• 제목/요약/키워드: 내부결합

검색결과 890건 처리시간 0.029초

A Study on the Blue Fluorescence Characteristics of Silica Nanoparticles with Different Particle Size (실리카 나노 입자의 크기에 따른 청색 형광 특성 연구)

  • Yoon, Ji-Hui;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제20권5호
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    • pp.1-6
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    • 2019
  • Organic dye-doped silica nanoparticles are used as a promising nanomaterials for bio-labeling, bio-imaging and bio-sensing. Fluorescent silica nanoparticles(NPs) have been synthesized by the modified $St{\ddot{o}}ber$ method. In this study, dye-free fluorescent silica NPs of various sized were synthesized by Sol-Gel process as the modified $St{\ddot{o}}ber$ method. The functional material of APTES((3-aminopropyl)triethoxysilane) was added as an additive during the Sol-Gel process. The as-synthesized silica NPs were calcined at $400^{\circ}C$ for 2 hours. The surface morphology and particle size of the as-synthesized silica NPs were characterized by field-emission scanning electron microscopy. The fluorescent characteristics of the as-synthesized silica NPs was confirmed by UV lamp irradiation of 365 nm wavelength. The photoluminescence (PL) of the as-synthesized silica NPs with different size was analyzed by fluorometry. As the results, the as-synthesized silica NPs exhibits same blue fluorescent characteristics for different NPs size. Especially, as increased of the silica NPs size, the intensity of PL was decreased. The blue fluorescence of dye-free silica NPs was attributed to linkage of $NH_2$ groups of the APTES layer and oxygen-related defects in the silica matrix skeleton.

Geotechnical Characteristics of Reduced Slag-soil Mixtures in Electric Furnace (전기로 제강 환원 슬래그 혼합토의 지반공학적 특성)

  • Shin, Jaewon;Yoon, Yeowon;Yoon, Gillim
    • Journal of the Korean GEO-environmental Society
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    • 제12권7호
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    • pp.31-37
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    • 2011
  • Only a few studies have been conducted using reduced slag as recycled material. The reduced slag in electric furnace is produced as a by-product in making a steel and a few applications of the reduced slag as expensive additives and bonding materials or as the stabilized soils was reported. The purpose of this study is to present the feasibility of the reduced slag as recycled material, especially, in a field of civil engineering. In order to achieve the purpose experiments such as SEM and XRF analysis was conducted for the reduced slag in electric furnace. Based on the results various geotechnical experiments were conducted to know engineering properties of slag-soil mixtures. Weathered soils and clay are mixed with reduced slag for various ratios. As the ratio of reduced slag to weathered soil increases, the maximum dry unit weight of the mixture decreased with increasing optimum moisture content. The results indicates that there is no effect on a reduced slag by compaction efforts. The shear strengths of the weathered soil-slag mixtures are slightly higher or similar to those of weathered soils. The permeability of the weathered soil-slag mixtures is similar to that of silty or sandy soils. Therefore, it is possible to use the mixtures as embankment or backfill materials in the fields. The unconfined strength of the mixtures of reduced slag and clay is higher than that of clay and it tends to increase with the curing time. Therefore it can be used to improve the soft ground.

Experimental Study of Transition to Secondary Acoustic Instability at Downward-Propagating Premixed Flame in a Tube (튜브 내 하향 전파하는 예혼합 화염의 이차 열음향 불안정성 천이에 관한 실험적 연구)

  • Park, Juwon;Kim, Daehae;Park, Dae Geun;Yoon, Sung Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • 제26권7호
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    • pp.915-921
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    • 2020
  • Thermoacoustic instability caused by air conditioning in a combustion chamber has emerged as a problem that must be solved to establish a stable combustion system. Thermoacoustic instability is largely divided into primary and secondary acoustic instability. In this study, an experimental study of the effects of heat losses was conducted to investigate the mechanism of secondary acoustic instability. To generate the secondary acoustic instability, a quarter-wavelength resonator with one open end and one closed end was used, and the inside of the resonator was filled with premixed gases. Subsequently, secondary acoustic instability with downward-propagating flames could be realized via thermal expansion on the burnt side. To control heat losses qualitatively, an additional co-axial tube was installed in the resonator with air or nitrogen supply. Therefore, additional diffusion flames can be formed at the top of the resonator depending on the injection of the oxidizer into the co-axial tube when rich premixed flames are used. Consequently, secondary acoustic instability could not be achieved by increasing heat losses to the ambient when the additional diffusion flame was not formed, and the opposite result was obtained with the additional diffusion flame.

Evaluation of Woodchip and Synthetic Fiber as Biofilter Media for the Treatment of Livestock Stormwater (가축사육단지 강우유출수 처리목적 바이오 필터 여재로서 우드칩과 합성섬유의 평가)

  • Cheng, Jing;Guerra, Heidi B.;Kim, Youngchul
    • Journal of Wetlands Research
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    • 제23권1호
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    • pp.94-105
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    • 2021
  • Two vertical flow biofilters in series (BFS) employing synthetic fiber (FBF) followed by woodchip (WBF) was investigated in order to assess its potential as an alternative to the typical vertical-horizontal flow configuration in removing nonpoint source pollutants specifically nutrients and organics. These lab-scale column biofilters were operated for 176 days alongside three other columns that were added for control and sampling purposes. The biofilter columns were fed with either a semi-artificial piggery stormwater or artificial stormwater with specific ammonia and nitrate contents. Results reveal that the BFS was more effective than a single biofilter in removing pollutants especially nitrogen. FBF was found to remove up to 100% of ammonia from the stormwater with corresponding increase in nitrate in the outflow which shows evidence of active nitrification. Meanwhile, the succeeding vertical WBF was able to subsequently remove 77% of the nitrate. The effective reduction of nitrate in a vertical flow biofilter was believed to be due to the use of woodchip which can provide a carbon source that is required for denitrification. However, further investigation is needed to support this claim. Nonetheless, the study shows the potential of vertical flow BFS as a nitrogen removal mechanism especially in areas where enough land space for horizontal flow biofilters is limited.

Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제10권2호
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.

The Effect of Recycled Aggregate Produced by the New Crushing Device with Multi-Turn Wings and Guide Plate on the Mechanical Properties and Carbonation Resistance of Concrete (다중 회전 날개 및 가이드 판 설치 파쇄장치를 통해 제작된 순환골재가 콘크리트의 역학적 특성 및 탄산화 저항성에 미치는 영향)

  • Cho, Sung-Kwang;Kim, Gyu-Yong;Eu, Ha-Min;Kim, Yong-Rae;Lee, Chul-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제9권2호
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    • pp.135-142
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    • 2021
  • In this work, multi-turn wings and guide plates are installed on recycled aggregate crushing devices to improve existing low recycled aggregate quality. Simulation analysis to evaluate the crushing efficiency of the new device shows enhanced crushing efficiency since the installation of guide plates shreds most of the inputs inside the crushing drum, and the multi-turn wings and guide plates induce rebound and circulation of the aggregate. Through this, the new device was found to be more economical and efficient than the existing recycled aggregate crushing device. Also, the amount of cement paste and mortar attached to the surface of the aggregate was smaller than that of the existing recycled aggregate, and it was found that the mechanical properties and elastic modulus deterioration were reduced. However, the carbonation resistance of concrete was not improved to the level of natural aggregates due to the remaining tiny cement paste and mortar on the surface of the new recycled aggregate. Therefore, it is deemed necessary to further research and experiment such as device improvement or binder development to reduce durability degradation of concrete mixed with new recycled aggregate.

Instrumentation Management of the Deep Soft Ground with Dredged Clay Reclaimed in the Upper (준설점토가 상부에 매립된 대심도 연약지반 계측관리)

  • Jung, Na-Young;Kang, Seung-Chan;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • 제38권12호
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    • pp.67-78
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    • 2022
  • In this study, the measurement results of the coastal deep soft ground buried in the upper part of the dredged clay were analyzed and compared with the current specification standards. Based on the results, a suitable proposal was suggested for the selection, installation, data arrangement, and analysis of each instrument used in the deep soft ground improvement construction. The pore water pressure meter has a range of 1.5 times or more of the expected measurement range, considering the field conditions of the soft ground. The groundwater level meter installed in the horizontal drainage layer checks the change in the groundwater level during the embanking as well as the performance of the catchment well and the horizontal drainage layer. Therefore, it is important to manage so that the groundwater level exists inside the horizontal drainage layer during embanking. It is enough to install the inclinometer in the gravel layer below the soft ground or weathered rock with an N value of 40 or more for the deep soft ground. It seems desirable to install a screw type for differential settlement meter. However, the screw type should not settle due to its own weight. Considering that it is a dredged landfill where subsidence occurs significantly, it is sufficient to manage the tolerance of leveling at about 10 mm (L is the one-way distance (km)).

Application of Natural Dyes for Developing Colored Wood Furniture (I) - Color Variation by Extraction Methods of Natural Dyes - (색채 목가구재 개발을 위한 천연염료의 이용에 관한 연구 (제1보) - 천연염료의 추출 방법에 따른 색채 변화 연구 -)

  • Moon, Sun-Ok;Kim, Chul-Hwan;Kim, Jae-Ok;Kim, Jong-Gab
    • Journal of the Korean Wood Science and Technology
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    • 제32권5호
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    • pp.75-85
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    • 2004
  • The natural dyes from Gardenia jasminoides, Carthamus tinctorius L., Rhus javanica, Lithospermum erythrorhizon, Caesalpinia sappan L., and Castanea crenata were extracted under different pH in distilled water, As the pH in distilled water went from acid to alkali, the much deeper colors in the same color tone were generated from the individual plant species. Before dyeing, wood species were treated by different mordants including AI, Cu, Cr and Fe for color-fixing between wood and the natural dyes. Each mordant could develop independent color on the surface of the woods. The wood species dyed by the natural dyes created deep-tone colors according to higher pH and temperature of the dyeing solution, leading to deeper penetration of the dyes into the wood tissues. Finally through the computer modelling of natural-dyed wood furniture, it was confirmed that the colored furniture can adequately be compatible with the current interior spaces of diverse colors.

Crisis of trust of journalism in France: Cracks in journalistic institutions and professionalism, and the impact of social movement (프랑스 언론의 신뢰도 위기: 저널리즘 제도의 내적 균열과 사회운동의 영향)

  • Park, Jin woo;Kim, Soel ah
    • Analyses & Alternatives
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    • 제6권2호
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    • pp.185-226
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    • 2022
  • This study examines the crisis of trust of French journalism in the context of a global decline of media credibility. First of all, in the process of a huge social movement called the 'yellow vest' movement that started in 2018, distrust of the French journalism was expressed in an extreme form. This study examines some external factors in terms of the historical development of the French journalism and the public's long-standing 'criticism of journalism'. Specifically, this study first examines the quantitative indicators of trust of French journalism which were shown in Digital News Report published by the Reuters Institute for the Study of Journalism. Next, it examines the historical and institutional formation process of French journalism and public distrust that emerged along with it. And specifically, the structural crisis-economic crisis, digital transformation and intensification of competition, and deterioration of quality problems etc.-of the French journalism exposed in media coverage on social movement in 2018 is review in relation with the working process or 'routine' of actual news production. In conclusion, this study asserts that the various aspects of internal rifts in French journalism system, as well as external shocks (the influence of social movements), are a key factor in explaining the recent decline of trust in French journalism.

Reviews on Post-synthetic Modification of Metal-Organic Frameworks Membranes (다결정 금속 유기 골격체 분리막의 후처리 성능 제어기술 개발 동향)

  • Hyuk Taek, Kwon;Kiwon, Eum
    • Membrane Journal
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    • 제32권6호
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    • pp.367-382
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    • 2022
  • Numerous metal-organic frameworks (MOFs) produced by periodic combinations of organic ligands and metal ions or metal-oxo clusters have led the way for the creation of energy-efficient membrane-based separations that may serve as viable replacements for traditional thermal counterparts. Although tremendous progress has been made over the past decade in the synthesis of polycrystalline MOF membranes, only a small number of MOFs have been exploited in the relevant research. Intercrystalline defects, or nonselective diffusion routes in polycrystalline membranes, are likely the reason behind the delay. Postsynthetic modifications (PSMs) are newly emerging strategies for providing polycrystalline MOF membrane diversity by leveraging advanced membranes as a platform and improving their separation capabilities via physical and/or chemical treatments; therefore, neither designing and developing MOFs nor tailoring membrane synthesis techniques for focused MOFs is necessary. In this minireview, seven subclasses of PSM techniques that have recently been adapted to polycrystalline MOF membranes are outlined, along with obstacles and future directions.