogen(N) and phosphorus(P) in municipal wastewater. M-Dephanox process was designed to improve the performance of Dephanox process on denitrification efficiency. As the results, removal efficiencies of total chemical oxygen demand(TCOD), total nitrogen(T-N) and total phosphorus(T-P) in M-Dephanox process, which is hybrid process, were 12,3, 18.6 and 28.2% higher than those in MLE, which is suspended-growth process. The better removal efficiencies of TCOD, T-N and T-P in M-Dephanox than those in MLE result that M-Dephanox is not only hybrid or multi-sludge process but also process using biosorption mechanism which is possible to use organics in denitrification, effectively. Ammonia removal efficiency in nitrification reactor of M-Dephanox was 96.7% at short hydraulic retention time(HRT) of 2 hr which was 3 hr more short HRT than that(HRT 5 hr) reported in other related papers. This indicates that M-Dephanox process can reduce HRT of whole process.

Design and fabrication of GaAs MMIC high power amplfier and microstrip combiner for IMT-2000 handset (IMT-2000 고출력 전력전폭기의 GaAs MMIC화 및 전송결합기 설계 구현에 관한 연구)

  • 정명남;이윤현
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.11A
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    • pp.1661-1671
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    • 2000
  • 본 고에서는 한국통신(Korea Telecom) IMT-2000 시험시스템(이하: Trial system 라고 함) 단말기용 전력증폭단으로 적용하기 위한 다단구동증폭기 및 전력증폭기를 GaAs MMIC로 설계 구현하는 기술을 제시하였다. 설계된 구동증폭기는 3단으로구성하여 RF(Radia Frequency) 송신신호(1955$\pm$70MHz)대역에서 2단 (중간단)의 이득 조정범위가 40 dB이상이 될 수 있도록 능동부품인 MESFET를 Cascade 형으로 구성하고 MESFET의 게이트(gate)에 조정전압을 인가하는 증폭기를 설계하여 GaAs MMIC화 1 침(크기4$\times$5 mm)으로 제작하였다. 아울러, 본 논문에서는 제시한 구동증폭기는 동작주파수 대역폭 범위기 3.5배이고 출력전력은 15dBmm 이며, 출력전력이득이 25~27dB이고 반사계수는 -15~20dB이며 이득평탄도 3dB(동작주파수 대역폭내)로써 Trial system용 단말기의 최종단인 전력증폭단의 출력단 특성을 효과적으로 나타내었다. 그리고, 전력 증폭기는 2개의 입력단에서 출력되는 신호를 분배하는 전력분배기와 병렬구조인 4개의 증폭단에서 출력되는 출력신호를 외부에서 접속하는 전력결합기를 접소하여 구성하였으며 RF(Radio Frequency) 주파수(1955 $\pm$70NHz)에서 대역폭을 4배로 설계하여 광대역인 대역폭을 구현하였고 출력전력은 570mW이며, 출력부가효율(PAE; Power Added Efficency)가 -15$\pm$20dB이고, 이득 평탄도(Gain flatness)는 동작주파수 대역내에서 0.5dB이며 입출력 전압정재파비(Input & Output VSWR)가 13이하인 고출력 전력증포기를 GaAs MMIC화 1칩 (크기; 3$\times$4mm)으로 제작하였다.의 다양성이나 편리성으로 변화하는 것이 국적을 바꾸는 것보다 어려운 시 대가 멀지 않은 미래에 도래할 것이다. 신세기 통신 과 SK 텔레콤에는 현재 1,300만명이 넘 는 고객이 있으며. 이들 고객은 어 이상 음성통화 중심의 이동전화 고객이 아니라 신세기 통신과 SK텔레콤이 함께 구축해 나갈 거대란 무선 네트워크 사회에서 정보화 시대를 살아 갈 회원들이다. '컨텐츠의 시대'가 개막되는 것이며, 신세기통신과 SK텔레콤은 선의의 경쟁 과 협력을 통해 이동인터넷 서비스의 컨텐츠를 개발해 나가게 될 것이다. 3배가 높았다. 효소 활성에 필수적인 물의 양에 따른 DIAION WA30의 라세미화 효율에 관하여 실험한 결과, 물의 양이 증가할수록 그 효율은 감소하였다. DIAION WA30을 라세미화 촉매로 사용하여 아이소옥탄 내에서 라세믹 나프록센 2,2,2-트리플로로에틸 씨오에스터의 효소적 DKR 반응을 수행해 보았다. 그 결과 DIAION WA30을 사용하지 않은 경우에 비해 반응 전환율과 생성물의 광학 순도는 급격히 향상되었다. 전통적 광학분할 반응의 최대 50%라는 전환율의 제한이 본 연구에서 찾은 DIAION WA30을 첨가함으로써 성공적으로 극복되었다. 또한 고체 염기촉매인 DIAION WA30의 사용은 라세미화 촉매의 회수 및 재사용이 가능하게 해준다.해준다.다. TN5 세포주를 0.2 L 규모 (1 L spinner flask)oJl에서 세포간의 응집현상 없이 부유배양에 적응,배양시킨 후 세포성장 시기에 따른 발현을 조사한 결과 1 MOI의 감염조건 하에서는 $0.6\times10^6$cell/mL의 early exponential시기의 세포밀도에서 72시간 배양하였을 대 최대 발현양을 나타내었다. 나타내었다. $\beta$4 integrin의 표현이 침투 능력을 높이는 역할을 하나 이때에는 laminin과 같은 리간드와의 특이

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Pig slurry treatment by the pilot scale hybrid multi-stage unit system (HMUS) followed by sequencing batch reactor (SBR) (HMUS와 SBR 반응조를 이용한 축분처리에 관한 연구)

  • Lee, Young-Shin;Han, Gee-Bong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.2
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    • pp.63-70
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    • 2013
  • Experiments in a pilot-scale hybrid multi-stage unit system (HMUS) combination of ATAD and EGSB followed by SBR process for pig slurry treatment were conducted to demonstrate the feasibility of using autothermal thermophilic aerobic digestion (ATAD) and expended granular sludge bed (EGSB) followed by sequencing batch reactor (SBR) system. Contaminants in pig slurry with high organic matter, nitrogen (N) and phosphorus (P) content were completely removed in the combined process. The highest removal rate for CODcr among contaminants in the feed pig slurry was attained by about 43.3% in ATAD unit process. Also TS removal rate of 96.5% was attained and the highest in the next coagulation unit process. The highest removal rate of CODcr under operating parameter conditions of OLR(organic loading rate), 3-6Kg $COD/m^3{\cdot}day$ and line velocity, 1.5-4m/h was earned at 3days of HRT. The disinfection of pathogens was effective at 50,000mg/L of TS in ATAD unit process. Biogas production per organic removal was $2.3{\sim}8.5m^3/kgTS{\cdot}d$ (average $5.2m^3/kgTS{\cdot}d$) in EGSB unit process. The average removal rates of CODcr 71.7%, TS 64.1%, TN 45.9%, and TP 50.4% were earned in the intermittent aeration SBR unit process.

Solid Flow Rate and Gas Bypassing with Operating Variables of J-valve in Multistage Annular Type Fluidized Beds (다단 환원형 유동층에서 J-valve의 운전변수에 따른 고체 흐름량 및 기체 우회)

  • Hong, Yoon-Seok;Kang, Gyung-Soo;Park, Joo-Sik;Lee, Dong-Hyun
    • Clean Technology
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    • v.17 no.1
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    • pp.62-68
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    • 2011
  • Hydrodynamic characteristics in multistage annular type fluidized bed (riser: $0.01{\times}0.025{\times}2.8m^3$, J-valve: $0.009{\times}0.015m^2$)were investigated. Glass beads ($d_p=101{\mu}m$, ${\rho}_b=1,590kg/m^3$, $U_{mf}=1.25{\times}10^{-2}m/s$, Geldart classification B) was used as a bed material. Accumulated weight by the electronic balance was measured to determine the solid flow rate in batch-type. In circulation condition, we measured the accumulated weight of particle transported from riser. At the steady state condition, solid circulation rate was calculated from time interval of the heated bed material passing between two thermocouples. Solid flow rate increased with increasing inlet gas velocity ($1.2-2.6U_{mf}$) and the static bed height (z, 0.24-0.68 m) from 2.2 to 23.4 kg/s. However, mean residence time decreased with increasing inlet gas velocity ($1.2-2.6U_{mf}$) and the static bed height (z, 0.24-0.68 m) from 1,438 to 440 s. The solid holdup in the riser was determined by measuring pressure differences according to the riser height. These results showed a similar trend to that of simple exponential decay type except for the top section of the riser. To verify the gas bypassing from top bubbling beds to middle bubbling beds, $CO_2$ gas was injected by tracer gas in constant ratio, and then was measured $CO_2$ concentration in outlet gas by gas chromatography. Gas bypassing occurred below 2.6% which is negligible value.

Recovery of Silver from Nitrate Leaching Solution of Silicon Solar Cells (실리콘 태양전지 질산침출액에서 LIX63를 이용한 은(Ag) 회수)

  • Cho, Sung-Yong;Kim, Tae-Young;Sun, Pan-Pan
    • Resources Recycling
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    • v.30 no.2
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    • pp.39-45
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    • 2021
  • Spent photovoltaic module is one of the important resource of silver, while related research concerning silver recovery remains limited. In our previous research, HNO3 was utilized to dissolve Ag(I) and Al(III) from the spent silicon solar cells. In order to recover Ag(I) from the leachate of a silicon solar cell, the present study made use of a nitrate solution containing Ag(I) and Al(III), which was subjected to a solvent extraction process with 5,8-diethyl-7-hydroxydodecan-6-oxime (LIX63). Ag(I) was selectively extracted with LIX63 over Al(III) from the nitrate leach solution. Subsequently, quantitative stripping of Ag(I) from the loaded LIX63 was performed by using 20% ammonia water. The McCabe-Thiele plots for the extraction and stripping isotherms of Ag(I) were also constructed. Extraction and stripping simulation tests confirmed an Ag(I) extraction and stripping efficiency of >99.99% and 98.9%, respectively with high purity Ag (99.998%) and Al (99.99%) solution. A process flow sheet for Ag(I) recovery from the nitrate leach solution was proposed.

Anaerobic Organic Wastewater Treatment and Energy Regeneration by Utilizing E-PFR System (E-PER 반응기를 이용한 유기성 폐기물의 혐기성 처리와 재생에너지 생산에 관한 연구)

  • Kim, Burmshik;Choi, Hong-Bok;Lee, Jae-Ki;Park, Joo Hyung;Ji, Duk Gi;Choi, Eun-Ju
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.2
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    • pp.57-65
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    • 2008
  • Wastewater containing strong organic matter is very difficult to treat by utilizing general sewage treatment plant. but the wastewater is adequate to generate biomass energy (bio-gas; methane gas) by utilizing anaerobic digestion. EcoDays Plug Flow Reactor (E-PFR), which was already proved as an excellent aerobic wastewater treatment reactor, was adapted for anaerobic food wastewater digestion. This research was performed to improve the efficiency of bio-gas production and to optimize anaerobic wastewater treatment system. Food wastewater from N food waste treatment plant was applied for the pilot scale experiments. The results indicated that the efficiency of anaerobic wastewater treatment and the volume of bio-gas were increased by applying E-PFR to anaerobic digestion. The structural characteristics of E-PFR can cause the high efficiency of anaerobic treatment processes. The unique structure of E-PFR is a diaphragm dividing vertical hydraulic multi-stages and the inversely protruded fluid transfer tubes on each diaphragm. The unique structure of E-PFR can make gas hold-up space at the top part of each stage in the reactor. Also, E-PFR can contain relatively high MLSS concentration in lower stage by vertical up-flow of wastewater. This hydraulic flow can cause high buffering capacity against shock load from the wastewater in the reactor, resulting in stable pH (7.0~8.0), relatively higher wastewater treatment efficiency, and larger volume of bio-gas generation. In addition, relatively longer solid retention time (SRT) in the reactor can increase organic matter degradation and bio-gas production efficiency. These characteristics in the reactor can be regarded as "ideal" anaerobic wastewater treatment conditions. Anaerobic wastewater treatment plant design factor can be assessed for having 70 % of methane gas content, and better bio-gas yielding and stable treatment efficiency based on the results of this research. For example, inner circulation with generated bio-gas in the reactor and better mixing conditions by improving fluid transfer tube structure can be used for achieving better bio-gas yielding efficiency. This research results can be used for acquiring better improved regenerated energy system.

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Biological treatment process for Food wastewater Using ER-1 bioreactor (다단 수직형 호기성반응기(ER-1)를 이용한 음식물 폐수의 생물학적 처리기술)

  • Lee, Jae-ki;Choi, Hong-Bok;Shin, Eung-Bai;Park, Ju-Hyoung;Choi, Eun-Ju;Kim, Jung-Rae;Park, Young-Sook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.4
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    • pp.113-120
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    • 2006
  • Wastewater generated through the food waste recycling process have known high concentration, BOD 20,000~150,000 mg/L, which has to treat to the proper level because of a ban on reclamation. But it is impossible to treat less than 10 days by existing water treatment plant. Ecodays Ltd. is to treat this wastewater during 2~4 days by ER-1, which can simultaneously induce the modified PFR(Plug Flow Reactor) of the oxygen transfer rate, MLVSS concentration, and influent concentration to top from bottom of reactor. We tested the pilot test about low concentration food wastewater(BOD 16,500 mg/L) and high concentration food wastewater(64,431 mg/L) at the food waste recycling plant of H-Gun(20t/d). Hydraulic retention time(HRT) of ER-1 for low concentration food wastewater is 2.5day. In low concentration conditions, ER-1 treatment efficiency is to appear BOD 99%, COD 98%, TN 97%, and TP 96%. While ER-1 process for high concentration food wastewater treatment is composed 2 stages, which are to be HRT 2.5day for law wastewater and HRT 1.5 day for secondary treatment. In high concentration conditions, ER-1 treatment efficiency is to appear BOD 97%, COD 84%, TN 66%, and TP 95%. It is treated without temperature control about high temperature($50^{\circ}C$) to appear low treatment efficiency in high concentration conditions.

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