• Proceedings of the Korean Fiber Society Conference
• /
• 2001.10a
• /
• pp.334-337
• /
• 2001

오늘날 건설, 교통, 섬유 등의 일상 생활에서부터 최첨단 분야인 항공 및 IT 까지 난연성을 요구하는 분야가 점차 확대되고 있어, 그에 대한 연구가 활발히 이루어지고 있다. 지금까지 가장 효율적인 고분자 재료의 난연제로써 할로겐화 화합물을 사용해 왔지만, 이러한 할로겐화 화합물은 우수한 난연 효과에 비해 심각한 단점들을 많이 가지고 있다. (중략)

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2008.04a
• /
• pp.108-110
• /
• 2008

본 연구에서는 균일한 난연성능을 지닌 산업용 난연시트 제조 기술 개발을 목적으로, 제조공정 제어와 함께 친환경 난연제를 개발하였다. 기존 난연시트 제조과정에 산발적으로 나타나는 낮은 방염성능이 기모공정에 원인이 있음을 알고 기모촉진제 및 기모에 의한 물리적 화학적 결합력의 변화에 대하여 조사하였다. 그 결과 기모촉진제화 난연제간 혼화성은 문제가 없지만 기모촉진제 처리 후 시료표면의 소수성과 기모에 의한 물리적 구조의 변화가 난연제의 흡착을 방해함을 알 수 있었다. 따라서 기모공정과 난연공정 사이에 수세공정 첨가의 영향, 난연공정 온도변화의 영향, 그리고 염색과 동욕에서 난연제를 처리하는 방법으로 제조공정을 변화하여 균일한 난연성능 구현의 가능성을 조사하였다.

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.6
• /
• pp.792-797
• /
• 2015

In this study, three softwood species were treated with water-soluble melamine resin by different concentration and treatment time under vacuum pressure for improving mechanical property, abrasion resistance, and incombustibility. After the treatment, a compreg was manufactured and then evaluated on physical properties. Additionally, incombustibility of compreg was determined by comparing with a wood that was treated by spraying a water-soluble fire retardant on surface. As concentration of resin increased, bending strength and Brinell hardness increased as well as abrasion resistance, but there was no correlation on treatment and mechanical properties by treatment time. The wood impregnated by water-soluble melamine resin under vacuum pressure showed better incombustibility than that of a water-soluble fire retardant sprayed wood. Therefore, this treatment could be used for improving incombustibility of wood.

• Fire Science and Engineering
• /
• v.33 no.3
• /
• pp.29-36
• /
• 2019

The combustion properties required for fire simulations of multi-layer, multi-component flame retardant cables were measured using a cone calorimeter. The CO and soot yields combustion efficiencies of the flame retardant cables were investigated. TFR-8 (flame retardant PCV and XLPE added), TFR-CVV-SB (flame retardant PCV and general PVC), and VCTF, which are excellent in the flame retardancy of cables, were considered. As the main result, the CO yield (y_CO) of the TFR-8 and TFR-CVV-SB flame retardant cables increased by 23% and 16%, respectively, with increasing incident radiation heat flux from 25 kW/㎡ to 50 kW/㎡. On the other hand, the CO yield of VCTF was not influenced significantly by the changes in radiant heat flux. Finally, the soot yield and combustion efficiency increased as the sheath material (flame retardant performance) was strengthened. Therefore, in a fire environment where various heat fluxes coexist, attention should be paid to the top of the application of the combustion property of the flame retardant cable.

• Journal of the Korea Institute of Building Construction
• /
• v.21 no.2
• /
• pp.113-119
• /
• 2021

Polymers are widely applied to construction materials due to their lightweight and excellent mechanical properties. However, owing to the combustible properties, polymers are one of the biggest reason of spreading large fires in fire accidents that occur frequently in the construction industry. Therefore, as a solution to this problem, many research has been conducted to impart flame retardancy by incorporating flame retardants to polymer matrix. Among these flame retardants, organic phosphorus-containing flame retardants have been attracting much attention because they have excellent compatibility with polymer matrix and low toxicity compared with halogen or inorganic-containing flame retardants. Accordingly, this study aims to design and synthesize an alkoxyamine-based organic phosphorus flame retardant to improve flame retardancy of polylactide which is an eco-friendly polymer used for construction materials.

• Fiber Technology and Industry
• /
• v.11 no.2 s.42
• /
• pp.59-68
• /
• 2007

• Proceedings of the Korean Institute of Industrial Safety Conference
• /
• 2000.11a
• /
• pp.113-117
• /
• 2000

경량 건축소재는 건축자재의 경량화, 고급화 및 다양화 등의 기능성 건축소재로의 역할을 요구하고 있으며 그 중 대표적인 것으로는 polyurethane foam이 있다 일반적인 플라스틱 foam의 경량 건축소재는 난연성에 대한 문제점과 첨가제에 의한 중량 증가, 화재 발생시 과다연기발생 등의 문제점이 있으며 저밀도 콘크리트 등의 무기소재는 flexibility가 떨어져 충격과 휨강도가 매우 낮은 단점을 가지고 있다.(중략)

• Proceedings of the Korean Institute of Industrial Safety Conference
• /
• 1998.11a
• /
• pp.329-334
• /
• 1998

난연성을 지닌 고분자 물질중 Chlorosulfonated Polyethylene(CSPE; Hypalon)은 Polyethylene에 염소와 황을 첨가한 것으로 염소를 첨가함으로써 기름과 화염에 대한 저항성을 향상시키고, 황 또한 기름, 화염에 대한 저항을 향상시킬 뿐 아니라 인장강도를 크게 해서 기계적 강도를 향상시킨 것이다. CSPE는 염소량의 등급에 따라 Coating재료, 호스 구조재, Wire와 Cable의 피복재료등 여러 가지 용도로 많이 쓰이고 있으며 특히 염소함량이 35%인 CSPE(Hypalon-40)의 경우 열저항과 압출 특성이 우수하기 때문에 Cable의 피복재료로 많이 쓰이고 있다.

• Polymer(Korea)
• /
• v.31 no.4
• /
• pp.273-277
• /
• 2007

Cyclophosphazene derivatives were synthesized in order to use as a non-halogen flame retardant for ABS. Chlorocyclophosphazene was reacted with phenol, catechol, aniline, 1,2-diaminobenzene respectively, and each product was characterized by UL94 and LOI test for ABS resin. The physical properties of the sample containing these flame retardants were also characterized. The derivative synthesized from catechol showed best flame retardancy, and the derivative from phenol exhibited the flame retardancy in which the synergic effect was shown with novolac.

• Fire Science and Engineering
• /
• v.20 no.4 s.64
• /
• pp.110-115
• /
• 2006

Polyurethane(PU) was mixtured by the treatment with flame retardants such as Tri(chloroisopropyl) phosphate(TCPP), Triethyl phosphate(TEP) and Trimethyl phosphate(TMP) at about $90^{\circ}C$. Rigid polyurethane foam was produced using the mixured products as flame retardants. The mechanical property and flammability of rigid polyurethane was investigated. The mixtured polyurethane shows reduced flammability over virgin polyurethane. Mechanical strength of mixtured polyurethane also shows as high as that of virgin polyurethane. In order to evaluate flame retardant properties of the mixtured polyurethane foams, heat release rate(HRR) of the foam was measured by cone calorimeter. Scanning electron micrograph of mixtured PU shows uniform cell morphology as virgin PU.