• Title/Summary/Keyword: 다단반응

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Characteristics of UBC and NOx Emission in Air Staging Combustion (공기 다단 연소 기법 적용에 따른 미연탄소분 및 질소산화물 배출특성)

  • Kim, Jeong Woo;Lim, Ho;Go, Young Gun;Jeon, Chung Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.10
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    • pp.637-644
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    • 2016
  • The purpose of this study is to understand the characteristics of unburned carbon (UBC) and NOx emissions for pulverized coal when air staging combustion is applied. A two-staged drop tube furnace capable of applying air staging combustion was designed and installed. The combustion of sub-bituminous (Tanito) has been investigated. UBC and the NOx concentration were measured under various temperatures and stoichiometric ratios in unstaged and staged combustion. As a result, UBC decreased and the NOx concentration increased with an increase in stoichiometric ratio and temperature. In particular, the NOx reduction mechanism was activated when the temperature in the fuel rich zone increased. Both UBC and the NOx concentration decreased as the temperature increased in the fuel rich zone. A high NOx reduction effect was obtained, compared to the UBC increase, when the air staging technique was applied.

Development of RTD Model of the Mixer-Settler-Type Extractor Using the Stimulus-Response Method (자극-반응법(反應法)을 이용(利用)한 혼합침강형(混合沈降型) 추출장치(抽出裝置)의 RTD 모델 개발(開發))

  • Lee, Jin-Young;Kim, Joon-Soo;Lee, Hoo-In;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.16 no.5
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    • pp.65-70
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    • 2007
  • This study presents the findings of the experiments that were conducted on single- and multi-stage solvent extractors using the stimulus-response method, with the am of identifying flow characteristics of the material inside the mixer-settler-type extractor. The results of this study show that the response characteristics of a single-stage mixer is the same as that of a completely stirred tank reactor (CSTR), and that the lag time of a mixer-settler-type extractor increases with the number of its extraction stages. The experimental data for the single- and multiple-stage extractors were analyzed using K-RTD, a response analysis program, to obtain a retention time distribution (RTD) model of one-stage and four-stage extractors. The correlation coefficient between the calculated values and the experimental data was 0.963 for the one-stage extractor and 0.995 for the four-stage extractor, showing quite a good correlation.

Numerical Analysis of Turbulent Combustion of a Kerosene/Oxygen Coaxial Injector with a Recess (리세스가 있는 케로신/산소 동축 분사기의 난류 연소 유동 해석)

  • Choi, Jeong-Yeol;Shin, Jae-Ryul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.77-78
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    • 2011
  • A multi-step quasi-global mechanism is developed for the kerosene/oxygen combustion analysis including dissociation products. Reaction constants of the global reaction are determined to have agreement with experimental data. The mechanism is used for the numerical analysis of the combustion flow field of the kerosene/oxygen shear coaxial injector. The results from high-resolution numerical analysis confirmed qualitatively that the recess enhance the fuel/air mixing and combustion efficiency by the increased flow instabilities.

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Numerical Study on the Effect Recess on the Turbulent Combustion of Kerosene/LOx Coaxial Rocket Injector (케로신-산소 로켓 동축 분사기 난류 연소에서 리세스의 영향에 대한 수치해석)

  • Choi, Jeong-Yeol;Shin, Jae-Ryul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.92-95
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    • 2011
  • A multi-step quasi-global mechanism is developed for the kerosene/oxygen combustion analysis including dissociation products. Reaction constants of the global reaction are determined to have agreement with experimental data. The mechanism is used for the numerical analysis of the combustion flow field of the kerosene/oxygen shear coaxial injector. The results from high-resolution numerical analysis confirmed qualitatively that the recess enhance the fuel/air mixing and combustion efficiency by the increased flow instabilities.

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Onset and Propagation of Hydrogen-Air Premixed Flame with Multiple Kinetics (다단 반응을 고려한 수소-공기 예혼합 화염의 발생 및 전파)

  • Han Cho Young;Baek Seung Wook
    • Journal of computational fluids engineering
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    • v.9 no.1
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    • pp.25-33
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    • 2004
  • Flame onset and propagation within hydrogen premixed gas mixture are numerically investigated in an rectangular enclosure. A detailed chemistry for hydrogen reaction is applied to anticipate the thermochemical behavior of intermediate species appropriately. To facilitate computation, 10 species and 16 elementary reaction steps for hydrogen combustion are taken into account. On the basis of 30% of hydrogen concentration in hydrogen-air mixture, the effects of position and quantity of ignition sources on the flame evolution are analyzed. From the simulation results, the methods to decrease the potential hazard caused by the flame propagation are suggested.

The Effect of Partitioning Porous Plate on Bubble Behavior and Gas Hold-up in a Bench Scale (0.36 m × 22 m) Trayed Bubble Column (벤치스케일(0.36 m × 22 m) 다단형 기포탑에서 다공판이 기포의 거동 및 기체 체류량에 미치는 영향)

  • Yang, Jung Hoon;Hur, Young Gul;Lee, Ho-Tae;Yang, Jung-Il;Kim, Hak-Joo;Chun, Dong Hyun;Park, Ji Chan;Jung, Heon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.505-510
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    • 2012
  • The gas hold-up has a strong relationship with the size distribution and rising velocities of bubbles in a bubble column. Therefore, many previous researchers have studied on the hydrodynamics focusing on the bubble size variation in bubble column. In this study, the bubble behavior was influenced by partitioning porous plates installed at a certain height in a trayed bubble column. The gas hold-up was increased in non-sparging region (H/D > 5) as well as sparging region. We identified the effect of the partitioning porous plate using three trayed bubble columns with different reactor geometries. Furthermore, the bubble break-up frequency and size distribution were observed before and after individual bubbles penetrated through the plate. The arrangement of the plates was also investigated using a 0.15-m-in-diameter bubble column. Based on the result, we applied this design concept to a 0.36-m-in-diameter, 22 m tall trayed bubble column and identified the effect of the partitioning porous plate on the gas hold-up increase.

Numerical Analysis on the Autoignition of Hydrogen/Air Mixture Near a Hot Surface (고온벽면에 의한 수소-공기 예혼합기체의 자연발화에 관한 수치적 해석)

  • 박은성;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.1
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    • pp.70-76
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    • 1992
  • Ignition of hydrogen-air premixed gas in the vicinity of a hot surface has been investigated. Especially multistep reaction model was compared with a single reaction model. It was found that the multistep model with 48 step elementary chemical reactions produced a phenomenologically reasonable trend in ignition delays. The ignition d(2lays increase as the mixture becomes either fuel-rich or fuel-lean with a minimum near the stoichiometric value. The minimum surface temperature has been deduced by extrapolating predicted ignition delays. It was in quite good agreement with the experimental data.

A Study on the Exhaust Gas Created by Staged Combustion and Gas Generator Cycle LRE by Using CEA (CEA를 이용한 다단연소사이클 및 가스발생기 사이클 LRE 배출가스 성분 분석)

  • Moon, In-Sang;Moon, Il-Yoon;Lee, Soo-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.863-866
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    • 2011
  • Recently environmental issue is more and more emphasized and 'Green Growth' became on of the key words of this Government. Based on this trend, the exhaust gases out of the gas generator cycle and the staged combustion cycle LRE whose propellants are kerosene and LOx were compared. For this purse, 8 tonf class of each cycle engine was designed and the amount and the components of the gases were investigated by using CEA. As expected, the staged combustion cycle engine generates less pollutants than the other cycle. In addition, the graphite that is generated by the gas generator can be reacted with the oxygen in the atmosphere creating additional pollutants.

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Operating Characteristics of 1 $Nm^3/h$ Scale Synthetic Natural Gas(SNG) Synthetic Systems (1 $Nm^3/h$ 규모 합성천연가스(SNG) 합성 시스템의 운전 특성)

  • Kim, Jin-Ho;Kang, Suk-Hwan;Ryu, Jae-Hong;Lee, Sun-Ki;Kim, Su-Hyun;Kim, Mun-Hyun;Lee, Do-Yeon;Yoo, Yong-Don;Byun, Chang-Dae;Lim, Hyo-Jun
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.491-497
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    • 2011
  • In this work, we proposed the three different reactor systems for evaluating of synthetic natural gas(SNG) processes using the synthesis gas consisting of CO and $H_2$ and reactor systems to be considered are series adiabatic reaction system, series adiabatic reaction system with the recirculation and cooling wall type reaction system. The maximum temperature of the first adiabatic reactor in series adiabatic reaction system raised to 800. From the these results, carbon dioxide in product gas as compared to other systems was increased more than that expected due to water gas shift reaction(WGSR) and the maximum $CH_4$ concentration in SNG was 90.1%. In series adiabatic reaction system with the recirculation as a way to decrease the temperature in catalyst bed, the maximum $CH_4$ concentration in SNG was 96.3%. In cooling wall type reaction system, the reaction heat is absorbed by boiling water in the shell and the reaction temperature is controlled by controlling the amount of flow rate and pressure of feed water. The maximum $CH_4$ concentration in SNG for cooling wall type reaction system was 97.9%. The main advantage of the cooling wall type reaction system over adiabatic systems is that potentially it can be achieve almost complete methanation in one reactor.

개량된 초임계수산화법에 의한 염소계유기물(PCB, 4-CDBz, PVC)의 완전분해반응

  • Lee, Sang-Hwan;Park, Gi-Cheol;Park, Yun-Yeol;Yang, Jong-Gyu;Kim, Jeong-Seong;Park, Bu-An
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.272-275
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    • 2005
  • 본 실험은 염소계유해유기화합물을 처리하는 목적으로 종래의 초임계수산화법의 결점을 완전히 해결하기 위해서 도달한 것이 질산나트륨을 산화제로서 사용하는 개량된 초임계수 산화법(다단계산화법)이다. 이와 같이 본 연구팀이 개발한 개량된산화법(다단계산화법)은 매우 간단하며 저렴한 염소계유기물 분해처리시스템을 구축하는 것이 가능하다.

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