• Title/Summary/Keyword: 농도방정식

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A Study on Characteristics of Sedimentation Rate of Suspended Fine Particles under Floc Size and Density (플록의 입경과 밀도에 따른 부유된 미세 미립자의 침전률 특성에 관한 연구)

  • Kim, Jong-Woo
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.4
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    • pp.107-113
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    • 2009
  • This paper considers the influence of floc on the sedimentation rate for the cohesive material. The effects of floc density and size changes were also taking into consideration during the experiment. The settling velocity of a discrete floc was measured in a quiescent water column. Floc diameter and density were investigated using a modified Stokes equation with some constants such as water density, viscosity, material density and the floc fractal dimension $n_f$ obtained from the relationship between the floc diameter and the floc settling. The floc diameter of quartz and alumina increased at increasing initial concentrations. The floc size of quartz with increasing NaCl concentration varied between approximately 0.8 um to $10{\mu}m$. Floc density decreased as floc size increased. The floc settling velocity and the floc diameter have a straight line relationship on a logarithm. The floc fractal dimension nf was 2.65 with increasing of initial concentration and 2.93 with increasing of NaCl. The exponent n to predict the settling velocity was proposed and varied from 1 to 1.93.

Transport and Distribution of Calcium Salt in Tofu Manufacturing Process -Part I. Conductometric Measurement of Calcium Salt in Tofu and Drained Solution- (두부제조공정(製造工程)중 Calcium 염(鹽)의 행동(行動)과 분포(分布) -제1보(第一報). 전기전도도법(電氣傳導度法)에 의한 두부 및 순물의 Calcium 농도 측정방법(測定方法)-)

  • Yim, Sang-Bin;Lee, Choon-Ki;Chun, Jae-Kum
    • Applied Biological Chemistry
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    • v.28 no.1
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    • pp.8-12
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    • 1985
  • For measuring calcium content during the manufacturing process of Tofu, conductometric electrodes were made with the copper plate, and the results were compared with chemical analysis methods. Three types of plate material (I, II, III) for electrode were tested to apply for measuring $CaCl_2$ content in solution, drained solution from Tofu and in agar-agar gel ana Tofu. Empirical linear correlation equations between conductivity (Y, mho) and calcium content (C, Mole $\bar{C}$, mg% wet basis) were obtained for the quick estimation of calcium content during Tofu processings. Equations with plate II type electrode were Y=0.6364C+0.0775 for drained solution with r=0.99, and $Y=7.1503{\times}10^{-5}\bar{C}-2.9895{\times}10^{-3}$ for Tofu with r=0.91,respectively.

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Subthreshold Current Model for Threshold Voltage Shift Analysis in Junctionless Cylindrical Surrounding Gate(CSG) MOSFET (무접합 원통형 게이트 MOSFET에서 문턱전압이동 분석을 위한 문턱전압이하 전류 모델)

  • Jung, Hakkee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.4
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    • pp.789-794
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    • 2017
  • Subthreshold current model is presented using analytical potential distribution of junctionless cylindrical surrounding-gate (CSG) MOSFET and threshold voltage shift is analyzed by this model. Junctionless CSG MOSFET is significantly outstanding for controllability of gate to carrier flow due to channel surrounded by gate. Poisson's equation is solved using parabolic potential distribution, and subthreshold current model is suggested by center potential distribution derived. Threshold voltage is defined as gate voltage corresponding to subthreshold current of $0.1{\mu}A$, and compared with result of two dimensional simulation. Since results between this model and 2D simulation are good agreement, threshold voltage shift is investigated for channel dimension and doping concentration of junctionless CSG MOSFET. As a result, threshold voltage shift increases for large channel radius and oxide thickness. It is resultingly shown that threshold voltage increases for the large difference of doping concentrations between source/drain and channel.

Prediction of Carbonation Progress for Concrete Structures Considering Change of Atmospheric Environment (대기환경변화를 고려한 콘크리트 구조물의 중성화 예측)

  • Lee, Chang-Soo;Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.574-584
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    • 2003
  • The most common deterioration cause of concrete structures in urban environment is carbonation. Recently, the $CO_2$ concentration and temperature at atmosphere is sharply increased with time due to global warming phenomena. In this study, the climate scenario IS92a, which was suggested by the IPCC, is used to consider temperature and atmospheric $CO_2$ concentration change in the model of service life prediction. The modified mathematical solution, which was based on the Fick's 1st law of diffusion, was used to reflect concrete materials properties such as the degree of hydration of concrete with elapsed time, and important parameters, which associated with deterioration rate. The techniques of service life prediction are developed introducing the method of reliability and stochastic concept to consider microclimatic condition in Seoul, South Korea. From the result of service life prediction, concrete containing high W/C ratio is shown fast carbonation rate due to $CO_2$ concentration increase. It is concluded that the deterioration of concrete structures due to carbonation is insignificant problem on the conditions that below W/C 55%, well curing concrete.

Experimental Study of Flow and Pollutant Dispersion in Meandering Channel (사행수로에서의 흐름 및 오염물질 혼합에 관한 실험적 연구)

  • Park, Sung-Won;Seo, Il-Won;Lee, Kyu-Hwan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.883-888
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    • 2007
  • 일반적인 하천의 흐름방향으로 발생하는 주흐름(primary flow)에 중첩하여 주흐름 방향의 수직단면에 이차류(secondary flow)가 발생하게 되며 이러한 이차류의 발달은 투입된 오염물질의 횡혼합을 증대시킨다. 오염물질의 혼합은 이송(advection)과 확산(diffusion) 또는 분산(dispersion)의 과정으로 설명되며 본 연구에서는 수로전체의 혼합과정을 설명하기 위해서 이송 확산 방정식을 적용하였다. 본 연구에서는 실험수조를 $150^{\circ}$의 중심각을 갖는 S자 형태의 만곡수로를 제작하여 유량조건은 15, 30, $60\;{\ell}l/sec$의 세 가지 경우로, 수심은 15, 20, 30, 40 cm의 경우로 총 12 케이스의 실험을 수행하였다. 유속장의 측정은 Sontek사의 3차원 micro-ADV(Acoustic Doppler Velocimeter)를 이용하였다. 오염물질 확산실험은 소금물 용액에 주변수와의 밀도차를 없애기 위해서 메탄올 용액을 첨가하여 추적자로 이용하여 농도장의 분석을 일본 KENEK사의 전기전도도계(conductivity meter)와 Gartner사의 DAS(data acquisition system)를 이용하여 횡방향 유속장의 분포와 오염운의 거동을 비교하여 다음과 같은 결론을 얻게 되었다. 주 흐름은 직선구간에서는 중앙에서 최대 유속을 나타내며, 좌우대칭적인 유속분포의 모습을 보이고, 만곡부에서는 수로안쪽을 따라 최대유속이 발생하였다. 수로의 직선구간에서는 최대유속이 발생하는 즉, 중앙에서의 오염물질의 분산이 가장 활발하게 이뤄졌으며 농도의 퍼짐형상인 오염운 역시 만곡부에서는 수로만곡부의 안쪽을 따라 확산 이동함을 알 수 있었다. 만곡부 외측에서는 오염물질의 정체현상이 일시적으로 발생하며, 유속구조의 횡방향 비대칭구조로 인한 종 횡방향의 분리현상이 발생하고, 오염운의 중첩현상이 종방향으로 연속되게 나타난다. 향후 수심방향 거동을 포함한 3차원적 분석이 요구되며 이 연구결과는 2차원적 수치해석의 적용 및 분석 자료로써 이용이 가능하다.

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Analysis of the Effects of CO Poisoning and Air Bleeding on the Performance of a PEM Fuel Cell Stack using First-Order System Model (일차계 모델을 이용한 고분자전해질 연료전지 스택의 CO Poisoning 및 Air Bleeding 효과 분석)

  • Han, In-Su;Shin, Hyun Khil
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.370-375
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    • 2013
  • We analyze the effects of CO poisoning and air bleeding on the performance of a PEM (polymer electrolyte membrane) fuel cell stack fabricated using commercial MEA (membrane electrode assembly). Dynamic response data from the experiments on the performance of a stack are identified by obtaining steady-state gains and time-constants of the first-order system model expressed as a first-order differential equation. It is found that the cell voltage of the stack decreases by 1.3-1.6 mV as the CO concentration rises by 1 ppm. The time elapsed to reach a new steady state after a change in the CO concentration is shortened as the magnitude of the change in the CO concentration increases. In general, the steady-state gain becomes bigger and the time-constant gets smaller with increasing the air concentration (air-bleeding level) in the reformate gas to restore the cell voltage. However, it is possible to recover 87%-96% of the original cell voltages, which are measured with free of CO, within 1-30 min by introducing the bleed air as much as 1% of the reformate gas into the stack.

First-Order Mass Transfer in a Diffusion-Dominated (Immobile) Zone of an Axisymmetric Pore: Semi-Analytic Solution and Its Limitations (대칭형 다공성 매질의 확산주도 영역에 관한 1차 물질이동 방정식)

  • Kim, Young-Woo;Kang, Ki-jun;Cho, Jung-ho;Kabala, Zbigniew
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4664-4670
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    • 2010
  • Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.

The Measurement of Airborne Radon Daughter Concentrations in the Atmosphere (대기중(大氣中) 라돈 붕괴생성물(崩壞生成物)의 공기중(空氣中) 방사능(放射能) 농도(濃度)의 측정(測定))

  • Ha, Chung-Woo;Lee, Jai-Ki;Moon, Philip S.;Yook, Chong-Chul
    • Journal of Radiation Protection and Research
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    • v.4 no.1
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    • pp.5-13
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    • 1979
  • A simple method for determining the airborne concentration of radon daughter products has been developed, which is based on gross alpha counting of the air filter collections at several time intervals after completion of air sampling. The concentration of each nuclide is then obtained from an equation involving the alpha disintegrations, the sampling time, and the known numerical coefficients. The state of radioactive disequilibrium is also investigated. The atmosphere sampled in the TRIGA Mark-III reactor room was largely in disequilibrium. The extent of radioactive disequilibrium between radon daughter products seems likely depend on sampling times associated with turbulence conditions. The data obtained here will certainly provide useful information on the evaluation of internal exposure and calibration of effluent monitoring instruments.

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Analytical Solutions for a Three-Member Decay Chain of Radionuclides Transport in a Single Fractured Porous Rock (단일균열 다공성암반에서 방사성핵종의 수송에 대한 3단계 붕괴사슬의 해석해)

  • Yu, Young-Woo;Chung, Chang-Hyun;Kim, Chang-Lak
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.453-460
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    • 1994
  • The migration equation is modified for a three-member decay chain in the fracture and porous matrix Analytical solutions are obtained by utilizing Laplace transform the initial conditions of Delta function and Bateman equation. The concentrations for each nuclide of Np$^{237}$ -U$^{233}$ -Th$^{229}$ and U$^{234}$ -Th$^{230}$ -Ra$^{226}$ chains selected from the 4n+1 and 4n+2 chains are plotted by utilizing analytical solutions in the fracture. Retardation coefficient of the nuclides are obtained using those of the granite. The results indicate that the daughter nuclides such as U$^{233}$ , Th$^{229}$ , Th$^{230}$ and Ra$^{226}$ become important at the far field from the repository though there is very small initial inventory in the waste solid or spent fuel, for they are produced by the mother nuclides decayed in the fracture and porous matrix.

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Interpretation of Ammonia Absorption Behavior in Water Turbulent Flow (물 난류에서의 암모니아 흡수 거동 해석)

  • Lee, Sang-Ryong;Park, Jin-Won
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.3
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    • pp.75-80
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    • 2019
  • The article is devoted to the interpretation of ammonia, one of the fine dust precursors, absorption behavior in water turbulent flow. The water flow was considered as a turbulent flow with Reynolds number more than $10^4$, because ammonia gas penetration depth was deeper at turbulent flow compared to laminar flow. For the interpretation, the dimensionless mass transfer governing-equation and the constant physical-properties at room temperature were used. The diffusivity of ammonia in water and the kinematic viscosity of water were $2{\times}10^{-9}m^2/s$ and $1{\times}10^{-6}m^2/s$, respectively. The concentration distribution of ammonia in water was estimated with respect to the position from the point where the water started to be exposed to ammonia. The quantitative distribution as a function of the mixing length was also acquired. The quantitative interpretation may provide the insight how much the turbulent flow was more efficient to remove ammonia rather than the laminar flow.