• Proceedings of the Computational Structural Engineering Institute Conference
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• 2011.04a
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• pp.685-688
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• 2011

본 논문에서는 다양한 음향 가진에 따른 음향 응답을 유한 요소법을 통하여 효과적으로 계산하기 위한 새로운 모델 축소법을 제안한다. 일반적인 유한 요소법을 통한 기계구조물의 응답을 구하기 위해서는 음향 방정식의 강성 및 행렬을 구한 뒤 이들의 조합을 통한 동적 강성행렬을 구한 뒤 역행렬을 구하여 다양한 주파수 응답을 구하게 된다. 현재 컴퓨터 하드웨어의 발전과 소프트 웨어의 발전에 의하여 더 많은 유한 요소를 사용할 수 있게 되었고 이로 인하여 더욱 정확하고 넓은 대역의 음향 응답을 구할 수 있게 되었다. 그러나, 아직까지도 아주 복잡한 구조물의 음향 응답을 구하기 위하여 유한 요소를 무한정으로 증가할 수 없는 경우가 많다. 이를 해결하기 위하여 일반적으로 모델 축소법(Model order reduction) 기법을 사용한다. 이 모델 축소법은 기본적으로 전체 행렬을 아주 작지만 효율적인 작은 행렬로 바꾸어 응답을 예측하는 기법으로 mode superposition method, ritz vector method, quasi-static ritz vector method등이 있다. 기존의 모델 축소법은 기본적으로 질량 및 강성행렬이 가진 주파수에 영향을 받지 않는 행렬이라 가정한다. 그렇기 때문에 경계조건이나 다공성 재료를 모델링할 경우 가진 주파수에 영향을 받는 강성행렬과 질량행렬이 만들어지게 되어 기존의 모델 축소법은 효과적이지 못하게 된다. 이런 문제점을 해결하기 위하여 이 논문에서는 Quasi-static ritz vector method의 기본적인 개념을 확장하여 여러 개의 중심 주파수(Center frequency)에서 기저를 계산하고 이를 동시에 이용하는 Multi-frequency quasi-static ritz vector method를 제안한다.

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.539-544
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• 2020

A three-dimensional (3D) porous polyaniline (PANI) film was fabricated by a combined photo-and soft-lithography technique based on a large-area nanopillar array, followed by a controlled chemical dilute polymerization. The as-obtained 3D PANI film consisted of hierarchically interconnected PANI nanofibers, resulting in a 3D hierarchical nanoweb film with a large surface and open porous structure. Using electrochemical measurements, the resulting 3D PANI film was demonstrated as a flexible pH sensor electrode, exhibiting a high sensitivity of 60.3 mV/pH, which is close to the ideal Nernstian behavior. In addition, the 3D PANI electrode showed a fast response time of 10 s, good repeatability, and good selectivity. When the 3D PANI electrode was measured under a mechanically bent state, the electrode exhibited a high sensitivity of 60.4 mV/pH, demonstrating flexible pH sensor performance.

• Membrane Journal
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• v.24 no.4
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• pp.317-324
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• 2014

It is very well known that the conventional polyamide (PA) thin film composite (TFC) reverse osmosis (RO) membranes have excellent permselective properties, but their chlorine tolerance is not good enough. In this study, to improve such chlorine tolerance, microporous membranes containing hydrophilic functional groups such as -COOH were used as a support to prepare PA TFC RO membranes, employing the conventional interfacial polymerization method. Meta-phenylene diamine (MPD) and 2,6-diamine toluene (2,6-DAT) were used as diamine monomers and tri-mesoyl chloride (TMC) as an acid monomer. The membranes prepared were characterized using various instrumental analytical methods and permeation test set-up. The flux obtained from the membranes prepared so was more than $1.0m^3/m^2day$ at 800 psi of operating pressure, while the salt rejection was over 99.0%. The chlorine tolerance of them was also found to be better than that of the membrane prepared by using conventional polysulfone support without hydrophilic functional groups.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.984-990
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• 2017

Mesh screen modeling and liquid propellant discharge simulation of surface tension tank were performed using commercial CFD software Flow-3d. $350{\times}2600$, $400{\times}3000$ and $510{\times}3600$ DTW mesh screen were modeled using macroscopic porous media model. Porosity, capillary pressure, and drag coefficient were assigned for each mesh screen model, and bubble point simulations were performed. The mesh screen model was validated with the experimental data. Based on the screen modeling, liquid propellant discharge simulation from PMD tank was performed. NTO was assigned as the liquid propellant, and void was set to flow into the tank inlet to achieve an initial volume flow rate of liquid propellant in $3{\times}10^{-3}g$ acceleration condition. The intial flow pressure drop through the mesh screen was approximately 270 Pa, and the pressure drop increased with time. Liquid propellant discharge was sustained until the flow pressure drop reached approximately 630 Pa, which was near the estimated bubble point value of the screen model.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.442-448
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• 2021

Flow field is an important parameter for polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on the reactant supply, heat and water diffusion, and contact resistance. In this study, PEMFC performance was investigated using Cu foam flow field at the cathode of 25 cm² unit cell. Polarization curve and electrochemical impedance spectroscopy were performed at different pressure and relative humidity conditions. The Cu foam showed lower cell performance than that of serpentine type due to its high ohmic resistance, but lower activation and concentration loss due to the even reactant distribution of porous structure. Cu foam has the advantage of effective water transport because of its hydrophobicity. However, it showed low membrane hydration at low humidity condition. The metal foam flow field could improve fuel cell performance with a uniform pressure distribution and effective water management, so future research on the properties of metal foam should be conducted to reduce electrical resistance of bipolar plate.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.11
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• pp.905-911
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• 2015

In this study, to examine the effect of a hole size change(smaller hole diameter) in the outer region of the lower-support-structure-bottom plate(LSSBP) on the reactor core-inlet flow-distribution, simulations were conducted with the commercial CFD software, ANSYS CFX R.15. The predicted results were compared with those of the original LSSBP. Through these comparisons, it was concluded that a more uniform distribution of the mass flow rate at the core-inlet plane could be obtained by reducing the hole size in the outer region of the LSSBP. Therefore, from the nuclear regulatory perspective, design change of the hole pattern in the outer region of the LSSBP may be desirable in terms of improving both the mechanical integrity of the fuel assembly and the core thermal margin.

• Membrane Journal
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• v.24 no.2
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• pp.113-122
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• 2014

Porous poly(L-lactic acid)(PLLA) scaffold membranes were prepared via. phase separation process. Chloroform, dichloromethane and 1,4-dioxane were used as solvent and, ethyl alcohol was used as non-solvent. Morphologies, mechanical properties and mass transfer characteristics of the scaffold membranes were investigated through SEM, stress-strain test and glucose diffusion test. The scaffold membranes obtained from the casting solutions with chloroform and with dichloromethane showed similar morphologies. They showed sponge-like porous structure with the pore size in the range of $3-10{\mu}m$ and, their porosities were in 50-80% range. Using 1,4-dioxane as solvent, nano-fibrous scaffold membranes with porosities over 80% were fabricated. When the polymer content in the solution with 1,4-dioxane was lowered to 4%, highly porous, macroporous and nano-fibrous scaffold membranes were obtained. The size of the macropore was tens of the microns and the porosity was around 90%. These results indicate that the solvent has significant effect on the scaffold membrane structure and, that scaffold membranes with various structures can be fabricated through phase separation method by choosing solvent and by controlling polymer concentration in the casting solution.

• Journal of the Korean Vacuum Society
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• v.3 no.2
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• pp.220-226
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• 1994

본 연구에서는 폴리에스터(PET) 필름 위에 아연을 연속적으로 진공증착하는 실험을 수행한 후 얻어진 박막의 조직 및 조성을 SEM 및 AES로 조사하였다. 박막의 X-선 회절부석 결과, 2$ heta$=36。에서 아연의(0002)면이 주피크로 나타났으며 투과전자 현미경 관찰 결가 hcprn조로 증착시 basal plane인 (0001)면에 평행한 방향으로 우선 성장한다. 대기중 노출시 증착필름은 수분 및 산소와 반응하여 매우 다공성이며 부착성이불량한 산화피막을 형성하기 때문에 1차피막형성 후에도 산화가 지속적으로 진행되 었다. 박막내 존재하는 산소의 농도는 내부로 갈수록 지수함수적으로 감소하다가 증착금속과 기판간의 계면에서 다시 증가하는 경향을 보인다. 박막의 부식 특성을 조사현 결과 균일한 산화막 형성과 더불어 수분 존재하에 아연충에 미세한 pin hole 이 공극 부분부터 형성되어 개수가 증가하며 주위로 확장되는 형태를 나타내고 있다.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.367-368
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• 2009

High-rise building in modern society is becoming increasingly necessary to reduce the weight of the building. Accordingly, increased use of lightweight bubble concrete is a trend Porous ceramics (ALC) is the most common, lightweight bubble concrete. And it is by lightweight blocks the same used as building materials. This research is related to the physical characteristics of ALC controlled by particle size and contents of raw materials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.164-164
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• 2008

금속배선공정에서 높은 전도율과 재료의 값이 싸다는 이유로 최근 Cu를 사용하였으나, 디바이스의 구조적 특성을 유지하기 위해 높은 압력으로 인한 새로운 다공성 막(low-k)의 파괴와, 디싱과 에로젼 현상으로 인한 문제점이 발생하게 되었다. 이러한 문제점을 해결하고자, 본 논문에서는 Cu 표면에 Passivation layer를 형성 및 제거하는 개념으로 공정시 연마제를 사용하지 않으며, 낮은 압력조건에서 공정을 수행하기 위해, 전해질의 농도 변화에 따른 Liner sweep voltammetry 법을 사용하여 전압활성화에 의한 전기화학적 반응이 Cu전극에 어떤 영향을 미치는지 연구하였으며, 표면 조성을 알아보기 위하여 Energy Dispersive Spectroscopy (EDS) 분석을 하였고, Cu disk의 결정성과 배향성 관찰을 위해 X-Ray diffraction (XRD)로 금속 표면을 비교하여 실험 결과로 얻어진 데이터를 통하여 ECMP 공정에 적합한 전해액 선정과 농도를 선택하였다.