• Title/Summary/Keyword: 내황산

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Development of high performance patching repair mortars with light weight and sulfuric acid resistance properties (경량 및 내황산 특성을 가진 고성능 단면복구 모르타르의 개발)

  • Kim, Kyoungmin;Park, Junhui;Ahn, Tae-ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.4
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    • pp.167-172
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    • 2017
  • In this study, high performance patching repair mortars with light weight and sulfuric acid resistance properties were suggested. Their performance estimation were investigated based on KS F 4042 using patching repair mortar with light weight aggregate and soluble polymer of Type I and sulfuric acid resistance mortar of Type II, From these results, it was confirmed that these motors were satisficed and improved by all standard tests of KS F 4042.

해상 빅데이터 기반의 공간지도를 활용한 황산화물 배출규제 효과 분석

  • ;;;AKHAHENDA WHITNEY KHAYENZELI
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2023.05a
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    • pp.137-139
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    • 2023
  • MARPOL (Maritime Pollution Treaty) 부속서 (Annex VI) 경우 대기오염 규제 내용이며, 최근 선박 배기가스 배출규제 강화 목적 개정됨에 따라 관련 규정을 충족하기 위한 적극적인 조치가 요구된다. 예를 들어 Sulfur Dioxide (SOx, 황산화물) 경우 2020년 기준 전 세계 해역 내 운항하는 선박은 황 함유량 0.5% 기준의 배출 요구 기준을 충족해야 한다. 배출규제 해역 지정 시 해당 해역 선박 배기가스 배출량 계산 산정 기준 확립이 필요함에 따라 대기환경에 대한 종합적인 분석이 필수적으로 요구된다. 본 연구에서는 황산화물 배출량 산출 방법론으로써 그리드 셀 내 선박 점유시간을 계산한다. 점유시간이 길수록 선박 통항 및 배기가스 배출이 밀집되어 있음을 의미한다. 밀집도 분석에 더불어 선박의 특성이 반영된 시간당 배출량을 적용하여 배출 공간 인벤토리를 구축하였으며 분석 결과를 GIS (Geographical Information System) 환경에서 공간 지도로 시각화하였다. 기존 국내 황산화물 배출규제 해역의 효과 평가에 더불어 외항 범위까지 규제 확대 시나리오확립 후 비교 평가를 통하여 배출량 감소 효과를 정량적으로 확인하였다.

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Study on the stability of ammonium cobalt thiocyanate solution and the formation of perthiocyanuric acid (Ammoninm Cobalt Thiocyanate 용액의 안정도 및 Perthiocyanuric acid의 생성반응에 관한 연구)

  • 최종인
    • YAKHAK HOEJI
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    • v.7 no.2_3
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    • pp.36-41
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    • 1963
  • Cobalt thiocyanate ion에 미치는 영향을 연구하였다. Cobalt ion이 $NH_{4}CNS$ 용액에 의해서 생성되는 ion의 색의 transmittance는 확산에 의하여 적어지며, 황산존재하에서는 황산의 양과 Transmittance 사이에 비례적 관계가 있다. 염산 및 질산도 역시 Transmittance의 값에 영향을 미치기는 하나 염산의 경과에는 이 착 ion이 황산존재하보다 다소 불안정하며 질산에 의해서는 안정화가 극히 적어서 단시간내에 Perthiocyanuric acid로 인정되는 물질로 분해한다. 또한 그 Transmittance가 과량의 광산존재하에서 적어지는 현상으로 부터 $Co(SCN)^{2-n/_{$ n/의 n의 값이 커지는 것은 ether에 이행하는 SCN-을 Volhard 씨법으로 정량함으로서 확증하였다.

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${SO_4}^{2-}$ ion Removal from Solution by Crystal Precipitation on Surface Active Glasses (표면활성유리에의 결정석출을 이용한 용액중 황산염 이온 제거)

  • 남명식;김철영
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1286-1293
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    • 1998
  • ${SO_4}^{2-}$ ions present in industrial waste water if combined with other metal ions in the water can cause serious scale problem in a transporting pipe. In this study therefore ${SO_4}^{2-}$ ions in an acidic solution have been removed by using surface active glasses. Glasses with various compositions of $SiO_2-Na_2O-B_2O_3-RO$ (R=Mg, Ca, Sr, Ba) system were reacted in a ${SO_4}^{2-}$ ion-containing solution with various pHs ranging from 1 to 4 for various time the reacted glass surfaces were analyzed by XRD and SEM and all ions in the reacted solution were also measured ${SO_4}^{2-}$ ions in the solution were combined with divalent ions leached out of glass and precipitated on the glass surface as sulfate crystals. In this was the surface ion could be removed from the acidic solution. The sulfate ion removal capacity is closely related to the solubility product con-stants of the newly formed sulfate crystals. Almost no sulfate crystal was formed on the MgO-containing glass while sulfate crystals were easily formed on the glass containing either SrO or BaO This indicates that those glasses have strong removal efficiency of ${SO_4}^{2-}$ ions from the solution.

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Further Characterization of Protein Sulfotransferase(s) of Rat Brain by Alkaline Hydrolysis of Sulfated Proteins (황산화 단백질의 알칼리 가수분해에 의한 쥐 뇌의 단백질 황산기전달효소의 추가특성 연구)

  • 유재욱;최명언
    • The Korean Journal of Zoology
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    • v.33 no.4
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    • pp.468-475
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    • 1990
  • An In vitro protein sulfation in the soluble fraction of rat brain was charaderized further by an improved method of alkaline hydrolysis and thin layer ceflulose electrophoresis TLE) The protein sulfation was carried out in a reaction system containing [35 S] 3'-phosphoadenosine-5'-phosphosulfate (PAPS), Tris-maleate buffer (pH 8), MgCI$_2$, and soluble proteins from rat brain. The sulfated proteins were precipitated by acetone and alkaline hydrolysis was performed to obtain sulfated amino acids. The hydrolysate was separated further by TLE and the separated residues were identified by fluorography. The Iluorography of one-dimensional The showed at least nine sulfated residues including tryosine-O-sulfate. The other spots were not identified yet positively. General properties of protein sulfotransferases (PST) using this method were re-examined such as effects of concentrations of PAPS, pH, incubation temperature and $Mg^2$+. These results suggest a possible occurrence of several PST corresponding to each sulfated residue in rat brain and that the sulfation can occur not only in tyrosine but also in other residues as well.

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Effects of Consecutive Copper-Administration on Feed and Water Intake, Weight Gain, Blood Pictures and Mineral Level of Orgins in Rats (연속적인 Cu투여가 Rat의 사료와 물 섭취량, 증체량, 혈액치 및 장기내 무기물 수준에 미치는 영향)

  • 김상근;이명헌
    • Korean Journal of Animal Reproduction
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    • v.25 no.1
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    • pp.35-42
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    • 2001
  • This study was performed to elucidate the patho-physiology of copper-poisoned rats after consecutive oral administrations of the copper sulfate. The changes in feed and water intake, gains of body weight, blood pictures and mineral compositions of several organs were observed to measure the effects of copper poisoning. 1. Compared with control group, every experimental group of which 1,000, 2,000, or 4,000 ppm/kg of copper sulfate was administered displayed a gradual decrease in feed intake in dose-dependent manners. 2. After 1,000, 2,000 or 4,000 ppm/kg of copper sulfate administration, water intake seemed to decrease in every experimental group in dose-dependent manners, but there was little statistical significance. 3. After 1,000, 2,000 or 4,000 ppm/kg of copper sulfate administration, body weight decreased in every experimental group in dose-dependent manners. 4. After 1000, 2,000 or 4,000 ppm/kg of copper sulfate administration, the PLT values and numbers of RBC and WBC significantly increased after copper sulfate administration, but the values of Hb and PCV were lower than those of control group's. 5. After 2,000 or 4,000 ppm/kg of copper sulfate administration, the levels of Cu, Mn, Fe, Pb and Zn in the liver were lowered, but the levels of Mn, Fe, Pb and Zn in the kidneys increased except Cu levels.

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Study on Determination of Design Factor of Bioreactor for Sulfate Reduction in Mine Drainage (광산배수 내 황산염 저감을 위한 생물반응기의 설계인자 도출 연구)

  • Kim, Kang-Ho;Kang, Chan-Ung;Kim, Sun-Joon;Kim, Tae-Heok;Ji, Won-Hyun;Jang, Hang-Seok;Park, Hyun-Sung
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.527-537
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    • 2018
  • Column tests of a sulfate reducing bacteria (SRB) bioreactor were conducted to determine the design factors for sulfate-rich mine drainage. Various substrates were applied to the bioreactor, including cow manure and its mixture with a mushroom compost, with rice straw and limestone as subsidiary materials. This procedure provided a removal efficiency of up to 82% of the total sulfur with the mixture of cow manure (70%), mushroom compost (10%) and rice straw (20%), and higher efficiencies were observed after 2 days of retention time. In the downflow condition of the flow direction, oxygen supply and re-oxidation of the sulfates occurred, causing a decrease in sulfate removal efficiency. The addition of an inorganic sludge containing heavy metals, which was intended for production of metal-sulfides in the bioreactor, had a negative effect on the long-term operation owing to arsenic release and toxicity to the SRB. The results thus show that a bioreactor using a mixed substrate with cow manure and operating in the downflow direction could reduce sulfates and total dissolved sulfur content; this process confirms the applicability of the SRB bioreactor to sulfate-rich saline drainage.

Colour Difference and Colour Rastness of Dyed Silk Fabric with Serveral Kinds of Vegetable Dyes. (식물염료염색 견직물의 색채 및 견우도에 관하여)

  • Jeong, In-Mo;Lee, Yong-U;Song, Gi-Eon
    • Journal of Sericultural and Entomological Science
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    • v.28 no.2
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    • pp.61-64
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    • 1986
  • This study was carried out to identify Hue, Value and Chroma (H, V/C) of silk fabric dyed with several kinds of Vegetable Dyes according to Munsell renotation system and to disclose the colour fastness of dyed silk fabric against washing and light. The Hue of dyed silk fabric which was in colour of yellow or yellow red, was differentially altered by kinds of Vegetable Dyes, the Value and Chroma (V/C) of that was uniformally lowered by treatments of mordants after dyeing. The Colour fastness to washing and light of dyed silk fabric was improved by mordanting with coppor sulfate or ferrous sulfate, as compared with unmordanting.

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Sulfate Reduction of Rice Paddy, Foreshore, and Reservoir Soil (논과 갯벌과 저수지 토양의 황산염 환원)

  • Kim, Min-Jeong;Park, Kyeong-Ryang
    • Journal of Life Science
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    • v.20 no.10
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    • pp.1468-1475
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    • 2010
  • Sulfate reduction rates (SRR) using $^{35}SO_4^{-2}$, sulfide producing rates (SPR) using gas chromatography, the number of sulfate reducing bacteria (SRB) using the most probable number (MPN) method, and soil components (moisture, ammonium, total nitrogen, total organic carbon, total carbon, total inorganic phosphorus, total phosphorus, and sulfate) using standard methods in the organic/conventional rice paddy soils, cleaned/polluted reservoir soils, and cleaned/polluted foreshore soils were studied with the change of seasons. The average SRR was more related to the number of SRB and soil components (especially nitrogen and phosphorus) than sulfate concentration. SRR was also recorded to be highest in October soil samples. However, SPR was higher in foreshore soils containing a high concentration sulfate than in fresh water soils, and it was also recorded to be higher in the polluted areas than in clean areas. From these results, we can conclude that the SRR and SPR of anaerobic environments were affected by the number of SRB, soil components and temperature.

Effect of plasma resistance in Tartaric-sulphuric Acid on coating of Al 2024 alloy

  • Choe, Sin-Ho;Yun, Ju-Yeong;Lee, Chang-Hui;Sin, Jae-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.101.1-101.1
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    • 2015
  • 플라즈마에 의한 식각 공정중 챔버 내에서 발생한 오염입자가 기판위에 떨어져 제품의 불량을 일으키고 그에 따른 부품 교체비용이나 교체시 가동을 멈춰야하는 문제점들이 있다. 이러한 문제점을 해결하기 위해 내플라즈마성이 우수하다고 알려진 아노다이징 피막을 사용하고 있다. 하지만 다양한 아노다이징 공법중 어떠한 요인이 내플라즈마 특성과 관계되는지에 대한 보고는 부족한 실정이다. 기존의 아노다이징 특성평가방법으로는 내화학 특성과 열안정성 평가, 구조적 특성을 확인하는 것이 주로 사용되어 왔다. 따라서 본 연구에서는 기존 내화학 특성과 열안정성이 우수하다고 알려진 황산-주석산법을 이용한 피막의 특성을 평가하여 내화학특성, 열적 안정성, 구조적 특성이 내플라즈마 특성과 어떠한 관계가 있는지 확인했다.

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