• Title/Summary/Keyword: 다공성입자

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생체친화성 다공성 유기입자의 개발 동향

  • 배은희;이동신
    • Polymer Science and Technology
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    • v.15 no.4
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    • pp.430-437
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    • 2004
  • 인간 게놈 프로젝트 완성 및 간세포 (Stem cell) 발견으로 미래에는 현재 의학적 치료의 한계를 극복하는 의학적 혁명이 예상되고 있다. 간세포를 이용한 치료기술 개발을 위하여서는 균일한 간세포의 대량배양, 원하는 세포로의 균일한 분화, 면역학적 안전성 등이 매우 중요한 이슈가 되고 있으며 이의 해결을 위하여서는 생체적합성이 우수한 지지체의 개발이 기본이 되고 있다. (중략)

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Synthesis of porous $TiO_2$ using organic-templating and application for dye-sensitized solar cells (유기물 템플레이트를 이용한 다공성 티타늄 산화물의 합성 및 염료감응 태양전지로의 적용)

  • Lee, Jin-Kyu;Oh, Jae-Kyung;Kim, Hyun-Su;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.147-149
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    • 2009
  • 가수분해 및 응축반응을 사용하여 다공성의 TiO2입자를 합성하였다. 다공성 구조의 열적 영향을 살펴보기위해 annealing 시간을 조절하였고 태양전지에 적용하기 위해 paste로 만들었다. 그 구조적 특성을TEM(Transmission electron microscopy)과 XRD(X-ray diffraction) 통하여 분석하였고 광 전기화학적 활성을 측정해 보았다. 결과적으로 3시간 열처리한 시료의 효율이 최적화된 조건이였음을 확인하였다.

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Multi-scale simulation of drying process fey porous materials using molecular dynamics (part 3: multi-scale simulation) (분자동역학을 이용한 다공성 물질 건조공정 멀티스케일 시뮬레이션(3부: 멀티스케일 시뮬레이션))

  • Baik S.M.;Keum Y.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.168-174
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    • 2005
  • In this study, the numerical simulation of drying processes for porous materials is performed by employing the hierarchical multi-scale modeling and the nano-scale material properties obtained from the molecular dynamics simulation. The multi-scale simulation system is set up using pre- and post-processors and the drying process of electric porous ceramic insulator is simulated. The temperature, moisture, residual stress, and displacement distributions are compared with those based on homogenized properties.

Preparation of $SiO_2-TiO_2$ Porous Composite Pigments Using a Pickering Emulsion Method as Template (피커링 에멀젼을 형판으로 하는 $SiO_2-TiO_2$ 다공성 분체의 제조)

  • Lee, Sang-Gil;Kim, Young-Ho;Hong, Jun-Ki;Pyo, Hyeong-Bae;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.377-392
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    • 2012
  • It has been known that small solid particles act as a stabilizer in pickering emulsion system. In this study, we successfully prepared stable pickering emulsion in n-hexylalcohol and water system with $TiO_2$ whose surface was treated by alkylsilane. The optimum condition to prepare pickering emulsion stabilized by $TiO_2$ particles was determined by amount of $TiO_2$ particles and ratio of water and oil phase. The type of pickering emulsion was dependent on wettability of particles for water and n-hexylalcohol. When the amount of $TiO_2$ particles increased up to 5.00 wt%, the stability of pickering emulsion was showed to be improved. The most stable pickering emulsion was prepared in the case of W/O type which has the ratio of oil and water phase (3 : 7). We tried to prepare porous $SiO_2-TiO_2$ composite pigments using a pickering emulsion as template at the optimal condition. Porous pigments were synthesized with Ludox HS-30 as an inorganic material by sol-gel process. The characteristics and shape of porous pigments were measured by optical microscope, SEM, BET, XRD and EDS.

Electrochemical Characterization of Porous Graphene Film for Supercapacitor Electrode (다공성 그래핀 필름의 슈퍼캐패시터 전극용 전기화학적 특성)

  • Choi, Bong Gill;Huh, Yun Suk;Hong, Won Hi
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.754-757
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    • 2012
  • In this report, we fabricate the porous graphene films through embossing process and vacuum filtration method and demonstrate their superior electrochemical properties as supercapacitor electrode materials. Insertion/removal of polystyrene nanoparticles between the graphene sheets allows to provide pore structures, leading to the effective prevention of restacking in graphene films. As-prepared porous graphene films have a large surface area, a bicontinuous porous structures, high electrical conductivity, and excellent mechanical integrity. The electrochemical properties of the porous graphene films as electrode materials of supercapacitor are investigated by using aqueous $H_2SO_4$ and ionic liquid solution under three-electrode system. The porous graphene films exhibit a high specific capacitance (284.5 F/g), which is two-fold higher than that of packing graphene films (138.9 F/g). In addition, the rate capability (98.7% retention) and long-term cycling stability (97.2%) for the porous graphene films are significantly enhanced, due to the facilitated ion mobility between the graphene layers.

Study on CMPO (Carbamoylphosphate) derivative functionalized ordered mesoporous silicates for selective removal of lanthanide (희토류 원소의 분리를 위한 표면 개질 된 메조 다공성 실리케이트의 개발에 관한 연구)

  • Kwon, Bob Jin;Jung, Hyun;Kim, Jong Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.6
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    • pp.291-298
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    • 2012
  • Carbamoylphosphate (CMPO) [CMPO analogue; 2-(diphenylphosphoryl)-N-(3-(triethoxysilyl)propyl)acetamide]silane, as a functional self-assembled molecules, grafted mesoporous silicates were prepared by simple hydrolysis and condensation reaction. Pore sized tailored mesoporous silicates such as MCM-41, SBA-15, or amorphous silica nanoparticles were adopted as host materials. The surface area of ordered mesoporous silicates was ranged from 680 $m^2/g$ to 1310 $m^2/g$ with different pore diameters that estimated to be ca. 2.3~9.1 nm by BJH method. Among the OMMs host materials, SBA-15(II) has higher loading ratio (~35 wt%) of CMPO derivative than other OMMs. Accessibility to CMPO silane functional groups in the surface of mesoporous silicas was studied by lanthanide ions sorption experiments. All of the CMPO modified OMMs favors the smaller Eu(III) and Nd(III) cations than La(III) for relative larger ionic radius.

Calcination Condition of CsPbBr3-SiO2 Composite Nanoparticles (CsPbBr3-SiO2 복합 나노입자의 소결 조건 연구)

  • Jeon, Min-Gi;Kabir, Rezaul MD;Kirakosyan, Artavazd;Choi, Jihoon
    • Composites Research
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    • v.35 no.4
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    • pp.298-302
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    • 2022
  • Owing to the superior optoelectronic properties, halide perovskites have emerged as next-generation materials for display application. In this study, we reported a novel route for CsPbBr3 calcination into porous SiO2 nanoparticles to overcome the stability issues of halide perovskite via a spatial confinement of crystal growth within SiO2 pores. The resulting CsPbBr3-SiO2 nanoparticles exhibited the photoluminescence (PL) emission peak at 515 nm under optimal calcination condition. In several polar solvents, PL properties of CsPbBr3-SiO2 nanoparticles was maintained owing to the enclosed pores during calcination process, suggesting their promising application for display color conversion film.

Characteristics of Energy Dissipation in Nano Shock Suspension System Using Silica Gel (세라믹 분말을 이용한 나노 충격 완화 장치의 에너지 소산 효율 특성에 대한 연구)

  • 문병영;정성원
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.3
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    • pp.17-22
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    • 2003
  • This paper presents an experimental investigation of a reversible colloidal seismic damper, which is statically loaded, The porous matrix is composed from silica gel (labyrinth or central-cavity architecture), coated by organo-silicones substances, in order to achieve a hydrophobic surface. Water is considered as associated lyophobic liquid. Reversible colloidal damper static test rig and the measuring technique of the static hysteresis are described. Influence of the pare and particle diameters, particle architecture and length of the grafted molecule upon the reversible colloidal damper hysteresis is investigated, for distinctive types and mixtures of porous matrices, Variation of the reversible colloidal damper dissipated energy and efficiency with temperature, pressure, is illustrated.

A Particle Tracking Method for the Lagrangian-Eulerian Finite Element Method in 3-D Subsurface System (3차원 지표하 시스템에서 Lagrangian-Eulerian 유한요소법에 대한 입자추적 알고리즘)

  • Lee, Jae-Young;Kang, Mee-A
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.205-215
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    • 2009
  • The conventional numerical models to analyze flow in subsurface porous media under the transient state usually generate numerical oscillation and unstability due to local flux domain for critical cases such as infiltration into initially dry soil during rainfall period. In this case, it is required refined mesh and small time step, but it decrease efficiency of computation. In this study, numerical unstability in discontinuity domain is removed by applying particle tracking algorithm to simulate unsteady subsurface flow with inflow boundary condition. Finally the hybrid LE FEM improving numerical stability is proposed. The hypothetical domains with unsteady uniform and nonuniform flow field were used to demonstrated algorithm verification. In comparison with analytic solution, we obtained reasonable results and conducted simulation of hypothetical 3-D recharge/pumping area. The proposed algorithm can simulate saturated/unsaturated porous media with more practical problems and will greatly contribute to accuracy and stability of numerical computation.