• Resources Recycling
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• v.28 no.1
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• pp.23-31
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• 2019

Cementation is one of economical and efficient recycling method precipitating the metal ion in solution by adding another active metal. In this study for optimizing cadmium recovery efficiency, it was performed as a function of the effect of pH, temperature, particle size, and input amount of zinc in 0.1 M $CdSO_4$ solution and Ni-Cd battery leaching solutions, respectively. The particle size of zinc and temperature were key factors for Cd cementation and it was confirmed that the input amount of 2.6 of Zn/Cd ratio using granular-type zinc was optimal condition for selective Cd recovery efficiency at $25^{\circ}C$.

• Resources Recycling
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• v.27 no.4
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• pp.36-43
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• 2018

In order to recycle waste nickel-cadmium batteries, cadmium was selectively removed by ion substitution reaction so that cadmium and nickel could be separated efficiently. The electrode powder obtained by crushing the electrode in the waste nickelcadmium battery was leached with sulfuric acid. The cadmium in the nickel-cadmium solution was precipitated with cadmium sulfide by the addition of sodium sulfide. Ion substitution experiments were carried out under various conditions. At the optimum condition with pH = -0.1 and $Na_2S/Cd=2.3$ at room temperature, the residual Cd in the solution was about 100 ppm, and most of it was precipitated with CdS.

• The Science & Technology
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• v.32 no.12 s.367
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• pp.14-15
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• 1999

지난 20여년동안 수소저장합금에 관한 연구에 몰두해 온 전북대 신소재공학부 송명엽교수는 재충전이 가능한 2차전지 개발에 성공하여 상품화하는데 심혈을 기울이고 있다. 송교수가 개발한 2차전지는 현재 사용하고 있는 니카드 2차전지보다 전지용량이 1.5~2배에 이르는 우수한 성능을 갖고 있어 휴대용 전화기를 비롯해 노트북 컴퓨터, 켐코더 등의 새로운 전원으로 대체될 것으로 기대를 모으고 있다.

• Resources Recycling
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• v.26 no.5
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• pp.67-76
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• 2017

In order to efficiently recycle waste industrial nickel-cadmium batteries, anodic and cathodic materials were crushed by a cut mill and classified by sieves. We used wet magnetic separation method for eliminating iron components from the crushed powders. In addition, the acid leaching test for the obtained anode and cathode powders was carried out under various conditions by means of the wet process. At the optimum leaching conditions with 2.0 M $H_2SO_4$ at $90^{\circ}C$, 15 wt $H_2O_2$ and L/S=20 for 3 hours, the leaching efficiency of nickel and cadmium was 99%, respectively.

• Resources Recycling
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• v.28 no.5
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• pp.51-59
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• 2019

This study focused on the synthesis of the nickel hydroxide using ammonium sulfate in leaching solution from waste nickel-cadmium batteries. The effect of pH, temperature and the input amount of ammonium sulfate in leaching solution was investigated. The ammonium nickel sulfate with high purity was obtained in acidic leaching solution and the solution temperature of $60^{\circ}C$. The suitable molar ratio of the input amount of ammonium sulfate to nickel in solution is 2:1. The impurity about 1.4 at.% of Cd was included in the nickel hydroxide precipitates when ammonium nickel sulfate was used. At the process using sodium sulfide which precipitates the cadmium in solution, nickel and iron compounds were precipitated together.

• Journal of the Korean Electrochemical Society
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• v.10 no.1
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• pp.31-35
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• 2007

In this review article, we are going to explain the recent development of lithium secondary batteries for a cellular phone. There are three kinds of rechargeable batteries for cellular phones such as nickel-cadmium, nickel-metal hydride, and lithium ion or lithium ion polymer. The lithium secondary battery is one of the most excellent battery in the point of view of energy density. It means very small and light one among same capacity batteries is the lithium secondary battery. The market volume of lithium secondary batteries increases steeply about 15% annually. The trend of R&D is focused on novel cathode materials including $LiFePO_4$, novel anode materials such as lithium titanate, silicon, and tin, elecrolytes, and safety insurance.

• Resources Recycling
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• v.8 no.5
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• pp.28-33
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• 1999

Trus paper presenls a hydrometallurgical process Tor recovcnng ~uckcals mckcl sulfate fiom the spent nickel-cadrnlum bauery in whch c:,dmi~lm war re~novcdb y vapowing m e h d in vacuum. F ~ s ts,e lcct~vcc rushing and classification mell~odw ere performed to separate iron physically and the nickel-rich sample (over 80% nickel) was obtained. Ths sarnple was dissolved in sulf~ uiuica cid to obtain a luckcl sulfatc soluho~d~o se to its seluradon painl. TIE Cree acid in the unpurificd nickcl solut~onw as neutl-dized and iron war ve~novedk om the solulmn Thc mckel sulhte solution was c~yst~llizeadt around 45'C to obtain ruckel sulfate henahyril-ate.

• Proceedings of the Korea Information Processing Society Conference
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• 2017.04a
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• pp.657-660
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• 2017

최근에 개발된 출입문 시스템은 출입자의 신원과 출입시간을 정확하게 기록할 뿐만 아니라 방문자에게 일시적인 출입권한을 동적으로 부여하기도 한다. 이러한 기능은 스마트폰에 NFC 카드 에뮬레이션 기능이 탑재되기 시작하면서 가능해졌다. RFID와 달리 스마트폰에 탑재된 NFC는 출입할 때마다 변경되는 전자키를 전달 할 수 있고 출입키 이외에 여러 가지 정보를 전달할 수도 있다. 이는 매우 강력한 보안기능을 구현할 수 있는 토대가 될 뿐만 아니라 더욱 다양한 기능을 출입문에 부여할 수 있는 기반 기술이 된다. 본 논문에서는 오프라인 단말기와 스마트폰을 이용한 출입시스템을 제안한다. 오프라인 단말기란 출입문에 부착된 NFC 단말기가 오프라인 상태, 즉 외부로 통신이 연결되지 않은 상태에 있는 것을 의미한다. 본 시스템은 출입문 단말기에 출입자의 정보를 등록하지 않고 동적으로 출입자를 추가하거나 삭제할 수 있어 비정기적인 방문자를 위한 출입시스템을 구현하기에 매우 유리하다. 또한, 본 시스템은 오프라인 단말기를 이용하지만 온라인 단말기를 이용한 시스템과 동일한 기능을 구현할 수 있다. 단말기에 통신라인을 연결하지 않음에도 불구하고 기존 온라인 단말기를 이용한 출입 시스템에서 가능했던 출입자 실시간 등록과 출입사항 기록 및 실시간 조회 기능을 모두 구현할 수 있게 된 것이다. 온라인 단말기 기반의 출입 시스템 보다 유지보수가 쉽고 저렴한 출입시스템을 구현할 수 있다는 것은 본 논문에 제안한 방식의 강점이다.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.19-27
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• 2022

Fish that inhabited in the watersheds of Andong, Imha and Yeongju Dam in the upper Nakdong River were analyzed heavy metals by separated into muscle, gill, stomach and liver part. Thirteen fish species such as dark chub, skygager, coreoperca herzi, Korean piscivorous chub, cornet fish, Japan crucian carp, catfish, bass, crucian carp, mandarin fish, carp, long-nosed barbel, Korean sharpbelly were analyzed using ICP/MS. The results of the analysis based on the overall average concentration showed that the muscle part is lower than other parts in all heavy metal items except mercury. The gill part showed high concentrations of chromium, manganese, nickel, and lead, the stomach part has high zinc, and the liver part showed high concentrations of iron, copper, arsenic, and cadmium.