• Title/Summary/Keyword: 나노코팅

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Partially Dry-Transferred Graphene Electrode with Zinc Oxide Nanopowder and Its Application on Organic Solar Cells (ZnO 나노 분말 코팅 기반 건식전사 그래핀 전극 제작 및 유기태양전지 응용)

  • Jo, Yeongsu;Woo, Chae Young;Hong, Soon Kyu;Lee, Hyung Woo
    • Journal of Powder Materials
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    • v.27 no.4
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    • pp.305-310
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    • 2020
  • In this study, partially dry transfer is investigated to solve the problem of fully dry transfer. Partially dry transfer is a method in which multiple layers of graphene are dry-transferred over a wet-transferred graphene layer. At a wavelength of 550 nm, the transmittance of the partially dry-transferred graphene is seen to be about 3% higher for each layer than that of the fully dry-transferred graphene. Furthermore, the sheet resistance of the partially dry-transferred graphene is relatively lower than that of the fully dry-transferred graphene, with the minimum sheet resistance being 179 Ω/sq. In addition, the fully dry-transferred graphene is easily damaged during the solution process, so that the performance of the organic photovoltaics (OPV) does not occur. In contrast, the best efficiency achievable for OPV using the partially dry-transferred graphene is 2.37% for 4 layers.

Opto-electrical properties of solution based carbon nanotube electrode (용액코팅된 탄소나노튜브 전극의 광전기적 성질)

  • Woo, Jong-Seok;Kim, Sun-Young;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.394-394
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    • 2007
  • Transparent conductive films can serve as a critical component in displays, solar cells, lasers, optical communication devices, and solid state lighting. Carbon nanotube (CNT) based transparent conductive films are fabricated on glass and polymer substrates. CNTs typically exist in form of quasi-crystalline bundles or highly entangled bundles containing tens of individual nanotubes. To achieve full potential, CNTs must be dispersed in a solvent or other organic media. CNTs are acid treated with nitric acid then the stable dispersion of CNTs in polar solvent such as alcohols, DMF, etc. is achieved by sonication. The solubility of CNTs correlates well with the area ratio of the D and G bands from Raman spectrum. Thin films are formed from well dispersed CNT solutions using spray coating method. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders.

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Development of Spray Coating Methods for Large Area Sol-Gel ZnO/Ag Nanowire Composite Transparent Conducting Substrates (대면적 졸-겔 산화아연/은 나노선 복합 투명 전도 기판 제조를 위한 스프레이 코팅법 개발)

  • Cho, Wonki;Baik, Seung Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.1
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    • pp.55-60
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    • 2018
  • Transparent conductive thin films (TCFs) are essential materials for solar cells, organic light-emitting diodes, and display panels. Indium tin oxide (ITO) is one of the most widely used commercial materials to create TCFs'; however, new materials that can possibly replace ITO at a lower cost and/or those possessing mechanical flexibility are urgently needed. Silver nanowire (AgNW) is one of those promising materials, as it is less expensive and possesses superior mechanical flexibility as compared to ITO. We used AgNW and sol-gel ZnO to fabricate composite thin films by spray coating. We propose two spray-coating methods: the 'metal-organic chemical vapor deposition (MOCVD)/AgNW' method and the Mixture method. These two methods are expected to be commercialized for high-quality and low-cost products, respectively.

Properties of Nano-Hybrid Coating Films Synthesized from Colloidal Silica-Silane (콜로이달 실리카와 실란으로부터 합성된 나노하이브리드 코팅 박막의 특성)

  • Na, Moon-Kyong;Ahn, Myeong-Sang;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.232-233
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    • 2006
  • In recent years the interest in organic/inorganic hybrid materials has increased at a fast rate. Nano organic-inorganic hybrid composites have shown advantages for preparing hard coating layers. Especially, nano hybrid composite has low environmental pollution. It has high transparency, hardness, toughness, thermal dissociation temperature, hydrophobicity by using nano sized inorganic material. There are many ways in which these materials may be synthesized, a typical one being the use of silica and silanes using the sol-gel process. The structure of sol-gel silica evolves as a result of these successive hydrolysis and condensation reactions and the subsequent drying and curing. The sol-gel reactions are catalyzed by acids and produce silica sol solutions. The silica sol grows until they reach a size where a gel transition occurs and a solid-like gel is formed. Colloidal silica(CS)/silane sol solutions were synthesized in variation with parameters such as different acidity and reaction time. In order to understand their physical and chemical properties, sol-gel coating films were fabricated on glass. From all sol-gel solutions, seasoning effect of sol-gel coating layer on glass was observed.

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Characterization and fabrication of one component solution based CNT/epoxy binder conductive films (일액형 탄소나노튜브/에폭시 바인더 코팅액을 이용한 전도성 필름 제조 및 특성 분석)

  • Han, Joong-Tark;Woo, Jong-Seok;Kim, Sun-Young;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.455-456
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    • 2007
  • Optically transparent, highly conductive coating have been major theme of thin film science efforts for some years. In this work, t-MWNT(thin Multi-walled Carbon Nanotubes) are acid treated, then the stable dispersion of t-MWNTs in polar solvent such as alcohols, was achieved by sonication. The transparent conducting films are prepared using the one component solution of t-MWNT/epoxy binder via spray coating on glass substrate. The characterization of acid treated t-MWNTs was performed by Raman spectrometer. The opto-electrical properties of conducting films are analyzed by the binder concentration, and the effect of co-solvent on the compatibility and dispersibility of one component t-MWNT/epoxy binder solutions are discussed.

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Microstructure Evolution of Cu-based BMG Coating during APS Process and Phase Analysis by Nano-indentation Test (대기 플라즈마 용사공정을 이용한 Cu계 벌크 비정질 금속 코팅의 미세조직 분석과 나노 압입시험을 이용한 상 분석)

  • Kim, Jung-Hwan;Kang, Ki-Cheol;Yoon, Sang-Hoon;Na, Hyun-Taek;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.27 no.6
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    • pp.43-48
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    • 2009
  • In this study, Cu-based bulk metallic glass (BMG) coatings were deposited by atmospheric plasma spraying (APS) process with different process conditions (with- and without hydrogen gas). As adding the hydrogen gas, thermal energy in the plasma flame increased and induced difference in the melting state of the Cu-based BMG particles. The microstructure and mechanical properties of the coatings were analyzed using a scanning electron microscope (SEM) with an energy dispersive spectroscopy (EDS) and nano-indentation tester in the light of phase analysis. It was elucidated by the nano-indentation tests that un-melted region was a mainly amorphous phase which showed discrete plasticity observed as the flow serrations on the load.displacement (P - h) curves, and the curves of solidified region showed lower flow serrations as amorphous phase mingled with crystalline phase. Oxides produced during the spraying process had the highest hardness value among the phases and were well mixed with other phases resulted from the increase in melting degree.

Critical heat flux measurement experiment to improve safety of copper nano-particle coated heat exchanger (구리나노입자가 코팅된 열교환기의 안전성 향상을 위한 임계 열유속 측정실험)

  • Mo, Yong-Hyun;Kim, Nam-Jin;Jeon, Yong-Han;Lee, Deok-Soo
    • Journal of the Korea Safety Management & Science
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    • v.19 no.4
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    • pp.317-322
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    • 2017
  • When the heat flux on the heating surface following changing heat condition in the boiling heat transfer system exceeds critical heat flux, the critical heat flux phenomenon is going over to immediately the film boiling area and then it is occurred the physical destruction phenomenon of various heat transfer systems. In order to maximize the safe operation and performance of the heat transfer system, it is essential to improve the CHF(Critical Heat Flux) of the system. Therefore, we have analysis the effect of improving CHF and characteristics of heat transfer following the nanoparticle coating thickness. As the results, copper nanocoating time are increased to CHF, and in case of nano-coatings are increased spray-deposited coating times more than in the fure water; copper nanopowder is increased up to 6.40%. The boiling heat transfer coefficients of the pure water are increased up to 5.79% respectively. Also, the contact angle is decreased and surface roughness is increased when nano-coating time is increasingly going up.

Synthesis of High Concentrated $TiO_2$ Nano Colloids and Coating on Boron Nitride Powders (고순도로 합성된 나노콜로이드 티타늄옥사이드의 BN 파우더 코팅에 관한 연구)

  • HYEIN JANG;KYUNGCHUL LEE;SUNGHO HONG;HONGKEUN JI
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.28 no.1
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    • pp.214-224
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    • 2002
  • High concentrated $TiO_2$ nano colloids were synthesized by sol-gel method. Reactions were performed in $TiCl_4$/HCl/$H_2O$ aqueous solution and the conditions of particles such as shape, size and aggregation, etc. were controlled by polymerization and adsorption of acrylamide in surface of $TiO_2$ nano particles. And also, aminopropyltriethoxysilane was added instead of acrylamide and compared each other. The prepared colloids were well dispersed and showed the strong absorption peaks at 350nm-370nm which is blue shifted to 20-30nm, compared to macro particles. The obtained techniques from $TiO_2$ nato colloids synthesis were utilized in coating on boron nitride powders which are nonpolar and isoelectronic materials of carbon. Their surface morphology, structure, thermal stability and U. V absorption chracteristics were examined by SEM(Scanning Electron Microscopy), XRD(X-ray diffraction), TG/DTA(Thermogravimetric and Differential Thermal Analysis), UV-VIS(Ultraviolet-Visible Spectroscopy).

Transport of PVP-coated Silver Nanoparticles in Saturated Porous Media (포화된 다공성매체에서 PVP-코팅된 은나노입자의 이동성 연구)

  • Bae, Sujin;Jang, Min-Hee;Lee, Woo Chun;Park, Jae-Woo;Hwang, Yu Sik
    • Journal of Soil and Groundwater Environment
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    • v.21 no.1
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    • pp.104-110
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    • 2016
  • The transport of silver nanoparticles (AgNPs) was investigated through a column packed with sand. A series of column experiments were carried out to evaluate the effect of ionic strength (IS), pH, electrolyte type and clay mineral on mobility of polyvinylpyrrolidone-coated silver nanoparticles (PVP-AgNPs). The deposition of PVP-AgNPs was increased with increasing solution ionic strength and decreasing pH. Furthermore, the depositon of PVP-AgNPs was affected by the electrolyte type (NaCl vs. NaNO3) and was shown to be greater at NaNO3 solution. Also, the transport of PVP-AgNPs was greatly increased after the pre-deposition of clay particles on sand. Our results suggest that various environmental factors can influence the mobility of PVP-AgNPs in soil-groundwater systems and should be carefully considered in assessing their environmental risks.

Effect of Thermal Post-Treatment using the Black Body Networking of Carbon Nano Structure For Internal Conduction from Solar Radiation (태양복사열 내부전도 성능향상을 위한 탄소 나노구조체 흑체코팅 열처리 효과연구)

  • Kim, Dae Weon;Jang, Seong Min;Lee, Du Hui;Park, June Yi;Kim, Young Bae
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.4
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    • pp.159-164
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    • 2021
  • The Improvement of thermal performance using heat treatment of carbon nanotubes coated on the copper heat sink to take the radiation energy from solar ray for the energy harvesting in earth orbit. Using the additive coating of purified CNT for the increase of specific area and development of thermal conductive capacity, the performance of heat transfer is improved about 0.181 K/W while applying the power of 22 W under temperature of 3.98℃. Coating of purified CNT shows increase of area and volume of thermal layer however it led the partial thermal resistance.