• The Journal of the Convergence on Culture Technology
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• v.6 no.3
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• pp.449-456
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• 2020

When you move to a new home, or when you change the wallpaper or flooring of your home, office, etc., you can enjoy the joy of opening your new home with the sick house syndrome, such as the stinging smell and stinging eyes that may appear after the interior work. It is only a moment. Volatile organic compounds from building materials, adhesives, wallpaper, and paints used in new buildings or new furniture cause residents' health and discomfort in indoor life. These volatile organic compounds include benzene, toluene, acetone, and styrene, as well as the representative formaldehyde, and these substances are slowly released over a long period of time, causing acute or chronic diseases to residents. As a method for removing organic volatile substances, physical methods using adsorption, chemical methods for converting volatile substances to other substances, or a mixture of the two are mainly used. In this paper, a sustained release chlorine dioxide gel pack obtained by a method for controlling the reaction rate of a reactant and the release of a product is mixed with a zeolite adsorbent having an optimized hole diameter to adsorb and decompose and remove formaldehyde suspended in the air. I would suggest an effective method.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1123-1128
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• 2005

NIB(methylisoborneol) is an earthy/musty odor compound produced as a second metabolite by cyanobacteria and actinomycetes. MIB is not removed by conventional water treatment(coagulation, sedimentation, filtration) and its presence in tap water, even at low ng/L levels, can result in consumer complaints. PAC(powdered activated carbon) can effectively remove MIB when the correct dose is applied. But, since most operators in water treatment plants apply a PAC dose and then adjust that dose depending on direct observation (odor detection) after treatment, the result is often under-dose or eve,-dose. In this study, kinetic and isotherm tests using $^{14}C$-radiolabeled MIB were performed to determine coefficients for the HSDM(homogeneous surface diffusion model), including liquid film mass transfer coefficient($K_f$) and surface diffusion coefficient ($D_s$). The HSDM gave a reasonable fit and allowed prediction with the experimental data. Base on the HSDM, the authors developed an optimum PAC dose prediction program using the Excel spreadsheet. When the developed program was applied at two water treatment plants, the PAC dose based on the experience of operators in the water treatment plant was significantly different from that recommended by the newly developed program. If operators are willing to use the optimum PAC dose prediction program, it should solve dosing problems.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.2097-2104
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• 2000

Naturally occurring taste and odor problems include those produced by microorganism. notably algae and bacteria. The major compounds causing taste and odor are MIB and Geosmin which can cause earthy-musty at very low concentration 9ng/L and 4ng/L, respectively. Especially, the problem is very serious from summer to fall in source and finished water. It is well known that using PAC is one of the best technology to control these compounds in drinking water treatment. In this study, optimum dosage and dosing time of PAC were observed with the adsorption isotherm experiments in single and binary compounds. Also, the effect of natural organic matter(NOM) was investigated by using a natural water with JSW. The adsorption capacity of Geosmin was higher than MIB in both with NOM and without NOM. The adsorption capacity of Geosmin and MIB was 4 times lower with NOM than that of without NOM. which was caused by competition adsorption. When the initial concentration of Geosmin and MIB were 100ng/L in JSW, at least 4 hours of reaction time was needed to achieve 99% removal with 20mg/L of the PAC.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.4
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• pp.455-460
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• 2008

Powered activated carbon(PAC) has been widely applied for controling odor causing compounds(OCCs) from water treatment plants. Because of their volatility, the OCCs can also be removed from water by air stripping methods. In this study, OCCs removal was tested with PAC adsorption, air stripping, and both PAC adsorption and air stripping from the Taecheong lake water. Removal efficiency of OCCs in terms of threshold odor number(TON) were 39.6% by both PAC (15mg/L) adsorption and aeration for 30 min, 33.6% by PAC(15mg/L) adsorption alone for 30 min, and 22.9% by aeration alone for 30 min, respectively. OCCs could be removed up to 50% by aeration for 120 min without PAC adsorption. At an extended aeration with 15mg/L of PAC, OCCs removal occurred mainly by PAC adsorption within 30 min aeration while it continued by air stripping afterward. At simulated jar tests with the raw water, removal efficiencies of geosmin and MIB were 48.3, 36.1% by coagulation and sedimentation without PAC addition. With 15mg/L of PAC on the same jar tests, the removal efficiencies were 83.1, 60.1%, respectively. Without PAC, OCCs could be possibly removed by stripping during the agitation processes.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.520-520
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• 2016

석유 화학공장에서 발생하는 spent sulfidic caustic (SSC) 폐수는 액화석유가스(LPG)나 천연가스(NG)의 정제과정에서 발생되는 것으로 고농도의 sulfide와 cresylic, phenolic 그리고 mercaptan 등이 포함된 독성과 냄새를 유발하는 물질이다. 이러한 물질들은 LPG나 NG의 정제과정에서 높은 산도를 가진 휘발성 황화합 물질들을 제거하기 위해 사용된 NaOH가 $H_2S$와 반응하여 발생하는 것이다. 진한 갈색 또는 검은색을 띄는 SSC 폐수는 12 이상의 높은 pH를 가지고 있으며 5~12 wt%의 높은 염분도를 가지고 있다. 또한 강한 부식성과 독성을 가진 황화합물의 농도가 1~4 wt%이며, 방향족 탄화수소 물질 (i.e. methanethiol, benzene, tolune and phenol)들도 다량 함유되어 있다. 따라서 이러한 유해 물질들은 기존의 하수처리 공정으로 방류하기 전에 완벽하게 처리해야만 하수처리 공정의 오염 부하량을 줄일 수 있다. 습식산화공정은 SSC 폐수를 처리하기 위해 흔히 사용되고 있는 물리-화학적 처리 공정이지만 고비용, 고에너지가 필요하며, 고온 및 고압에서만 작동되어 안전상의 문제점을 갖고 있다. 또한 습식산화공정을 거친 폐수는 배출허용기준을 만족하기 위해 생물학적 2차 처리가 반드시 필요하다. 철-과산화수소를 이용하는 펜톤산화 공정, 그리고 sulfide를 sulfate로 전환시키는 생물학적 처리 공정은 황화합물의 완전한 무기물화가 힘들며, 현장 적용 시 기술적 경제적 부담이 크다. 이러한 단점을 극복하고, SSC 폐수를 효과적으로 처리하기 위해 본 연구는, 높은 흡착력과 광산화력을 가진 흡착광산화 반응 시스템(Adsorption Photocatalysis System, APS)을 개발하였다. APS는 SSC 폐수를 시스템 내부로 유입하여 수중의 오염물질을 흡착광산화제로 구성된 반응구조체가 흡착하고, 흡착된 오염물질을 UV에너지와 이산화티타늄 광촉매의 광화학반응에 의해 최종적으로 무해한 물질로 환원시키는 폐수처리시스템이다. APS의 반응구조체는 태양에너지 및 인공에너지원에 의해 활용 가능하며, 난분해성 유기화합물질을 물과 이산화탄소로 분해할 수 있는 친환경적이고 경제적인 소재로서 널리 쓰이고 있는 이산화티타늄 광촉매와 화력발전소의 높은 소성온도에 의해 연소된 후 발생되는 bottom ash를 이산화티타늄의 지지체로 사용하여 높은 흡착력과 광촉매 산화력을 가진 복합물이다. 개발된 APS에 의해 SSC 폐수를 처리한 결과, COD 86.1%, 탁도 98.4%, sulfide 99.9%의 높은 처리효율을 보여주고 있다. 따라서 본 연구를 통해 개발된 APS는 강한 부식성과 독성 그리고 높은 농도를 가지고 있는 SSC 폐수를 효과적으로 처리할 수 있다.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.2
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• pp.237-247
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• 2012

This study assessed the removal characteristics of taste and odor causing compounds (2-methylisoborneol and geosmin) and organic matters, using a pilot-scale ozone/granular activated carbon ($O_{3}$/GAC) process treating surface water of Pal-dang reservoir in the Han river over a 3-month period. Experiments were conducted to verify the removal efficiency of $O_{3}$/GAC process which has two different empty bed contact time (EBCT) ($O_{3}$/GAC column 1 : 10 min and 2 : 15.1 min) with 10.86 min contact time of ozonation at 1.0 mg/L $O_{3}$. Spiking test using geosmin and 2-MIB was also conducted systematically to mimic the conditions when the algae appears, specifically at the levels similar to the concentrations experienced (geosmin: 250 ng/L) in the winter of 2011. In single ozonation process, organic materials, disinfection by-products (DBPs) and their precursors were disassembled but not removed completely. Meanwhile, it was verified that organic matters, taste and odor causing compounds, and DBPs were well removed when sequentially passing through the GAC process. The pilot results also showed that GAC column with larger EBCT achieved higher removal efficiency. Specifically, in spiking tests, single $O_{3}$ process showed approximately 89% removal efficiency of geosmin and 2-MIB. $O_{3}$/GAC combined process demonstrated excellent removal of geosmin and 2-MIB, which are higher than 95%.

• Journal of Korean Society on Water Environment
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• v.27 no.1
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• pp.104-109
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• 2011

The removal efficiencies of 2-methylisoborneol (MIB) and geosmin were investigated to reveal removal characteristics of typical organic compounds causing disagreeable taste and odor at the conventional water treatment plant installed with pulsator clarifier patented by the French company $Degr{\acute{e}}mont$. The injection rate of Powdered Activated Carbon (PAC) into water was changed step wisely as we conducted jar tests in the laboratory and water treatment in the actual plant. 2-MIB concentration decreased linearly while geosmin did exponentially along with the injection rate of PAC at our jar tests. The removal efficiency of geosmin by PAC injection was considerably higher than that of 2-MIB. In the real pulsator clarifier, 2-MIB concentration started decreasing as the injection rate reached up to 10 mg/L of PAC. On the other hand, the concentration of geosmin in water decreased proportional to the injection rate of PAC. In the sand filtration, removal efficiencies of 2-MIB and geosmin on July were much higher than those on March. It was carefully suggested beforehand and found afterwards that general microorganisms notably existed in the sand filter with no chlorine in filter influent and backwash water and the sand filter biologically activated removed much more odor compounds. It was considered as the reason why the removal efficiency of 2-MIB and geosmin was increased. The microbial activity maybe increased in summer with water temperature rising and low filtration rate possibly increased contact time between odor compounds and general microorganisms.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.2
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• pp.475-483
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• 2017

Geosmin and 2-methylisoborneol (2-MIB) produced by cyanobacteria during algal blooming in surface water are the major taste-and-odor-causing compounds in drinking water and need to be removed. Activated carbon is often used in treatment plants for the mitigation of odor problem. However, there is a lack of information on the effect of pore size distribution and particle size of activated carbon for adsorption of both odor compounds. Therefore, we studied the effect of pore size distribution and particle size of activated carbon on the adsorption of geosmin and 2-MIB. When comparing the adsorption of geosmin and 2-MIB between activated carbon fiber (ACF), powdered activated carbon (PAC) and granular activated carbon (GAC), the order of removal efficiency was PAC > ACF > GAC. As a result of comparing PACs with various pore distribution characteristics, well-developed micropores on activated carbon were found to be favorable for adsorption of geosmin and 2-MIB. For particle size, smaller was more effective for adsorption of geosmin and 2-MIB.

• Korean Journal of Clinical Laboratory Science
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• v.48 no.3
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• pp.230-236
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• 2016

Economic growth has increased the living standards around the world. Water pollution, in particular, is a public relations issue because it poses a direct threat to everyone's lives. As of recently, the production of taste and odor (T&O) compounds has been a common problem in the water industry. The adsorption process using granular activated carbon (GAC) has been the most widely used process. The objectives of this study were to evaluate the microorganisms before and after the backwashing of GAC and to identify the species of the microorganisms found. Five dominants microorganisms were confirmed after the microfiltration process from backwashing of GAC, and the dominant bacterial species were found to be ${\beta}$-proteobacterium species, Porphyrobacter donghaensis, Polaromonas rhizophaerae, Hydrogenophaga species, and Pseudonocardia species. However, when UV treatment after microfiltration was performed, Hydrogenophaga species and Psedonocardia species were eliminated. Herein, I conclude that the UV treatment post microfiltration process is more efficient than microfiltration process alone. The findings of this study may provide useful information regarding the management of microfiltration process.

• Food Science and Preservation
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• v.20 no.2
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• pp.207-214
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• 2013

This study was conducted to investigate changes in the main volatile flavor components of oriental melon during the process of alcohol fermentation via SPME (solid phase micro extraction). The flavor components of oriental melon were shown to have mainly included melon and green flavors. The green flavor was identified to be nonanal, 1-butanol, 1-octen-2-ol and benzene, and its relative concentration was shown to be 16.66%. The nonanal concentration was shown to have been reduced among the green-flavor components, but no significant change in remaining components was observed. Mainly, sweet flavor tended to increase, and the relative concentration of benzene was particularly shown to have increase by 25.58%, accounting for the highest relative concentration. The amount of green-flavor components, except for 1-butanol, was shown to have significantly decrease after alcohol fermentation. Then, no component of green-flavor, which causes an offensive smell, was found during fermentation and aging. Meanwhile, the volatile flavor components, which are consist of acids, were shown to have been produced during alcohol fermentation. In particular, octanoic acid, which causes off-flavor, was shown to be 60.99%, a very high relative concentration during the aging stage. In addition, acetic acid with a pungent sour flavor tended to be produced. A further study on the improvement of flavor in the production of oriental melon wine is required.