• Title/Summary/Keyword: 노화 측정

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Effect of Solar Radiation Aging on the Properties of Epoxy Polymers (에폭시 폴리머의 물성에 미치는 태양광 복사 노화의 영향)

  • Lee, Dong-Geon;Lee, Sang-Bong;Kim, Myung-June;Park, Jung-Sun;Lee, Soo-Yong;Kang, Tae-Yeob
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.9
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    • pp.769-774
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    • 2016
  • Epoxy polymer exposed to solar radiation on long-term is required to a long-term environmental test in order to ensure the reliability of operation performance. In this paper, the solar aging experiment is performed for 7, 14, 28, 56, and 84 cycles, using solar simulator designed according to MIL-STD-810. After the aging experiment, measuring RGB values and using the CIE1976 color space, each RGB decreasing rates and total color shift are calculated. In addition, using a universal testing machine, mechnical properties according to ASTM-D638 are measured. As a result, by increasing solar aging period, total color shift is increased, and the tensile strength and elongation are decreased, but the elastic modulus and the poisson's ratio are slightly changed.

HP-GPC Analysis for Characteristics Change of Asphalt Cement Due to Aging (노화(老化)에 의한 아스팔트 시멘트 형질변화(形質變化)의 HP-GPC 분석(分析))

  • Kim, Kwang Woo;Yeon, Kyu Seok;Choi, Joong Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.4
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    • pp.49-57
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    • 1992
  • This study was conducted to evaluate physical property change of asphalt cement chromatograms (by HP-GPC) were experimentally obtained from 3 types of AC-20 virgin ACs, 5 and 24-hour artificially aged ACs, and naturally aged 4 ACs that were recovered from 4 different roads. Absolute viscosity, kinematic visoosity and penetration were the physical properties tested. THF was used for mobil phase and RI detector was used as a detector for Hp-GPC testing. Correlation between each physical property change and the chromatogram variation was evaluated. Each chromatogram was divided into ten-equal-time slices. The percentage areas of 10 slices and each physical property were used for statistical correlation evaluation. Statistical analysis results showed that eaoh physical property had a strong correlation with the chromatogram characteristics. Aging was identified as a mechanism of change of molecular size distribution - increasing large size molecules and reducing coresponding samll size molecules.

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Anti-aging effects of casuarictin on UVB-induced CCD-986sk cell (UVB유도성 CCD-986sk cell에서의 Casuarictin의 항노화 효과)

  • Kim, You Ah;Kim, Dong Hee;Kim, Young A;Yu, Jae Myo;Park, Byoung Jun;Son, Jun Ho
    • Journal of Applied Biological Chemistry
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    • v.60 no.1
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    • pp.13-17
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    • 2017
  • To develop a new functional agent for cosmetics, we investigated the anti-aging activities in fibroblasts of casuarictin. The anti-aging effect of casuarictin in CCD-986sk cell was as follows: it inhibited ROS expression increased by Ultraviolet B and suppressed pro-collagen expression. Also, casuarictin had inhibited Matrix metalloproteinase-1 expression. Therefore, the results suggested that casuarictin has considerable potential as a cosmetics ingredient with a anti-aging effect.

Gelatinization and Retrogradation Properties of Modified Starch by Steeping Sweet Potato (고구마 수침에 의한 변성 전분의 호화와 노화 특성)

  • Lee, Shin-Kyung;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.26 no.5
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    • pp.638-643
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    • 1994
  • Gelatinization and retrogradation properties of modified starches which were prepared by steeping sweet potato at $40^{\circ}C$ for 2, 4, 7 and 10 days were investigated. The peak temperature of gelatinization and enthalpy of untreated starch by DSC were $53.9^{\circ}C\;and\;1.32\;cal/g$, respectively, but those of modified starch were increased by steeping. In gelatinization by alkali, starches with 2, 4 and 7 day steeping showed higher viscosities than untreated starch, whereas the viscosities of starches with 10 day steeping decreased. The clarities in paste decreased during storage in all starches and decreased in starches with steeping. The degrees of retrogradation by ${\alpha}-amylase-iodine$ method were higher in starches with steeping than untreated starch. The enthalpy of retrograded starches by DSC increased by steeping except 4 day steeping starch. The sweet potato extract containing sugar inhibited the retrogradation of starch paste and the degree were higher in residual starches than in untreated starch.

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The Analysis on the Effects of Hygrothermal Aging to THPP Using DSC and XPS (DSC와 XPS를 통한 수분노화가 THPP 점화제에 미치는 영향 분석)

  • Oh, Juyoung;Kim, Yoocheon;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.79-92
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    • 2019
  • Titanium hydride potassium perchlorate (THPP) is one of the commonly utilized pyrotechnic materials in aerospace industries. The current study elucidates the effects of hygrothermal aging on the combustion of THPP experimentally. First, applying the Differential Scanning Calorimetry (DSC) and isocoversional method, both the delay of reaction start and decrease in maximum reaction rate were observed. The kinetics parameters tended to fluctuate depending the thermal reaction or intermediate product formation of THPP. Also, the oxidants decomposition and fuel oxidation phenomenon were discovered by X-ray photoelectron spectroscopy (XPS). The experimental heat from DSC data were verified as reasonable by comparing with the theoretical heat obtained utilizing both THPP formulation from XPS and NASA Chemical Equilibrium with Applications (CEA). Both data had identical variation trend, which expecially had the highest heat value at 10 weeks aged sample.

Study on the Degradaion Behavior of Acrylonitrile Rubber(NBR) O-ring by Intermittent CSR and Time-Temperature Superposition Principle (간헐 압축응력완화 시험법과 시간-온도 중첩 이론을 이용한 NBR 오링의 노화 거동 분석 연구)

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myung Chan;Yun, Yu Mi;Kim, Wonho;Park, Sung Han;Jo, Nam-Ju
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.46-51
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    • 2019
  • Intermittent CSR testing was used to investigate the degradation of a NBR O-ring, and also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. Degradation of O-rings by thermal aging was observed between $40^{\circ}C$ and $120^{\circ}C$. O-rings showed non-linear degradation behavior under $80^{\circ}C$. At 20% of failure condition, predicted life-times were 32.5 years by Arrhenius plot and 22.6 years by WLF plot.

Comparison on Retrogradation Properties of Cowpea and Mung Bean Starch Gels (동부와 녹두전분 Gel의 노화특성 비교)

  • Yoon, Gae-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.6
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    • pp.672-676
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    • 1992
  • Retrogradation properties of cowpea and mung bean starch gels were investigated by rate of retrogradation, X-ray diffraction patterna and syneresis of gels. Retrogradation time constant of mung bean starch gel(30%) by Avrami equation had a similar value to that of cowpea starch gel. X-ray diffraction patterns of the two retrograded starch gels(10%) were B-type. The extent of retrogradation determined by syneresis showed that cowpea starch gel was a little larger than that of mung bean starch gel(6~10%).

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Anti-aging Effects of Sweroside Isolated from Nymphoides indica (어리연꽃으로부터 분리한 Sweroside의 항노화 효과)

  • Kim, You Ah;Kim, Dong Hee;Park, Chae Bin;Park, Tae Soon;Park, Byoung Jun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.2
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    • pp.103-110
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    • 2018
  • To develop a new functional agent for cosmetics, we investigated the anti-aging activities in fibroblasts using sweroside isolated from Nymphoides indica. The anti-aging effect of sweroside was validated in CCD-986sk cells. Results showed that sweroside inhibited expressions of UVB-induced ROS and increased pro-collagen. Furthermore, sweroside had inhibited MMP-1 expression. Taken together, the results suggested that sweroside has considerable potential as a new cosmetics ingredient with an anti-aging effect.

Storage Reliability Evaluation of Engine Assembly (엔진 조립체의 저장 신뢰도 평가)

  • Park, Jong-Won;Chang, Mu-Seong;Park, Tae-Kook;Kim, You-Il;Kim, Sun Je
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.157-159
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    • 2017
  • This paper presents a storage reliability evaluation method based on the accelerated degradation test for the engine assembly and parts of the guided missile. The test of the engine assembly is performed at accelerated conditions equivalent to the real storage period, and then the aging condition of parts is checked. For engine parts, performance degradation characteristics are measured periodically at the accelerated conditions and failure times are predicted at each condition. Storage lifetime at normal use conditions is predicted using an accelerated model and failure times at all accelerated conditions.

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Effect of TESPT Silane Coupling Agent on Mechanical Properties of Precipitated Silica Filled NBR Compound for Oil Seal (TESPT 실란커플링제가 침전 실리카로 보강된 오일씰용 NBR복합소재의 기계적 물성에 미치는 영향)

  • Lee, Young-Seok;Hwang, Ki-Seob;Lee, Jong-Cheol;Kim, Tae-Geun;Ha, Ki-Ryong
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.45-53
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    • 2011
  • The effect of the silane coupling agent, bis(triethoxysilypropyl)tetrasulfide (TESPT), on mechanical properties of a silica-filled NBR compound for oilseal was investigated. Curing behavior and crosslinking density of the compounds were measured using ODR (oscillating disk rheometer) and swelling ratio in toluene. UTM (universal testing machine) and shore A hardness tester were used in order to study the characteristics of mechanical properties of original vulcanizates and aged ones with heated air and ASTM No. 3. oil. Recovery of elasticity which influences the performance and service life of oilseal was investigated by giving bending deformation to vulcanizates in aging condition. After bending aging test, recovery distance was measured and calculated angle of recovery from it. TR (temperature retraction) test was performed on these vulcanizates to determine the low temperature recovery behavior. Wear resistance was measured by Taber type abrasion tester. In addition, SEM was used to characterize the morphology of the worn surface of vulcanizates. The result showed that addition of TESPT into silica-filled compound improves not only compound flow-ability, interaction between NBR and silica and crosslinking density, but also hardness, 100% modulus, recovery of elasticity, wear resistance, heat resistance and ASTM No.3 oil resistance of vulcanizates.