• Title/Summary/Keyword: 다공핀

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Electrochemical Characterization of Porous Graphene Film for Supercapacitor Electrode (다공성 그래핀 필름의 슈퍼캐패시터 전극용 전기화학적 특성)

  • Choi, Bong Gill;Huh, Yun Suk;Hong, Won Hi
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.754-757
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    • 2012
  • In this report, we fabricate the porous graphene films through embossing process and vacuum filtration method and demonstrate their superior electrochemical properties as supercapacitor electrode materials. Insertion/removal of polystyrene nanoparticles between the graphene sheets allows to provide pore structures, leading to the effective prevention of restacking in graphene films. As-prepared porous graphene films have a large surface area, a bicontinuous porous structures, high electrical conductivity, and excellent mechanical integrity. The electrochemical properties of the porous graphene films as electrode materials of supercapacitor are investigated by using aqueous $H_2SO_4$ and ionic liquid solution under three-electrode system. The porous graphene films exhibit a high specific capacitance (284.5 F/g), which is two-fold higher than that of packing graphene films (138.9 F/g). In addition, the rate capability (98.7% retention) and long-term cycling stability (97.2%) for the porous graphene films are significantly enhanced, due to the facilitated ion mobility between the graphene layers.

Flow and Heat Transfer Characteristics of Aluminum Foam Porous Fins (발포알루미늄 다공핀의 열유동특성)

  • 김서영;백진욱;강병하
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.5
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    • pp.511-518
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    • 2000
  • The present experimental study investigates the impact of porous fins on the pressure drop and heat transfer characteristics in plate-fin heat exchangers. Systematic experiments have been carried out in a simplified model of a plate-porous fin heat exchanger at a controlled test environment. Comparison of performance between the porous fins and the conventional louvered fins has been made. The experimental results indicate that friction and heat transfer rate are significantly affected by permeability as well as porosity of the porous fin. The porous fins used in the present study show a similar air-side performance to the louvered fin. The correlations of friction and modified j-factor are also given for the design of the plate-porous fin heat exchanger.

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Improvement of Electrochemical Reduction Characteristics of Carbon Dioxide at Porous Copper Electrode using Graphene (그래핀을 이용한 다공성 구리 전극의 전기화학적 이산화탄소 환원 능력 향상)

  • Bang, Seung Wan;Rho, Hokyun;Bae, Hyojung;Kang, Sung-Ju;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.105-109
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    • 2018
  • We studied graphene synthesis to porous Cu to improve the characteristics of carbon dioxide reduction of cu. Cu powders were formed through Thermal Chemical Vapor Deposition(TCVD) to Porous Cu/Graphene structures synthesized with graphene. As a result of electrochemical experiments using a 0.1 M $KHCO_3$ electrolyte at an applied potential of -1.0 V to -1.4 V, the current density of Porous Cu/Graphene was 1.8 times higher than that of Porous Cu. As a result of evaluating the product, CO and $H_2$ were generated to Porous Cu electrode. On the other hand, the product of porous Cu/Graphene produced CO, $CH_4$ and $C_2H_4$. It is considered that the graphene causes longer carbon dioxide adsorption time, which means that the intermediates formed during the reaction remain on the electrode surface for a longer time. As a result, it can be concluded that the production reaction of the C2 compound could be continuously performed.

High-performance of Flexible Supercapacitor Cable Based on Microwave-activated 3D Porous Graphene/Carbon Thread (마이크로웨이브 활성화 3차원 다공성 그래핀/탄소실 기반의 고성능 플렉서블 슈퍼커패시터 케이블)

  • Park, Seung Hwa;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.23-28
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    • 2019
  • We report a supercapacitor cable, which consists of three-dimensional (3D) porous graphene coated onto the surface of carbon thread. The 3D porous framework of graphene was constructed by microwave-activated process using a graphene oxide-coated carbon thread. The use of microwave irradiation enabled to convert graphene oxide into reduced graphene oxide without any reducing agents and activate graphene sheets into exfoliated and porous graphene sheets. Combining two wire electrodes with a polymer gel electrolyte successfully completed supercapacitor device in a form of cable construction. The supercapacitor cables were highly flexible, and thus can be transformed into various shapes of devices and be integrated into textile items. A high area-capacitance of 38.1 mF/cm was obtained at a scan rate of 10 mV/s. This capacitance was retained 88% of its original value at 500 mV/s. The cycle life was also demonstrated by repeating a charge/discharge process during 10,000 cycles even under bent states, showing a high capacitance retention of 96.5%.

Synthesis of Three-Dimensional Graphene Using Porous Nickel Nanostructure (다공성 니켈 나노 구조체를 이용한 3차원 그래핀의 합성)

  • Song, Wooseok;Myung, Sung;Lee, Sun Sook;Lim, Jongsun;An, Ki-Seok
    • Composites Research
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    • v.29 no.4
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    • pp.151-155
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    • 2016
  • Graphene has been a valuable candidate for use as electrodes for supercapacitors. In order to improve the surface area of graphene, three-dimensional graphene was synthesized on porous Ni nanostructure using thermal chemical vapor deposition and microwave plasma chemical vapor deposition. The structural and chemical characterization of synthesized graphene was performed by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was confirmed that three-dimensional and high-crystalline multilayer graphene onto various substrates was synthesized successfully.

Controlled Release of Nifedipine from Osmotic Pellet Based on Porous Membrane (니페디핀을 포함한 삼투성펠렛의 제조와 다공성막을 통한 약물방출제어)

  • Youn, Ju-Yong;Ku, Jeong;Kim, Byung-Soo;Kim, Moon-Suk;Lee, Bong;Khang, Gil-Son;Lee, Hai-Bang
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.328-333
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    • 2008
  • The osmotic delivery systems are based on osmosis. The transverse diffusion of water through a porous membrane from a medium with a low osmotic pressure to a medium with a high osmotic pressure. Nifedipine tablet dosage forms of Procardia $XL^{(R)}$(Pfizer) and $Adalat^{(R)}$(Bayer) are commercialized systems of this type that push-pull osmotic tablet operates successfully in delivering water-insoluble drugs. We prepared osmotic pellet system by fluidized bed coating method, and model-drug used nifedipine. The osmotic pellet system was composed of the core material. the swelling and osmotic pressure layer, the drug coating layer, and the porous membrane. This work is performed to investigate the effect of different factors, such as composition and thickness of membrane. The osmotic pellet has been successfully prepared by fluidized bed coating technology. The drug release behavior depended on the increase of CA ratio and thickness in porous membrane. The morphology of the osmotic pellet before and after the dissolution test were observed by SEM. In conclusion, we found that the drug release of osmotic pellet depended on the composition and coating thickness of porous membrane.

Preparation of Porous Nano Template of Parabola Shape by Anodic Aluminum Oxide (알루미늄 양극산화에 의한 포물선 형태의 다공성 나노 템플릿 제조)

  • Kim, An-Na;Kim, Hyeon-Jong;Im, Ha-Na;Jeong, Ji-Hye;Sin, Chi-Ho;Park, Chun-Man;Yu, Bong-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.274-274
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    • 2015
  • 양극산화를 통해 생기는 다공성 알루미나 산화막의 기공은 전해질과 적절한 온도 등 제작 조건에서 자기 조립하여 고도로 정렬된 (Highly ordered) 나노기공을 가지는 AAO (AnodicAluminum Oxide)를 제조하는데 주로 쓰이고 있다. 본 연구에서는 다단계 산화방법으로 빛의 파장에 무관하게 빛의 반사를 매우 효과적으로 줄이는 포물선 형태의 Moth-eye 구조를 가지는 템플릿을 제조하였다. SEM 측정을 통해 구조체 다공성 알루미늄 산화막의 표면적 변화를 알 수 있었고, 일정한 크기와 모양의 pore가 규칙적으로 형성된 것을 확인하였다. 그리고 제조된 템플릿 내부에 고분자를 채워 포물선 형태의 나노핀을 갖는 필름을 제조할 수 있었다.

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Enhancement of Electrochemical and Mechanical Properties of 3D Graphene Nanostructures by Dopamine-coating (도파민 코팅을 이용한 3차원 그래핀 나노 구조체의 전기화학적/기계적 특성 향상 연구)

  • Lee, Guk Hwan;Luan, Van Hoang;Han, Jong Hun;Kang, Hyun Wook;Lee, Wonoh
    • Composites Research
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    • v.32 no.6
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    • pp.388-394
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    • 2019
  • Inherited the excellent electrical and mechanical properties based on the low dimensional structure of graphene, three-dimensional graphene nanostructures have gathered great attention as electrochemical energy storage electrodes owing to their high porosity and large specific surface area. Also, having the catecholamine structure, dopamine has been regarded as a multifunctional material to possess high affinity to various organic/inorganic materials and to modify a hydrophobic surface to a hydrophilic one. In this work, through coating dopamine on the three-dimensional graphene nanostructure, we tried to increase the specific capacitance by enhancing the wettability with electrolyte and to improve the mechanical compressive property by strengthening the nano-architecture. As a result, the dopamine-coated nanostructure exhibited significant improvement on the specific capacitance (51.5% increase) and compressive stress (59.6% increase).

Experiments on the Heat Transfer and Pressure Drop Characteristics of a Channel with Pin-Fin Array (핀-휜을 삽입한 채널의 열전달 및 압력강하 특성 실험)

  • 신지영;손영석;김상민;이대영
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.7
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    • pp.623-629
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    • 2004
  • Rapid development of electronic technology requires small size, high density packaging and high power of electronic devices, which result in more heat generation by the electronic system. Present cooling technology may not be adequate for the thermal management in the current state-of-the-art electronic equipment. Forced convective heat transfer in a channel filled with pin-fin array is studied experimentally in this paper as an alternative cool-ing scheme for a high heat-dissipating equipment. Various configurations of the pin-fin array are selected in order to find out the effect of spacing and diameter of the pin-fin on the heat transfer and pressure drop characteristics. In the low porosity region, interfacial heat transfer and pressure drop seem to show different trend compared to the conventional heat transfer process.

Analysis on the Cooling Characteristics of a Channel with Pin-Fin Structure (핀-휜 구조물을 이용한 채널의 냉각특성 해석)

  • 신지영;손영석;이대영
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.8
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    • pp.667-673
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    • 2003
  • Recent trends in the electronic equipment indicate that the power consumption and heat generation in a chip increase as the components are miniaturized and the computing speed becomes faster. Suitable heat dissipation is required to ensure the guaranteed performance and reliable operation of the electronic devices. The aim of the present study is to investigate the forced-convective thermal-hydraulic characteristics of a pin-fin heat exchanger as a candidate for cooling system of the electronic devices. The influence of the structure of the pin-fin assembly on heat transfer is investigated by porous medium model. The results are compared with the experimental data or correlations of several researchers for the heat transfer coefficients for the channel flow with pin-fin arrays. Finally, the effects of design parameters such as the pin-fin diameter and the spacing are examined.