• Title/Summary/Keyword: 김철환

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Characteristics of Thermomechanical Pulps Made of Russian Spruce and Larix, and Myanmar Bamboo (러시아산 가문비와 낙엽송, 그리고 미얀마산 대나무로 제조한 열기계펄프 특성 연구)

  • Lee, Ji-Young;Kim, Chul-Hwan;Nam, Hyegeong;Park, Hyunghun;Kwon, Sol;Park, Dong-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.135-146
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    • 2016
  • Three fiber sources including Russian spruce (Picea jezoensis) and larix (Larix leptolepis), and Myanmar bamboo (Phyllostachys bambusoides) for thermomechanical pulp were explored to replace domestic pine (Pinus densiflora) pulp that has some limitations in an aspect of supply and pitch trouble. Thermomechanical pulps were manufactured under the identical condition, and then compared with their representative pulp properties and pulping process. Both Russian larix and Myanmar bamboo contained large amounts of extractives that would negatively affect mechanical pulping processes. Russian spruce showed the least contents in shives and pitch. Russian spruce and domestic pine reached an optimum freeness level within a short pulp processing time, which consumed less amount of refining energy compared to larix and bamboo. In particular, the spruce wood showed the highest brightness level which might lead to a less consumption of bleaching chemicals. It was expected that Russian spruce could be replaced with the domestic pine wood in respect of both pulping process and pulp quality.

The Prediction of tong-Term Creep Behavior of Recycled PET Polymer Concrete (단기 크리프 실험을 이용한 PET 재활용 폴리머콘크리트의 장기 크리프거동 예측)

  • Jo Byung-Wan;Tae Ghi-Ho;Kim Chul-Hwan
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.521-528
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    • 2004
  • In general, polymer concrete has more excellent mechanical properties and durability than Portland cement concrete, but very sensitive to heat and has large deformations. In this study, the long-term creep behaviors was predicted by the short-term creep test, and then the characteristic of creep of recycled-PET polymer concrete was defined by material and experimental variables. The error in the predicted long-term creep values is less than 5 percent for all polymer concrete systems. The filler carry out an important role to restrict the creep strains of recycled PET Polymer concrete. The creep strain and specific on using the $CaCO_3$ were less than using fly-ash. The creep increases with an increase in the applied stress, but not proportional the rate of stress increase ratio. The creep behavior of polymer concrete using recycled polyester resin is not a linear viscoelastic behavior.

Antimicrobial Activities of Botanical Antimicrobial Agent-Grapefruit Seed Extract Mixture for the Preparation of Anitimicrobial Packaging Paper (항균포장지 제조용 식물성 자몽종자추출물제재의 항균특성)

  • Cho Sung-Hwan;Kim Chul-Hwan;Park Woo-Po
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.411-416
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    • 2004
  • Botanical antimicrobial agent-grapefruit seed extract mixture(BAAG), which could be applied to the preparation of antimicrobial packaging paper, was investigated in order to prove the preservative function of fruits and vegetables. HAAG showed remarkable antimicrobial effects against Fusarium solani Botrytis cinerea, Pencillium crustosum, Erwinia carotovora, Phoma destructiva and Alternaria radicina causing the postharvest decay of fruits and vegetables. We have examined that HAAG could inhibit the growth of microorganims when treated with more than 500 $\mu$g/mL concentration. The activities of HAAG were stable in the wide spectrum of pH and temperature. Direct visualization of microbial cells by using scanning electron microscope showed the loss of microbial cell membrane function, which was destroyed by treating with the dilute solutions of HAAG. We could confirm that HAAG be an antimicrobial agent for the preparation of antimicrobial packaging paper.

Inhibitory Effect of Grapefruit Seed Extract Mixture on the Physiological Function of Botrytis cinerea (식물성 항균소재 처리가 Botrytis cinerea의 생리기능에 미치는 저해효과)

  • Cho Sung-Hwan;Kim Chul-Hwan;Park Woo-Po
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.417-423
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    • 2004
  • Botanical antimicrobial agent-grapefruit seed extract mixture (BAAG) have an unknown compounds which exhibit the antibiotic activities aganist microorganisms including bacteria and fungi. We have examined the effects of BAAG on the physiological function of Botrytis cinerea which was isolated from necrotic lesions of decayed fruits and vegetables such as cucumbers, grapes, tomatoes, and red peppers during storage. In the results of enzymatic activities related to the energetic metabolism there was no inhibitory effect of BAAG on the activities of several enzymes in vitro including glucose 6-phosphate dehydrogenase and malate dehydrogenase, while there was inhibitory effect of BAAG on the activities of hexokinase and succinate dehydrogenase. O-nitrophenyl-$\beta$-D-galactopyranoside(ONPG), the artificial substrate of $\beta$-galactosidase was hydrolyzed in the presence of BAAG, indicating that the membrane was pertubated by the BAAG. From the results we suggested that the antibiotic activity of BAAG is due to the change of membrane permeability of the cell. BAAG was fractionated and purified by silica gel and sephadex column chromatography. Among active fractions two peaks were identified as naringin and limonin when they were analyzed by by NMR and Fast atomic bombardment.

Study of Oil Palm Biomass Resources (Part 3) - Torrefaction of Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 III - 오일팜 바이오매스의 반탄화 연구 -)

  • Cho, Hu-Seung;Sung, Yong Joo;Kim, Chul-Hwan;Lee, Gyeong-Seon;Yim, Su-Jin;Nam, Hyeo-Gyeong;Lee, Ji-Young;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.1
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    • pp.18-28
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    • 2014
  • Renewable Portfolio Standards(RPS) is a regulation that requires a renewable energy generated from eco-friendly energy sources such as biomass, wind, solar, and geothermal. The RPS mechanism generally is an obligatory policy that places on electricity supply companies to produce a designated fraction of their electricity from renewable energies. The domestic companies to supply electricity largely rely on wood pellets in order to implement the RPS in spite of undesirable situation of lack of wood resources in Korea. This means that the electricity supply companies in Korea must explore new biomass as an alternative to wood. Palm kernel shell (PKS) and empty fruit bunch (EFB) as oil palm wastes can be used as raw materials used for making pellets after their thermochemical treatment like torrefaction. Torrefaction is a pretreatment process which serves to improve the properties including heating value and energy densification of these oil palm wastes through a mild pyrolysis at temperature typically ranging between 200 and $300^{\circ}C$ in the absence of oxygen under atmospheric pressure. Torrefaction of oil palms wastes at above $200^{\circ}C$ contributed to the increase of fixed carbon with the decrease of volatile matters, leading to the improvement of their calorific values over 20.9 MJ/kg (=5,000 kcal/kg) up to 25.1 MJ/kg (=6,000 kcal/kg). In particular, EFB sensitively responded to torrefaction because of its physical properties like fiber bundles, compared to PKS and hardwood chips. In conclusion, torrefaction treatment of PKS and EFB can greatly contribute to the implement of RPS of the electricity supply companies in Korea through the increased co-firing biomass with coal.

Study of Alkaline Peroxide Mechanical Pulp Made from Pinus densiflora (국내산 소나무로 제조된 APMP 특성 연구)

  • Lee, Ji-Young;Nam, Hyegeong;Kim, Chul-Hwan;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Lee, Min-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.100-110
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    • 2016
  • Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

Analysis of the Behavior of Fluorescent Whitening Agents in Recycling Process of White Ledger (형광증백제가 함유된 백상고지의 재활용에 따른 형광증백제의 거동 분석)

  • Lee, Ji Young;Kim, Chul Hwan;Park, Jong-Hye;Kim, Eun-Hea;Sung, Yong Joo;Heo, Young-Jun;Kim, Young-Hoon;Kim, Yeon-Oh
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.52-58
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    • 2015
  • White ledger usually includes white office paper, computer paper, and copy machine paper. Because these grades need high optical properties, fluorescent whitening agents (FWAs) are widely used in the papermaking process. FWAs are the most powerful and effective chemical used to obtain high CIE whiteness and ISO brightness in papers. The rising demand for white or ultra-white papers has increased the use of FWAs. However, FWAs used in white ledger can restrict its use, even though white ledger is widely used as a raw material in paperboard mills. Therefore, it is necessary to develop methods to control FWAs from white ledger to increase its use in paperboard mills. In this study, the behaviors of disulpho fluorescent whitening agent (D-FWA), tetrasulpo fluorescent whitening agent (T-FWA), and hexasulpho fluorescent whitening agent (H-FWA) during the recycling process were identified as a first step to remove FWAs from white ledger. We prepared four types of papers (dyed with D-FWA, T-FWA, and H-FWA), disintegrated these papers, and made handsheets. This recycling process was carried out three times in a laboratory. After each round of recycling, the hand-sheets' CIE whiteness and fluorescence index were measured, and the distribution of FWAs in the Z-direction was observed using CLSM images. FWA reductions in the model papers were calculated using fluorescence indices as a function of the number of recycling. FWAs in handsheets containing T-FWA and H-FWA decreased linearly as a function of the number of recycling, but D-FWA did not show a significant reduction in the fluorescence index after recycling. T-FWA and H-FWA showed similar distributions of D-FWA after recycling. Therefore, as much T-FWA and H-FWA as possible must be detached in the early processes of papermaking at paperboard mills.

Study of Oil Palm Biomass Resources (Part 4) Study of Pelletization of Torrefied Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 IV - 반탄화된 오일팜 바이오매스의 펠릿 성형 특성 연구 -)

  • Sung, Yong Joo;Kim, Chul-Hwan;Lee, Ji-Young;Cho, Hu-Seung;Nam, Hye-Gyeong;Park, Hyeong-Hun;Kwon, Sol;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.24-34
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    • 2015
  • Domestic companies supplying electricity must increase obligatory duty to use renewable energy annually. If not met with obligatory allotment, the electricity-supply companies must pay RPS (Renewable Portfolio Standards) penalty. Although the power plants using a pulverizing coal firing boiler could co-fire up to around 3 per cent with wood pellets mixed in with coal feedstock without any major equipment revamps, they recorded only about 60 per cent fulfillment of RPS. Consequently, USD 46 million of RPS penalty was imposed on the six power supplying subsidiaries of GENCOs in 2014. One of the solutions to reduce the RPS penalty is that the power supply companies adopt the co-firing of torrefied lignocellulosic biomass in coal plants, which may contribute to the use of over 30 per cent of torrefied biomass mixed with bituminous coals. Extra binder was required to form pellets using torrefied biomass such as wood chips, PKS (Palm Kernel Shell) and EFB (Empty Fruit Bunch). Instead of corn starch, 30, 50 and 70 per cent of Larix saw dusts were respectively added to the torrefied feedstocks such as Pinus densiflora chips, PKS and EFB. The addition of saw dusts led to the decrease of the calorific values of the pellets but the forming ability of the pelletizer was exceedingly improved. Another advantage from the addition of saw dusts stemmed from the reduction of ash contents of the pellets. Finally, it was confirmed that torrefied oil palm biomass such as PKS and EFB could be valuable feedstocks in making pellets through improved binding ability.

Quality Characteristics of Cherry Tomatoes Packaged with Paper Bag Incorporated with Antimicrobial Agents (항균소재를 함유한 포장재에 의한 방울토마토의 저장중 품질 특성 변화)

  • Park, Woo-Po;Cho, Sung-Hwan;Kim, Chul-Hwan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.8
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    • pp.1381-1384
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    • 2004
  • In order to help the preservation of the cherry tomatoes, antimicrobial paper incorporating grapefruit seed extract and zeolite was applied to packaging fruits. The fruits were packed with a paper bag of 15.5${\times}$24 cm and then stored at 1$0^{\circ}C$. During the storage, weight loss, pH, total acidity, soluble solid content, microbial load and decay were measured as quality indices. Steady weight loss due to the transpiration was observed to slightly increase the solid content during the storage with little difference between the packaging treatments. There were little change in pH and acidity of the stored fruits. The microbial loads of total aerobic bacteria, and yeast/mold counts were significantly suppressed during 10 day storage by the antimicrobial paper packaging, which also contributed to reducing the decayed fruits observed after 15 days.

Building TRMS S/W based on Reliability Centered Maintenance (신뢰성 기반의 유지보수를 위한 TRMS S/W개발)

  • Ahn, E.J.;Lee, K.S.;Lee, K.S.;Kim, S.O.;Yoo, D.Y.;Kim, C.H.;Yoon, H.S.;Lee, I.H.;Oh, S.H.
    • Journal of the Korean Society for Railway
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    • v.13 no.2
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    • pp.159-165
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    • 2010
  • In this paper the TRMS (Tilting Rolling-stock Maintenance System) that applies the concept of RAM (Reliability, Availability, and Maintainability) and RCM (Reliability Centered Maintenance) to Preventive and Corrective Maintenance Policy for TTX (Tilting Train Express) will be discussed. We will briefly introduce the RCM concepts and discus show these concepts and procedures are implemented in the TRMS S/W. In the TRMS S/W there are four modules, System and Operations Information Module, FMECA(Failure Modes, Effects, and Criticality Analysis)module, RAM Information Module, and RCM Analysis Module. The System and Operations Information Module provides the user interface for collection of systems and operations related data and the FMECA module provides a groundwork for the RCM analysis. The algorithms to calculate the reliability and failure rate for Weibull distribution and formulae to calculate the task intervals and task costs are proposed in the RAM and RCM Analysis Module respectively. There is a good possibility of applying RCM to other rolling stock maintenance systems if the benefit that RCM can brings to the maintenance world is fully recognized.