• Title/Summary/Keyword: 나노 재료

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Formation of (TEACOOH)-Montmorillonite Intercalations Complex and Polycondensation between the Layers of the Complex ((TEACOOH)-Montmorillonite 층간화합물의 형성 및 층 내에서의 고분자화 반응)

  • Yun, Do-U;Jo, Seong-Jun
    • The Journal of Engineering Research
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    • v.7 no.1
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    • pp.79-87
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    • 2005
  • [TEACOOH]-Montmorillonite intercalations complex obtained from Na-Montmorillonite and 10-Carboxy-n-decyldimethylethylammonium bromide(organic cation) was reacted with the monomer($\varepsilon$-caprolactone) to achieve the [TEACOOH]-$\varepsilon$-caprolactone-Montmorillonite intercalations complex. From intercalations complex Montmorillonite/Polycaprolactone Nanocomposite in which montmorillonite(inorganic material) is chemically linked with the polycaprolactone(organic polymer) was formed at $220^{\circ}C$ for 48 h. The basal spacing for the sample obtained after polymerization, extraction with methanol and dried at $65^{\circ}C$ in high vacuum for 24 h was 50.7 $\AA$.

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DEVELOPMENT OF ANTICARIOGENIC COMPOSITE RESIN (항우식성 복합레진의 가능성)

  • Park, Jeong-Won
    • Restorative Dentistry and Endodontics
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    • v.35 no.2
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    • pp.65-68
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    • 2010
  • Due to the improvement of the composite resin and esthetic desire of the patient, amalgam restoration has been replaced by composite resin. However, still there are many unsolved problems, for example, technique sensitivity, polymerization shrinkage stress and limited mechanical properties. These factors results in fracture of the restoration and secondary caries of the tooth. Also the use of the dental bonding system should be used for the retention of the restoration. In this paper, I want to talk about the present and the future of the remineralizing component released from dental composite resin to overcome the secondary caries and there possibility in the clinical use.

Single Walled Carbon Nanotubes-Reinforced Metal Matrix Composite Materials Fabricated by Spark Plasma Sintering (방전플라즈마 소결공정으로 제조된 단일벽탄소나노튜브 강화 금속기지 복합재료)

  • Kwon, Hansang
    • Journal of Power System Engineering
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    • v.21 no.4
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    • pp.94-99
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    • 2017
  • Single walled carbon nanotubes were mixed with various metal powders by mechanical ball milling and sintered by spark plasma sintering processes. Two compositional (0.1 and 1 vol%) of the single walled carbon nanotubes were dispersed onto the pure aluminum, 5052 aluminum alloy, pure titanium, Ti6Al4Vanadium alloy, pure copper, and stainless steel 316L. Each composite powders were spark plasma sintered at $600^{\circ}C$ and well synthesized regardless of the matrices. Vickers hardness of the composite materials was measured and they exhibited higher values regardless of the carbon nanotubes composition than those of the pure materials. Moreover, single walled carbon nanotubes reinforced copper matrix composites showed highest enhancement between the other metal matrices system. We believe that low energy mechanical ball milling and spark plasma sintering processes are useful tool for fabricating of the carbon nanotubes-reinforced various metal matrices composite materials. The single walled carbon nanotubes-reinforced various metal matrices composite materials could be used as an engineering parts in many kind of industrial fields such as aviation, transportation and electro technologies etc. However, detail strengthening mechanism should be carefully investigated.

Ge-Sb-Te 삼성 분계에서의 열처리 온도에 따른 구성 원소의 상호확산 특성

  • Bang, Gi-Su;Lee, Seung-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.218.1-218.1
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    • 2013
  • GeSbTe 삼원계 칼코겐화물 합금은 광디스크 및 상변화 메모리에서 활성물질로 사용되는 대표적인 재료이다. GeSbTe 합금은 결정질 상과 비정질 상의 두 종류의 상을 갖는데 그 상에 따라 반사율 및 전기저항이 서로 다르기 때문에 활성물질로서 작용한다. GeSbTe 합금 구성원소의 일부를 포함하는 두 종류의 물질로 접합을 형성하고 열처리 공정을 수행함으로써 GeSbTe 합금을 국부적으로 생성하는 방법이 최근에 보고되었다. 이러한 방법을 상변화 메모리 소자 제조에 이용하면 GeSbTe 합금을 제한된 영역에 나노 스케일로 만드는 것이 가능해져서 GeSbTe 합금의 상변화를 유도하는데 필요한 프로그래밍 전류를 낮추는 효과를 얻을 수 있다. 상변화 메모리 소자 내에서의 GeSbTe 합금의 두께 또는 크기는 상변화 메모리 소자의 동작 특성을 좌우하는 중요한 파라미터이며 이것은 열처리 공정 조건에 따라 결정되므로 열처리 공정 조건에 따라 GeSbTe 합금이 생성되는 양상이 어떻게 변화하는지를 밝힐 필요가 있다. 따라서 본 연구에서는 다양한 열처리 온도 조건에서 Ge-Sb-Te 삼성 분계에서의 구성 원소들의 상호확산 거동을 조사하였다. 순수한 Ge 박막과 조성이 다른 SbTe 박막의 접합을 형성하고 773K까지의 온도 범위에서 열처리를 실시하였다. Auger 수직 분석을 이용하여 Ge, Sb, 및 Te 원소의 깊이 방향의 확산 정도를 조사하였으며 그 결과로서 열처리 온도가 증가함에 따라 상호확산 정도가 심해지고 Te 원소가 상호확산에 있어서 중요한 역할을 한다는 사실을 확인하였다.

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A Study on Electromagnetic Interference Shielding Effectiveness of the Metal Powders and Nano Carbon black /Fiber Reinforced Epoxy composites (메탈 파우더와 나노 카본 블랙/섬유강화 복합재료의 전자파 차폐효과에 관한 연구)

  • Han Gil-Young;Kim Jin-Seok;Ahn Dong-Gyu
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.8 s.185
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    • pp.100-107
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    • 2006
  • The objective of this research is to investigate the electromagnetic interference(EMI) shielding characteristics of fiber reinforced composites. We fabricated glass and carbon fiber reinforced composites filled with metal powder and nano carbon black. The measurements of shielding effectiveness(SE) were carried out frequency range 300MHz - 1GHz for commercial purposes such as electric or telecommunication devices. The return loss and loss due to absorption were also measured as a function of frequency in the micro wave(300MHz-1GHz) region. It is observed that the SE of the composites is the frequency dependent, increase with the increases in filler loading. The Mg metal powder filled composite showed higher SE compared to that of carbon black. The Mg metal powder/epoxy composite was shown to exhibit up to 40dB of SE. The results indicates that the composite having higher filler loading can be used for the purpose of EMI shielding as well as for some microwave applications.

A Study of Mechanical Interfacial Properties of Carbon Nanotube on Carbon Fiber/Epoxy Resin Composites (탄소나노튜브로 표면처리 된 탄소섬유/에폭시 수지 복합재료의 기계적 특성 연구)

  • Hong, Eunmi;Lee, Kyuhwan;Kim, Yangdo;Lim, Dongchan
    • Journal of the Korean institute of surface engineering
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    • v.46 no.5
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    • pp.223-228
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    • 2013
  • In this work, the grow of carbon nanotube (CNT) on carbon fiber was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM) and mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS). From the results, it was found that the mechanical interfacial properties of CNT-carbon fibers-reinforced composites (CNT-CFRPs) enhanced with decreasing the CNT content. The excessive CNT content can lead the failure due to the interfacial separation between fibers and matrices in this system. In conclusion, the optimum CNT content on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the CNT-CFRPs.

High-temperature corrosion properties of Al2O3 + (Fe2O3, Al, Cr and Si) mixed sintering materials (Al2O3 + (Fe2O3, Al, Cr and Si) 소결 복합재료의 고온 부식 특성)

  • Kim, Min-Jeong;Won, Seong-Bin;Bong, Seong-Jun;Lee, Dong-Bok;Son, In-Jin
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.170-171
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    • 2012
  • $Fe_2O_3$, Al, Cr과 Si 분말을 고 에너지 볼 밀링해서 나노분말을 제조한 후 고주파유도 가열 활성 연소합성 장치로 1분 이내의 짧은 시간에 합성 및 소결한 $Al_2O_3+4.65(Fe_{0.43}Cr_{0.17}Al_{0.323}Si_{0.077})$, $Al_2O_3$ + 5.33 ($Fe_{0.375}Cr_{0.11}Al_{0.3}Si_{0.075}$), $Al_2O_3$ + 6.15 ($Fe_{0.325}Cr_{0.155}Al_{0.448}Si_{0.072}$), $Al_2O_3$ + 3.3 ($Fe_{0.6}Cr_{0.3}Al_{0.6}$) 소결체 시편을 $700^{\circ}C$의 온도에서 100시간 동안 공기 중에서 산화 및 $N_2-H_20-H_2S$ 혼합 가스 내에서 황화 부식을 실시하였다. 그 결과 산화 및 황화 부식 후에 ${\alpha}-Al_2O_3$가 표면에 생성되어 보호 피막으로 작용하여 우수한 내식성을 보였다.

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Technology Trend of Spin-Transfer-Torque Magnetoresistive Random Access Memory (STT-MRAM) (스핀전달토크형 자기저항메모리(STT-MRAM) 기술개발 동향)

  • Kim, D.K.;Cho, J.U.;Noh, S.J.;Kim, Y.K.
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.22-27
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    • 2009
  • Reduction of the critical current density ($J_c$) for STT magnetization switching is most important issue of magnetic tunnel junctions (MTJs) based MRAM. This report describes how to decrease the Jc and will introduce the recent research progresses of STT-MRAM devices with material engineering and structural improvement, respectively.

Fuel Cell Research Trend Analysis for Major Countries by Keyword-Network Analysis (키워드 네트워크 분석을 통한 주요국 연료전지 분야 연구동향 분석)

  • SON, BUMSUK;HWANG, HANSU;OH, SANGJIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.2
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    • pp.130-141
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    • 2022
  • Due to continuous climate change, greenhouse gases in the atmosphere are gradually accumulating, and various extreme weather events occurring all over the world are a serious threat to human sustainability. Countries around the world are making efforts to convert energy sources from traditional fossil fuels to renewable energy. Hydrogen energy is a clean energy source that exists infinitely on Earth, and can be used in most areas that require energy, such as power generation, transportation, commerce, and household sectors. A fuel cell, a device that produces electric and thermal energy by using hydrogen energy, is a key field to respond to climate change, and major countries around the world are spurring the development of core fuel cell technology. In this paper, research trends in China, the United States, Germany, Japan, and Korea, which have the highest number of papers related to fuel cells, are analyzed through keyword network analysis.

Developing Trend of Gas Separation Membrane for Dehumidification (제습용 기체분리막 개발동향)

  • Koh, Hyungchul;Lee, Choongsup;Ha, Seong Yong;Choi, Whee Moon;Rhim, Jiwon;Nam, Sangyong
    • Prospectives of Industrial Chemistry
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    • v.14 no.3
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    • pp.25-36
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    • 2011
  • 압축공기 중의 수분은 공압설비의 모든 요소에 중대한 해를 입히며 밸브의 고착, 계기의 막힘 또는 공압기기의 오작동을 일으키며 생산하는 제품의 질에 있어서도 많은 해를 입혀서 제품의 질을 떨어뜨리는 역할을 하게 된다. 따라서 수분을 제거하는 방법이 필요하며 기존의 냉동식 및 흡착식을 대신하여 분리막 법이 적용될 수 있다. 현재 제습용 기체분리막 모듈은 적용이 시작된 단계에 있다. 제습용 기체분리막은 의료기기, 분석기기, Instrument air 장비에 응용이 진행되고 있다. 최근 들어 선진각국 뿐만 아니라 국내에서도 막소재 개발, 복합막 개발, 모듈 개발, 시스템 설계 및 제작 기술 개발이 진행되고 있다. 현재로서는 제습막공정에 적합한 막소재의 개발이 시급하지만 이후 적용확대를 위해서는 제습용 기체분리막의 신뢰성 향상을 위한 다각도의 노력이 필요하다.