• Journal of the Korean Ceramic Society
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• v.35 no.6
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• pp.575-582
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• 1998

Sutiability of Jungsan clay shale dolomite sludge Anyang feldspar and alumina as raw materials for light-weight porous ceramics was examined. In order to find optimum manufacturing conditions compositions heating temperatuers and heating times were varied and their effects on physical properties were measured and bloating mechanism was investigated. Jungsan clay seems suitable as raw material to make the light-weight constructional materials with 5wt% of ANyang feldspar and alumina added in calcined clay (800$^{\circ}C$) having bulk density of 0.45g/cm3 water absorption of 1.34% and compressive strength of 85kg/cm2 rapid-heated at 1200$^{\circ}C$ for 30min. It is suggested that bloating mechanism depends on the difference of tem-peratures between the inside and outside in specimen the remained gases in interstices can bloat by the li-quid phase of surface with high viscosity and gas pressure at elevated temperature.

• Journal of the Korean Ceramic Society
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• v.32 no.5
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• pp.608-616
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• 1995

Porous silicon (PS) was prepared under different anodization conditions and the photoluminescence (PL) was measrued. In addition PL of the naturally and thermally oxidized PS was measured. It was found that the PL peak was shifted to shorter wavelength as the anodization current density and the extent of the oxidation increased. The absence of correlation between the PL behavior and the surface hydrogen species (Si-H2, Si-H) implies that the mechanism of PL of PS is not likely related to the surface hydrogen species effect but to the quantum confinement effect.

• Journal of the Korean Ceramic Society
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• v.37 no.11
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• pp.1119-1125
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• 2000

용융 Si 침윤 방법에 의한 새로운 다공질 RBSC 제조공정이 개발되었으며, 용융 Si 침윤공정 방법으로 제조된 다공질 RBSC의 최대 3-점 파괴 강도는 18 MPa, 최대 기공율은 46% 범위이었다. 용융 Si 침윤방법으로 제조된 다공질 RBSC의 기계적 특성 및 기공율은 성형체내 SiC 입자 표면의 카본 source의 양 및 침윤시 사용된 Si의 양에 직접적으로 영향을 받는 것으로 나타났다. 침윤시 상대 Si 양은 40%를 사용하였으며, SiC 입자 표면에 graphite와 phenol resin을 함께 코팅한 성형체를 사용하여 제조된 다공질 RBSC에서 최대 파괴강도 값을 얻었다. 상대 Si의 양의 증가는 다공질 RBSC의 파괴강도를 감소시켰으며, SiC 입자 표면의 카본 source 코팅층은 graphite와 phenol resin을 같이 사용하였을 때 다공질 RBSC의 파괴강도는 증가되었으나, RBSC 내 기공율은 감소되었다.

• Journal of the Korean Ceramic Society
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• v.41 no.12 s.271
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• pp.939-945
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• 2004

Glasses of $SiO_2-B_{2}O_3-Al_{2}O_3-CaO-La_{2}O_3$ with various amounts of $La_{2}O_3$ were infiltrated into a porous alumina to make an alumina-glass composite. The infiltration characterization and bending strength of the composite were examined in terms of glass composition. $La_{2}O_3$ in the glass decreased the high temperature viscosity and this enhanced the wetting behaviour of this glass to alumina, and made glass infiltration easier. The infiltrated glass dissolved the alumina skeleton, and $Al_{2}O_3$ component in the glass melt reprecipitated on the alumina. The grain growth occurred to a specific crystal direction. The glass containing $20mole\%$ of $La_{2}O_3$ was crystallized after infiltration, and this enhanced the bending strength of the composite.

• Journal of the Korean Ceramic Society
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• v.41 no.8
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• pp.628-632
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• 2004

A porous hydroxyapatite has been prepared using natural coral which resembles human cancellous bone in microstructure. To obtain a biomaterial having a good biocompatibility, substitution of silicon into the hydroxyapatite framework has been attempted. Si substituted hydroxyapatite has been prepared by hydrothermal treatment and solvothermal treatment of the natural coral repeatedly. Si concentration and phase of the Si substituted hydroxyapatite derived from coral have been characterized using a XRD, ICP, and EDS etc. EDS investigation confirmed the presence of silicon in the framework of hydroxyapatite structure.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.2
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• pp.167-177
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• 2016

This work investigated the decomposition of aqueous anatoxin-a originated from cyanobacteria using an underwater dielectric barrier discharge plasma system based on a porous ceramic tube and an alternating current (AC) high voltage. Plasmatic gas generated inside the porous ceramic tube was uniformly dispersed in the form of numerous bubbles into the aqueous solution through the micro-pores of the ceramic tube, which allowed an effective contact between the plasmatic gas and the aqueous anatoxin-a solution. Effect of applied voltage, treatment time and the coexistence of nutrients such as $NO_3{^-}$, $H_2PO_4{^-}$ and glucose on the decomposition of anatoxin-a was examined. Chemical analyses of the plasma-treated anatoxin-a solution using liquid chromatography-mass spectrometry (LC-MS) and ion chromatography (IC) were performed to elucidate the mineralization mechanisms. Increasing the voltage improved the anatoxin-a decomposition efficiency due to the increased discharge power, but the energy required to remove a given amount of anatoxin-a was similar, regardless of the voltage. At an applied voltage of 17.2 kV (oxygen flow rate: $1.0L\;min^{-1}$), anatoxin-a at an initial concentration of $1mg\;L^{-1}$ (volume: 0.5 L) was successfully treated within 3 min. The chemical analyses using LC-MS and IC suggested that the intermediates with molecular weights of 123~161 produced by the attack of plasma-induced reactive species on anatoxin-a molecule were further oxidized to stable compounds such as acetic acid, formic acid and oxalic acid.

• Journal of Energy Engineering
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• v.21 no.4
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• pp.385-392
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• 2012

The purpose of this study is investigated on the combustion and the thermal characteristics of porous media burners which are many using for a condensing boiler recently. In addition, results of this study will be used the fundamental information to decide the burner type which will be applied to the future development of EGR(Exhaust gas recirculation) condensing boiler. Two flat type of burners made of a the metal fiber(MF) and the ceramic(CM) were selected and examined, experimentally. As experimental results, the emitted CO concentration of CM was higher than that of MF. However, the NO concentration of MF was higher than that of CM. The efficiencies of both burners were increased as increasing the burner capacity. While the efficiency of MF was higher than that of CM, regardless of the burner capacity. In the experimental range, MF is appropriated for the burner material and 0.8 of equivalence ratio is an optimal operation condition, regarding of the proportional control, the thermal efficiency and emitted NO and CO concentration based on the regulations of KS B standard and EN 677 standard.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.535-542
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• 1993

It was investigated in this study that a preparation method, activation energy, surface area, pore volume, pore size distribution and DTA analysis of the dry gel in process of producing monolithic porous gel in Li2O-Al2O3-TiO2-SiO2 system by the sol-gel technique using metal alkoxides. Activation energy for gellation according to the variation of water concentration and the kind of catalysts ranged from 10 to 20kcal/mole. Monolithic dry gels were prepared after drying at 9$0^{\circ}C$ when the amount of water for gellation was 4~8 times more than the stoichiometric amount, that was necessary for the full hydrolysis of the mixed metal alkoxide. The specific surface area, the pore volume, the average pore radius of the dried gel at 18$0^{\circ}C$ according to the various kinds of catalyst were about 348~734$m^2$/g, 0.35~0.70ml/g and 10~35$\AA$, respectively. It showed that the dry gels were porous body. As a result ofthe analysis of DTA, it was confirmed that the exothermaic peaks at 715$^{\circ}C$ and 77$0^{\circ}C$ was clue to the crystallization of dried gel.

• Journal of the Earthquake Engineering Society of Korea
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• v.7 no.3
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• pp.17-22
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• 2003

This paper presents an experimental investigation of a reversible colloidal seismic damper, which is statically loaded, The porous matrix is composed from silica gel (labyrinth or central-cavity architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis are described. Influence of the pare and particle diameters, particle architecture and length of the grafted molecule upon the reversible colloidal damper hysteresis is investigated, for distinctive types and mixtures of porous matrices, Variation of the reversible colloidal damper dissipated energy and efficiency with temperature, pressure, is illustrated.

• Journal of the Korean Ceramic Society
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• v.40 no.12
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• pp.1177-1182
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• 2003

The porous sensing materials for BaTiO$_3$ gas sensors were fabricated by adding the graphite powders. The crystalline structure and microstructure of the porous BaTiO$_3$-based ceramics were studied. All the sintered bodies showed a tetragonal perovskite structure. The porosity increased with increasing graphite contents. This is mainly due to an enhanced evolution of CO and $CO_2$ gases resulting from the exothermic reactions of graphite and oxygen during the sintering. It was found that the discrepancy in the resistivities measured in air and CO atmospheres at high temperatures (>∼20$0^{\circ}C$) became remarkable with increasing temperature. The sensitivity of CO gas increased with porosity, since the reactions between CO gas and $O_2$$^{[-10]}$ and between CO gas and $O^{[-10]}$ are active due to the formation of many reaction sites. The porous BaTiO$_3$-based ceramics could be promising as a sensing material for CO gas sensors.