• Title/Summary/Keyword: 다공성 구조

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Characterization of Elastic Modulus of Kelvin Foam Using Elastic Structural Model and Ultrasound (초음파와 탄성 구조 모델을 이용한 캘빈 폼 재료의 탄성계수 평가)

  • Kim, Woochan Ethan;Kim, Nohyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.6
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    • pp.474-482
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    • 2016
  • A Kelvin foam plate - widely used in the energy and transport industries as a lightweight structural material - was examined to estimate its Young's modulus using ultrasound. An isotropic tetrakaidecahedron foam structure was designed in SolidWorks and printed using 3D printer with an ABS plastic material. The 3D printed foam structure was used to build a foam plate with a 14 mm thickness ($50mm{\times}100mm$ in size) for the ultrasonic test. The Kelvin foam plate, a significantly porous medium, was completely filled with paraffin wax to enable the ultrasound to penetrate through the porous medium. The acoustic wave velocity of the wax-filled Kelvin foam was measured using the time of flight (TOF) method. Furthermore, the elastic modulus of the Kelvin foam was estimated based on an elastic structural model developed in this study. The Young's modulus of the produced Kelvin foam was observed to be approximately 3.4% of the bulk value of the constituent material (ABS plastic). This finding is consistent with experimental and theoretical results reported by previous studies.

Long-Termed Behavior and Durability of Foam-Mixed Concrete Containing Porous Aggregates (다공성 골재를 함유한 기포혼합콘크리트의 장기거동 및 내구특성)

  • Kim, Sang Chel;Yi, Seong Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.113-123
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    • 2012
  • The technology developed for the decrease of applying loads and self-weight of a structure is to improve conventional Foam Cement Banking Method (FCB) by applying mixed slurry of bottom ash, cement and foams. Since the foam-mixed concrete, which is a major material of the Bottom ash-mixed Light weight concrete Banking method (BLB) developed, contains mineral admixture such as cement, the behavior shows time-dependent deformation and deterioration of durability due to environmental exposure. Thus, this study is subject to figure out the characteristics of long-termed behavior and durability of the developed method by carrying out experiments for schemed parameters, which are considered to be factors affecting mainly on concrete's characteristics from mechanical analysis. As results of tests, it was found that the developed concrete offers higher resistance than conventional foamed concrete in terms of long-termed behaviors associated with drying shrinkage and creep, and durability problems of freeze-thaw and carbonation processes, especially with addition of bottom ash.

Synthesis of Three-Dimensional Graphene Using Porous Nickel Nanostructure (다공성 니켈 나노 구조체를 이용한 3차원 그래핀의 합성)

  • Song, Wooseok;Myung, Sung;Lee, Sun Sook;Lim, Jongsun;An, Ki-Seok
    • Composites Research
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    • v.29 no.4
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    • pp.151-155
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    • 2016
  • Graphene has been a valuable candidate for use as electrodes for supercapacitors. In order to improve the surface area of graphene, three-dimensional graphene was synthesized on porous Ni nanostructure using thermal chemical vapor deposition and microwave plasma chemical vapor deposition. The structural and chemical characterization of synthesized graphene was performed by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was confirmed that three-dimensional and high-crystalline multilayer graphene onto various substrates was synthesized successfully.

Effect of the Formation of an Initial Oxide Layer on the Fabrication of the Porous Aluminium Oxide (초기 산화 피막의 형성이 다공성 알루미나 막 제작에 미치는 영향)

  • Park, Young-Ok;Kim, Chul-Sung;Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.79-83
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    • 2008
  • We have investigated the effect of the formation of an initial oxide layer on the fabrication of the porous aluminium oxide. The porous aluminium oxide was fabricated by two-step anodization process with a electropolished aluminium foil. Before the first anodization step, the initial oxide layer with thickness of 10 nm was formed under the applied voltage of 1 V and later the anodization was continued under 40 V using oxalic acid solution. With the formation of the initial oxide layer, the anodization process was stable and the anodization current was constant throughout the process. In case of the absence of the initial oxide layer, the anodization was very unstable and the continuous increase in the anodization current was observed. This indicates the formation of the initial oxide layer on the aluminium surface prevents the burning of the surface due to the nonuniform distribution of the applied electric field, and allows the stable anodization process required for the porous aluminium oxide.

Discovery of Porous Materials for H2/CO2 Gas Separation and High-Throughput Computational Screening (수소/이산화탄소 가스분리용 다공성 물질 탐색 및 고속전산스크리닝 연구동향)

  • Byung Chul Yeo
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.1-7
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    • 2023
  • Gas separation technology becomes more useful because key gases such as H2 and CO2 regarding renewable energy resources and environmental pollutant can be effectively extracted in mixed gases. For reducing energy consumption on gas separation, membrane and adsorption processes are widely used. In both processes, porous materials are needed as membrane and adsorbent. In particular, metal-organic frameworks (MOFs), one class of the porous materials, have been developed for the purpose of gas adsorption and separation. While the number of the MOF structures is increasing due to chemical and structural tunability, good MOF membranes and adsorbents have been rarely reported by trial-and-error experiments. To accelerate the discovery of high-performing porous materials that can separate H2 and CO2, a high-throughput computational screening technique was used as efficient skill. This review introduces crucial studies of porous materials and the high-throughput computational screening works focusing on gas separation of H2 and CO2.

Development of Porous Media for Sewage Treatment by Pyrolysis Process of Food Wastes with Loess (음식물 쓰레기 및 황토 혼합물의 열분해를 통한 수질정화용 다공성 담체 개발)

  • Kim, Sang-Bum;Lee, Myong-Hwa;Kim, Yong-Jin;Park, Chul-Hwan;Lee, Jong-Rae;Kim, Gyung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.289-296
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    • 2007
  • Porous media for sewage treatment were developed through a pyrolysis process of food wastes with loess in the study. This work was carried out in two consecutive stages; in the first stage, new porous media were prepared through a high temperature pyrolysis process, and then the resultant media were applied to a simple lab-scale sewage treatment process in the second stage. To determine the optimum operating conditions of pyrolysis and mixing ratio of materials, physical properties such as specific surface area, porosity and compressive strength of final products were analyzed. The removal efficiencies of TOC and COD were measured to evaluate the effectiveness of resultant porous media. As a result of the experiment, we found that the best mixing ratio of food wastes to loess was 1 : 1 at $1,100^{\circ}C$. Average porosity of the developed media was 37.0%, in which pore size ranged from 1 to $20{\mu}m$, showing quite vigorous microbial activation. After immersing the media into a reactor for sewage treatment for eight days, removal efficiencies of TOC and COD were 87.3% and 85.0%, respectively.

Numerical Analysis of Internal Flow Distribution in Scale-Down APR+ (축소 APR+ 원자로 모형에서의 내부유동분포 수치해석)

  • Lee, Gong Hee;Bang, Young Seok;Woo, Sweng Woong;Kim, Do Hyeong;Kang, Min Gu
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.9
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    • pp.855-862
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    • 2013
  • A series of 1/5 scale-down reactor flow distribution tests had been conducted to determine the hydraulic characteristics of an APR+ (Advanced Power Reactor Plus), which were used as the input data for an open core thermal margin analysis code. In this study, to examine the applicability of computational fluid dynamics with the porous model to the analysis of APR+ internal flow, simulations were conducted using the commercial multi-purpose computational fluid dynamics software ANSYS CFX V.14. It was concluded that the porous domain approach for some reactor internal structures could adequately predict the flow characteristics inside a reactor in a qualitative manner. If sufficient computational resources are available, the predicted core inlet flow distribution is expected to be more accurate by considering the real geometry of the internal structures, especially upstream of the core inlet.

Structuyal and physical properties of thin copper films deposited on porous silicon (다공성 실리콘위에 증착된 Cu 박막의 구조적 물리적 특성)

  • 홍광표;권덕렬;박현아;이종무
    • Journal of the Korean Vacuum Society
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    • v.12 no.2
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    • pp.123-129
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    • 2003
  • Thin transparent Cu films in the thickness range of 10 ~ 40 nm are deposited by rf-magnetron sputtering on porous silicon (PS) anodized on p-type silicon in dark. Microstructural features of the Cu films are investigated using SEM, AFM and XRD techniques. The RMS roughness of the Cu films is found to be around 1.47 nm and the grain growth is columnar with a (111) preferred orientation and follows the Volmer-Weber mode. The photoluminescence studies showed that a broad luminiscence peak of PS near the blue-green region gets blue shifted (~0.05 eV) with a small reduction in intensity and therefore, Cu-related PL quenching is absent. The FTIR absorption spectra on the PS/Cu structure revealed no major change of the native PS peaks but only a reduction in the relative intensity. The I-V characteristic curves further establish the Schottky nature of the diode with an ideality factor of 2.77 and a barrier height of 0.678 eV. An electroluminiscence (EL) signal of small intensity could be detected for the above diode.

Fabrification of Segmented Flat-Tubular SOFC cell (Segmented 평관형 SOFC 셀 제조)

  • Park, Sung-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Choi, Heon-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.137.1-137.1
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    • 2010
  • SOFC cell 하나의 전위차는 약1.1V이기 때문에 발전용으로 사용하기 위해서는 수많은 단전지를 직렬로 연결하는 구조가 필요하다. 이러한 stack의 디자인에서 발생하는 문제를 획기적으로 개선한 형태가 하나의 지지체에 셀을 직렬로 연결함으로 전극의 선폭 및 단위 셀 간의 간격이 기존 평판형, 원통형에 비해 대폭 축소되어 전극 및 연결재의 저항손실을 최소화할 수 있는 Segmented형 SOFC이다. Segmented SOFC에 적용하기 위한 세라믹 다공성 지지체는 연료와 공기에서의 화학적 안정성, 셀의 구성소재와 반응이 없으며 열팽창계수가 유사해야하는 특성을 가져야하는데 그 중에서도 지지체로써 적절한 기계적 강도와 높은 가스투과도가 요구되어진다. 본 연구에서는 고온에서 안정한 Spinel의 MgAl2O4를 주성분으로 하는 다공성 지지체를 압출 성형하여 평관형으로 제조하였으며 활성탄을 기공형성제로 사용하여 연료의 공급이 원활하도록 약 30%의 기공율을 가지는 다공성 세라믹 지지체를 제조하였다. 제조된 세라믹 지지체에 연료극(NiO/YSZ), 전해질(TZ8Y), 공기극(LSM)을 코팅하여 실제 SOFC에 적용이 가능함을 확인하였다.

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Synthesis and application of Polyurethane for Microporous Membrane (미세다공 멤브레인용 폴리우레탄 수지의 합성 및 응용에 관한 연구)

  • Jeon, Jae-Woo;Yang, Jeong-Han;Kim, Duck-Han;Oh, Kyung-Seok;Han, Young-Chul
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.105-105
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    • 2012
  • 기능성 아웃도어 제품을 제조하기 위해서 사용되어지는 멤브레인은 크게 미세다공형과 친수무공형으로 구분할 수 있다. 최근에는 소비자들이 기능성 아웃도어에 쾌적성을 요구하고 있으며, 그 측면에서 본다면 미세다공형 멤브레인이 친수무공형보다 유리하다. 기존의 미세다공형 멤브레인은 고가이며, casting이 불가능한 단점을 가지고 있다. 본 연구에서는 분자구조 및 유화제 첨가에 따른 casting이 가능한 미세다공형 폴리우레탄 멤브레인의 특성에 대하여 연구하였다. Casting용 미세다공형 폴리우레탄은 soft segment와 hard segment의 비가 1/2일 때, 그리고 사용되는 용제가 MEK 단독일 때 안정적인 반응성과 이상적인 필름의 물성을 보이는 것을 확인 하였으며, 수지에 첨가되는 분산유화제의 양이 10%이상일 때 상분리 현상이 발생하지 않음을 확인 할 수 있었다. 개발된 수지의 적용성을 평가한 결과, J-knife를 이용하여 knife over roll 방식으로 25~35$g/m^2$ (dry add on)를 도포하여 $80/120/140^{\circ}C{\times}10m/min$의 다단건조 공정으로 진행했을 때 최적의 물성을 얻을 수 있었다.

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