• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.371.1-371.1
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• 2016

다양한 물질계의 2차원 나노구조는 그래핀과 함께 그 고유특성으로 최근 광전소자, 전자소자, 센서, 에너지 생성 및 저장과 수소에너지 생성 등의 응용으로 매우 많은 관심을 받고 있다. 특히 층상이중수산화물 (layered-double hydroxide; LDH) 2차원 나노구조는 생성의 용이성과 층상 내 금속 이온의 교환을 통한 특성의 자유로운 제어가 가능하므로 많은 관심을 받고 있다. 층상이중수산화물 화합물은 [Zn(1-x) MIII(x)(OH)2][$An-x/n{\cdot}mH2O$] (MIII = Al, Cr, Ga; An- = CO32-, Cl-, NO3-, CH3COO-) 구조로써, Brucite-type 구조 내에서 3가 양이온의 상태에 따라서 다양한 특성을 제어할 수 있는 장점이 있다. 이러한 장점으로 인해 층상이중수산화물 화합물은 촉매나, 에너지 저장, 음이온 교환 및 흡착, 화학적 촉매, 바이오 소자 등에 응용이 연구되고 있으며, 다양한 금속 산화물을 제조하기 위한 중간자 precursor로써도 연구되고 있다. 하지만, 이러한 대부분의 연구들을 통한 결과물들이 분말 및 수용액 상태로 남게 되며, 이러한 화합물의 특성을 제어하기 어려운 문제점이 있다. 더욱이 이러한 나노구조물들을 다양한 소자로 응용하기 위해서는 상용의 실리콘이나 glass 등의 기판형태의 물질상에 성장시킬 수 있어야 하며, 그러한 기판 위에서의 형상 및 특성 제어가 용이해야 한다. 따라서 본 연구에서는 실리콘 기판을 적용한 Zn기반의 층상이중 수산화물 화합물을 성장하고, 하부물질의 조성제어를 통한 층상이중수산화물 화합물의 형상제어가 가능한 기술에 관한 연구를 보고하고자 한다. 이를 위한 하부물질의 조성은 Zn와 Al을 통해 이루어지며, 기형성된 Al2O3박막을 핵형성층으로 활용한다. 이러한 방법으로 형성된 층상이중수산화물 화합물에 대해 이차전자주사현미경, 투과전자현미경 및 X-ray회절기법을 통해 구조분석을 하고, Raman 및 광발광스펙트럼 분석을 통해 광학적 분석을 시행함으로써, 층상이중수산화물이 기판상에서 형성되는 메커니즘에 관한 규명을 시행하였다. 이러한 분석연구를 통해 핵형성층의 에칭 따라 실리콘 기판상에서 성장하는 층상이 중수산화물 화합물의 형상 및 조성이 제어되는 메커니즘을 구명하였다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.112.2-112.2
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• 2007

• Journal of the Korean Chemical Society
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• v.48 no.1
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• pp.46-52
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• 2004

The effect of crystallinity on the structural stability of layered manganese oxide has been systematically investigated. While well-crystalline manganate was prepared by solid-state reaction-ion exchange method, nanocrystalline one was obtained by Chimie-Douce reaction at room temperature. According to micro-Raman and Mn K-edge X-ray absorption spectroscopic results, manganese ions in both the manganese oxides are stabilized in the octahedral sites of the layered lattice consisting of edge-shared MnO6 octahedra. The differential potential plot clarifies that the layered structure of nanocrystalline material is well maintained during electrochemical cycling, in contrast to the well-crystalline homologue. From the micro-Raman results, it was found that delithiation-relithiation process for well-crystalline material gives rise to the structural transition from layered to spinel-type structure. On the basis of the present experimental findings, it can be concluded that nanocrystalline nature plays an important role in enhancing the structural stability of layered manganese oxides.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.213-214
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• 2007

에폭시/마이카는 높은 절연성과 강도, 열 안정성 등으로 인하여 고전압 회전기 고정자 권선의 절연재료로 사용되고 있다. 그러나 최근 청단기기의 등장과 냉난방 부하의 증가로 첨두 부하가 크게 증가하여 발전기 부하변동과 자동 정지횟수가 빈번해지고 있다. 이에 따라 기존에 사용되고 있는 절연재료를 획기적으로 발전시킨 새로운 소재의 개발이 필요하게 되었다. 최근 나노기술은 이러한 기술적 한계를 극복할 수 있는 좋은 대안으로 떠오르고 있다. 그리고 나노 크기의 층상화합물은 기존의 재료에 비해 월등한 전기적, 기계적, 열적 특성을 지닌 것으로 알려져 있다. 본 논문에서는 에폭시 기지에 층상 마이카와 점토를 혼합한 나노복합재료를 제조하여 주파수별, 온도별 유전특성을 살펴보았다.

• Polymer(Korea)
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• v.24 no.4
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• pp.571-577
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• 2000

A new type of filler for epoxy-clay nanocomposites has been prepared by the reaction of octadecyltrimethylammonium bromide and layered sodium montmorillonite (MMT) via an ion-exchange reaction. The gallery space was further modified by grafting the aminopropyl groups via a reaction between a octadecyltrimethylammonium-MMT and 3-aminopropyltriethoxysilane (APS). The interlayer modification of MMT was confirmed by XRD, IR, and solid-state $^{29}$ Si CP/MAS NMR. Furthermore, clay-polymer nanocomposites have been synthesized by the polymerization of diglycidyl ether of bisphenol A(DGEBA) and $C_{18}$ H$_{37}$ N($CH_3$)$_3$-APS-MMT. The resulting hybrid nanocomposites were characterized by XRD, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The results proved that the organomontmorillonite could be exfoliated and uniformly dispersed in the epoxy matrix.

• Journal of the Korean Magnetics Society
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• v.22 no.1
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• pp.11-14
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• 2012

The composites of expanded graphite oxide and magnetic nanoparticle (Ni and Co) were synthesized by using simple chemical method. From the raw material natural graphite, the expanded graphite was fabricated using sulfuric acid and $1^{st}$ heat treatment at $600^{\circ}C$ for 1 hour. The expanded graphite was changed to expanded graphite oxide by 2nd heat treatment at $1050^{\circ}C$ for 15 sec and chemical oxidation. The expanded graphite oxide/1-methyl-2-pyrrolidone solution reacts with the magnetic nanoparticle to form a magnetic graphite oxide composite. These graphite-based materials were characterized by x-ray diffractometer, Raman spectroscopy, transmission electron microscope, and vibration sample magnetometer. We expect that these results of this paper were become basis research of graphite oxide composite.

• Journal of the Korean Chemical Society
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• v.59 no.1
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• pp.36-44
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• 2015

This article describes synthesis and electrochemical properties of layer-by-layer self-assembled multilayer film composed of polyaniline (PANi), graphene oxide (GO) and phytic acid (PA), whereby the GO was electrochemically reduced to ERGO, resulting in $(PANi/ERGO/PANi/PA)_{10}$ film electrode. Especially, we examined the possibility to improve the volumetric capacitive property of $(PANi/ERGO)_{20}$ film electrode via combining a spherical hexakisphosphate PA nanoparticle into the multilayer film that would dope PANi properly and also increase the porosity and surface area of the electrode. The electrochemical performances of the multilayer film electrodes were investigated using a three-electrode configuration in 1 M $H_2SO_4$ electrolyte. As a result, the $(PANi/ERGO)_{20}$ electrode showed the volumetric capacitance of $666F/cm^3$ at a current density of $1A/cm^3$, which was improved to the volumetric capacitance of $769F/cm^3$ for the $(PANi/ERGO/PANi/PA)_{10}$ electrode, in addition to the cycling stability maintained to 79.3% of initial capacitance after 1000 cycles. Thus, the electrochemical characteristics of the $(PANi/ERGO)_{20}$ electrode, which was densely packed by ${\pi}-{\pi}$ stacking between the electron-rich conjugate components, could have been improved through structural modification of the multilayer film via combining a spherical hexakisphosphate PA nanoparticle into the multilayer film.

• Fire Science and Engineering
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• v.20 no.4 s.64
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• pp.72-76
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• 2006

Polymer/clay nanocomposites have generated considerable interests in the past decade because adding just tiny amount of clay to the polymer matrix could produce a dramatic enhancement in physical, thermal and mechanical properties. Smectite clays, such as montmorillonite (MMT), are of great industrial value because of their high aspect ratio, plate morphology, intercalative capacity, natural abundance and low cost. In this study, PE/MMT nanocomposites were directly prepared by melt intercalating PE and the modified clay. The nanostructure was verified by X-ray diffraction (XRD) and transmission electron microscopy (TEM), and their flame retardant properties were measured and discussed by limiting oxygen index (LOI), char yield and smoke mass concentration. And their thermal stabilities were measured by differential thermogravimetric (DTG) and thermogravimetric analysis (TGA). The PE/MMT nanocomposites proved more effective the conventional composites in reinforcement. Two functions in the thermal stability of the PE/MMT nanocomposite, one is the barrier effect to improve the thermal stability, and another is catalysis, leading to a decrease of the thermal stability. The flammability was greatly decreased due to the formation of the clay-enriched protective char during the combustion.