• Title/Summary/Keyword: 내아크

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Numerical simulation of VOC decomposition in an arc plasma reactor (수치해석 기법을 이용한 아크 플라즈마 반응기의 VOCs 분해성능 평가연구)

  • Park, Mi-jeong;Jo, Young-min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.1-7
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    • 2016
  • A range of techniques have been being developed to remove the volatile organic compounds from paining processes. High temperature decomposition of harmful VOCs using arc plasma has recently been proposed, and this work analyzed the extreme hot process by computer-aided fluid dynamics prior to the reactor design. Numerical simulations utilized the conservation equations of mass and momentum. The simulation showed that the fluid flowed down along the inner surface of the centrifugal reactor by forming intensive spiral trajectories. Although the high temperature gas generated by plasma influences the bottom of the reactor, no heat transfer in radial direction appeared. The decomposition efficiency of a typical VOCs, toluene, was found to be a maximum of 67% across the reactor, which was similar to the value (approximately 70%) for the lab-scale test.

Selective Separation of Trypsin by Affinity Polymer and Ultrafiltration Membranes (친화성 고분자 및 한외여과 분리막을 이용한 트립신의 선택적 분리에 관한 연구)

  • Lee, Je-Gueon;Jeong, Yong-Seob;Hong, Suk-In
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.305-312
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    • 1994
  • The fed-batch process which combinded high selectivity of affinity chromatography and membrane process was developed. The mixture of trypsin and chymotrypsin, having almost the same molecular weight and the chemical structure, were used as model enzymes. The water soluble polymer having more affinity for trypsin and celluose acetate membrane gelated in 50vol.% ethanol for removing free enzymes and retentating trypsin-affinity polymer complex simutaneously were used in this system. The membrane pore size was controlled by ethanol concentration in the gellation bath, and the affinity polymer was prepared by polymerization of acrylamide with N-acryloyl-m-aminobenzamidine at $4^{\circ}C$. The trypsin could be effectively concentrated by utilizing an affinity polymer and a prepared UF-50 ultrafiltration membrane. As a result, 86% purity trypsin was recovered by the current purification process.

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Photoelectrochemical Characteristics at the Titanium Oxide Electrode with Light Intensity and pH of the Solution (산화 티타늄 전극의 광학농도와 pH에 따른 광전기화학적 특성)

  • Park, Seong-Yong;Cho, Byung-Won;Yun, Kyung-Suk
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.255-262
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    • 1994
  • Arc melted Ti-5Bi alloy was oxidized by thermal oxidation method. In the present study free energy efficiency(${\eta}_e$) of titanium oxide electrode(TOE) was measured as a function of light intensity and light energy. Flat-band potential of TOE was measured as a function of the light intensity and the solution pH. The ${\eta}_e$ of TOE increased with the increase of light intensity and tight energy to maximum value of 3.2% and 13%, respectively, at $0.2W/cm^2$ and 4.0eV. The ${\eta}_e$ was strongly dependent on the magnitude of the bias voltage. Maximum value was found at 0.5V bias. Photocurrent of TOE was controlled by electron-hole pair generation in depletion layer. The flat-band potential of the illuminated TOE shifted to -0.065V/decade with increasing light intensity. With the decrease of pH of electrolyte, flat-band potential shifted to anodic direction. The experimental slope was in good agreement with the Nernstian value of 0.059V/pH decade.

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Preparation of Permselective Membrane by Mean of a Radiation-Induced Grafting (방사선 그래프트에 의한 반투막 제조연구)

  • Young Kun Kong;Hoon Seun Chang;Chong Kwang Lee;Jae Ho Choi
    • Nuclear Engineering and Technology
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    • v.15 no.1
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    • pp.1-10
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    • 1983
  • By controlling both the means of grafting and the cast-solution components, no degradation and dimensional change of radiation-induced graft polymerization were found. The electric resistance of styrene-cellulose acetate grafts increases with increasing styrene content, while those for the hydrophilic monomers show no marked effect. In comparison with the grafted cellulose acetate membrane by simultaneous irradiation method, the appearance of the grafted membrane by post-polymerization method was not markedly changed irrespective of the percent of grafting and radiation dose of electron beam or ${\gamma}$-ray. The combination of crosslinking agents such as divinyl benzene (OB) or trimethyl propane triacrylate (TMPT) in the VP:St:BPO system leads to gradual increase of the percent of grafting. The activation energy for grafting of St:VP:BPO solution onto cellulose acetate membrane was determined to be about 21.8 Kcal/mole over the range of 55$^{\circ}$-8$0^{\circ}C$. The initial rate of grafting (in %/hr) is proportional to the power 0.76 for dose intensities.

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Separation Technology of Pure Zirconia from Zirconsand by the Ar-H2 Arc Plasma Fusion and Sulfuric Acid Leaching with Microwave Irradiation (Ar-H2플라즈마 건식제련과 마이크로웨이브침출을 통한 지르콘샌드로부터 고순도 지르코니아 분리)

  • Lee, Jeong-Han;Hong, Sung-Kil
    • Resources Recycling
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    • v.25 no.3
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    • pp.49-54
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    • 2016
  • In this study, zircon sand is separated into zirconia and silica by using the Ar-$H_2$ arc plasma refining. And then silica is removed from it by the microwave leaching method to produce a high pure zirconia. Plasma melting consist of two sequential processes; reduction process with Ar gas only followed by refining process with Ar-$H_2$ gas. After cooling in chamber. The solid phase obtained at $240^{\circ}C$ were found to be composed of 20% sulfuric acid solution. The solution was used as a leaching solution with microwave irradiation to obtain a high purity zirconia.

Extensional Vibration Analysis of Curved Beams Including Rotatory Inertia and Shear Deformation Using DQM (미분구적법(DQM)을 이용 회전관성 및 전단변형을 포함한 곡선 보의 신장 진동해석)

  • Kang, Ki-Jun;Park, Cha-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.5
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    • pp.284-293
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    • 2016
  • One of the most efficient procedures for the solution of partial differential equations is the method of differential quadrature. The differential quadrature method (DQM) has been applied to a large number of cases to overcome the difficulties of complex algorithms of computer programming, as well as the excessive use of storage due to the conditions of complex geometry and loading. The in-plane vibrations of curved beams with extensibility of the arch axis, including the effects of rotatory inertial and shear deformation, are analyzed by the DQM. The fundamental frequencies are calculated for members with various slenderness ratios, shearing flexibilities, boundary conditions, and opening angles. The results are compared with the numerical results obtained by other methods for cases in which they are available. The DQM gives good mathematical precision even when only a limited number of grid points is used, and new results according to diverse variations are also suggested.

The development of welding process to prevent porosity in high speed MIG Welding of Al 6082-T6 (Al 6082-T6 고속 MIG 용접에서 기공방지를 위한 용접공정 개발)

  • Jung, Yun-Ho;Park, Kyung-Do;Baek, Sang-Yeob;Oh, Dong-Soo;Sung, Young-Ki;Kim, Jeong-Pyo;Cho, Sang-Myung
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.8-8
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    • 2009
  • 알루미늄 합금 Al 6082-T6는 최근에 개발되어 북유럽 등의 선진국에서는 그 뛰어난 해양 내식성과 우수한 강도로 인하여 해양구조물의 헬리데크(Helideck), 타워 갱웨이(Tower gangway), 알루미늄 피팅류(Aluminium fitting)등의 해양구조물과 플랫폼(Flatform), 알루미늄 래더(Aluminium ladder)등의 선박부품, 차량, 기계부품 분야에서 전 세계적으로 널리 사용되기 시작하였다. 그러나 전통적으로 용접금속의 기공은 결함으로 분류 되고, Rakesh Kumar 등의 논문에 따르면 용접 시 용접금속 내에 발생되어진 미세기공이 기계적 성질에 악영향을 미치는 것으로 보고되어졌다. 따라서 용접금속내의 발생하는 기공을 방지하는 용접공정의 개발이 반드시 필요하다. 본 연구의 목적은 Al 6082-T6 고속 MIG용접에서 기공방지를 위한 용접공정을 개발하는 것이다. Al 6082-T6의 7t 플레이트에 Al 5356의 와이어를 사용하여 아크길이 변경 및 용접속도를 60cpm과 120cpm으로 변경하여 실험하였고, 용접속도 120cpm의 고속 MIG용접에서 토치 진행각을 변경하여 실험을 진행하였다. 용접공정 파라메터 변경에 따른 기공율 측정은 이미지 분석 소프트웨어를 사용하여 정량적으로 분석하였다.

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A Consideration on the Causes of 22.9kV Cable Terminal Burning Accident (22.9kV 케이블 단말 부위 소손 사고의 원인에 관한 고찰)

  • Shim, Hun
    • Journal of Internet of Things and Convergence
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    • v.8 no.2
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    • pp.7-12
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    • 2022
  • The main cause of cable accidents is the accelerated deterioration of the cable itself or internal and external electrical, mechanical, chemical, thermal, moisture intrusion, etc., which reduces insulation performance and causes insulation breakdown, leading to cable accidents. Insulation deterioration can occur even when there is no change in the appearance of the cable, so there is a difficulty in preventing cable accidents due to insulation deterioration. Since cable accidents can occur in areas with poor insulation due to the effects of overvoltage and overcurrent, it is necessary to comprehensively analyze transformers and circuit breakers, and ground faults caused by phase-to-phase imbalance. Ground fault accidents due to insulation breakdown of cables can occur due to defects in the cable itself and poor cable construction, as well as operational influences, arcs during operation of electrical equipment (switchers, circuit breakers, etc.). analysis is needed. This study intends to examine the causes of cable accidents through analysis of cable accidents that occurred in a manufacturing factory.

A Case Study on Explosive Demolition of Turbine Building of Steel Frame Structure (터빈동 철골구조물 발파해체 시공사례)

  • Hoon, Park;Sung-Woo, Nam;You-Song, Noh;Chul-Gi, Suk
    • Explosives and Blasting
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    • v.40 no.4
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    • pp.35-46
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    • 2022
  • While the construction of dismantling the old industrial complex and restoring the dismantled industrial site to its original natural environment the is underway. In this paper, we introduce a case of dismantling a turbine building which one of the a large steel frame structures in an old industrial complex by applying the progressive collapse method among the blasting demolition methods. We used a charge container that generates a metal jet to cut dismantling the turbine building. The thickness of the steel structure was adjusted to 30 mm or less by applying gouging, which was a method of digging deep grooves by gas and oxygen flames or arc thermal, in the part where the cutting thickness was thick in the blasting section. The total amount of charge used for the blasting of turbine building was 175 kg, 165 electronic detonators and 124 charge containers. As a result of the blasting demolition, the turbine building was collapsed precisely according to the estimated direction. The blasting demolition was completed without causing any damage to the surrounding facilities.

A Study on the Comparison of Chloride Ion Quantification Methods for Magnesium-Aluminum (Mg-Al) Alloy Powder (마그네슘-알루미늄(Mg-Al) 합금 분말의 염소이온 정량법의 비교에 관한 연구)

  • Yunhwan, Kim;Youngson Choe
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.450-454
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    • 2023
  • Chloride ions in the alloy powder used as flux in Flux Cored Arc Welding (FCAW) can cause pores on the bead surface of the welding metal to cause defects, or chloride remaining in the alloy powder can cause corrosion of the metal. Combustion-ion chromatography is mainly used to quantify the chloride ions in alloy powder, but there is a limitation in that the equipment is expensive and requires a high degree of expertise. Therefore, this study aims to find an easy and accurate quantification method in the field by comparing combustion-ion chromatography (C-IC), which is mainly used for chloride ion quantification of alloy powder, X-ray fluorescence analysis (XRF), and potentiometric titration. In this article, magnesium-aluminum alloy powder is applied to the quantification of chloride ions because it is most commonly used as flux. This study confirmed that potentiometric titration can be applied to the quantification of chloride ions in the alloy powder in the industry field.