• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.149-154
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• 2012

The adsorption and desorption behavior of biofilter-medium was investigated on the performance of an adsorption column. Continuous flow-isothermal adsorption experiments were performed to treat waste air containing such a VOC as ethanol under the same condition of > 90% relative humidity as the condition of the feed to a biofilter process. In case of feeding waste air containing ethanol of 1,000 ppmv (or 2,050 mg ethanol/$m^3$) to the adsorption system at the rate of 2 L/min, the onsets of its breakthrough and reaching the state of dynamic equilibrium at the exit had been delayed 10 and 3 times, respectively, later than those at the 1st stage sampling port. Moreover, in case of 2,000 ppmv (or 4,100 mg ethanol/$m^3$), they had been delayed 9 and 3 times, respectively. Thus, regardless of feeding concentration, the ratios of delaying period were observed to be quite consistent each other at the exit of the adsorption column. With regard to the period of desorption, the ratios of delaying period were consistent each other to be 1.5 for both cases. In addition, the effect of microbial activity and sterilization-process was studied on adsorption equilibrium. The ethanol concentration in the vapor phase of vials packed with sterilized granular activated carbon (GAC) was quite consistent to that with unsterilized GAC. However, the ethanol concentrations in the vapor phase of vials packed with unsterilized compost and the unsterilized mixture of GAC and compost were higher than those with sterilized compost and the sterilized mixture of GAC and compost, respectively.

• Korean Journal of Animal Reproduction
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• v.26 no.3
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• pp.299-308
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• 2002

In horse, a single gene encodes both eCG and eLH $\beta$ subunits. The difference between eCG and eLH lies in the structure of their glycoresidues, which are both sialylated and sulfated in LH and sialylated in CG eCG consists of highly glycosyiated $\alpha$- and $\beta$-subunits and is an unique member of the gonadotropin family because it elicits response characteristics of both FSH and LH in other species than the horse. This dual activity of eCG in heterologous species is of fundamental interest to the study of gonadotropin structure-function relationships and the understanding of the molecular bases of the specific interactions of these hormones with their receptors. Thus, eCG is a dintinct molecule from the view points of its biological function and glycoresidue structures. The oligosaccharide at Asn 56 of the $\alpha$-subunit plays an indispensable role, whereas the carboxyl-terminal extension of the eCG $\beta$-subunit with its associated O-linked oligosaccharides is not improtant for, the in vitro LH-like activity of eCG. In contrast, both N- and O-linked oligosaccharides play important roles for FSH-like activity and increase FSH-like activity by removal of N- and O-linked oligosaccharides. Therefore, the dual LH- and FSH-like activities of eCG can be clearly separated by removal of either the N-linked oligosaccharide on the $\alpha$-subunit or CTP-associated O-linked oligosaccharides from its $\beta$-subunit. The glycoresidues seem to play crucial roles fer biological activities. The tethered-eCG was effciently secreted and showed similar LH-like activity to the dimeric eCG $\alpha$/ $\beta$ and native eCG. FSH-like activity of the tethered-eCG was also shown similarly in comparison with the native and wild type eCG $\alpha$/ $\beta$. Our data for the first time suggest that the tethered-eCG can be expressed efficiently and the produced product by the CHO-Kl cells is fully LH- and FSH-like activities in rat in vitro bioassay system. Our results also suggest that this molecular can imply particular models ot FSH-like activity not LH-like activity in the eCG. Taken together, these data indicate that the constructs of tethered molecule will be useful in the study of mutants that affect subunit association and/or secretion.

• Journal of the Korean Chemical Society
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• v.65 no.3
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• pp.197-202
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• 2021

In this study, activated clay treated with H₂SO₄ (20% by weight) and heat at 90 ℃ for 8 h for acid white soil was used as an adsorbent for the removal of PO₄^3--P in water. Prior to the adsorption experiment, the characteristics of activated clay was examined by X-ray Fluorescence Spectrometry (XRF) and BET surface area analyser. The adsorption of PO₄^3--P on activated clay was steeply increased within 0.25 h and reached equilibrium at 4 h. At 5 mg/L of low PO₄^3--P concentration, roughly 98% of adsorption efficiency was accomplished by activated clay. The adsorption data of PO₄^3--P were introduced to the adsorption isotherm and kinetic models. It was seen that both Freundlich and Langmuir isotherms were applied well to describe the adsorption behavior of PO₄^3--P on activated clay. For adsorption PO₄^3--P on activated clay, the Freundlich and Langmuir isotherm coefficients, K_F and Q, were found to be 8.3 and 20.0 mg/g, respectively. The pseudo-second-order kinetics model was more suitable for adsorption of PO₄^3--P in water/activated clay system owing to the higher correlation coefficient R² and the more proximity value of the experimental value q_e,exp and the calculated value q_e,cal than the pseudo-first-order kinetics model. The results of study indicate that activated clay could be used as an efficient adsorbent for the removal of PO₄³-P from water.

• Journal of the Korean Society for Precision Engineering
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• v.31 no.10
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• pp.955-965
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• 2014

Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.1309-1314
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• 2008

I.G.G is abbreviation for Inert Gas Generator, High temperature in Cargo Tank it desulfurize, exhausted and froze the gas that combined brimstone element and soot, then supply Inert gas by blower, and mack tank inside incombustible range this is equipment that nip in the bud the explosion. The blower for suppling inactivated gas has big impeller with heavy weight to achieve the high pressure, it causes a delay for first operation time and too much load is delivered to motor, total destruction by fire of motor is happening frequently. On this research, we will reduce the size & weight of impeller and install it with several stage, it makes an effect for reducing the first operation time. We also intend to contribute to efficient IGG blower design by research a flowing & pressure specialty from the diameter of impeller, number of blade, and size of casing.

• Journal of the Korean Chemical Society
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• v.37 no.4
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• pp.396-400
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• 1993

The structure-activity relationship of photo-skinsensitizing psoralens has been investigated by the MM2, FMO, molecular connectivity methods. The molecular complexes between DNA and photoskinsensitizing psoralens are discussed in terms of their differing abilities to complex and react with psoralen interstrand cross linking DNA base. The photoskinsensitiziers are analyzed with respect to the sterographics models of the active sites of the psoralens and frontier orbital density is closely correlated with photo-skinsensitizing carcinogenic activity.

• Journal of the Institute of Convergence Signal Processing
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• v.3 no.4
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• pp.29-34
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• 2002

In this paper, we present a new geometric active contour model based on level set methods introduced by Osher and Sethian for detection of object boundaries or shape and we adopt anisotropic diffusion filtering method for removing noise from original image. In order to minimize the processing time, we use the narrow band method which allows us to perform calculations in the neighborhood of the contour and not in the whole image. Using anisotropic diffusion filtering for each slice, we have the result with reduced noise and extracted exact shape. Volume rendering operates on three-dimensional data, processes it, and transforms it into a simple two-dimensional image.

• Korean Journal of Optics and Photonics
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• v.14 no.3
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• pp.279-285
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• 2003

Wide- and flat-gain laser diodes were designed and fabricated from asymmetric multiple quantum well (AMQW) structures which consist of three compressively strained InGaAsP wells of different thicknesses. For a 400 ${\mu}{\textrm}{m}$-long lasers with as-cleaved facets, -1 ㏈ and -3 ㏈ gain bandwidth were 45 nm and 80 nm, respectively. For this AMQW structure, calculated gain spectra with various line broadening functions were compared with experimental results. We confirmed the calculated gain spectra using an asymmetric line broadening function were in good agreement with the measured data.

• Korean Journal of Food Science and Technology
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• v.32 no.5
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• pp.1191-1197
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• 2000

In the preliminary study, we investigated the anti-complementary activities of 62 extracts from Korean edible seaweeds. Of those, Pachymeniopsis elliptica showed the highest anti-complementary activity. Therefore, it was purified as follows; i) PE-1 by ethanol precipitation, ii) PE-1-C by ultrafiltration, iii) PE-1-CIV by DEAE-Toyopearl 650C, and iv) PE-1-CIV-ii by Sepharose CL-6B. The purified compound, PE-1-CIV-ii, was the complexed homogeneous polysaccharide (molecular mass: 780 kDa) with 82.9% of anti-complementary activity. Also, it contained a significant amount of sulfate group (30.5%), which indicated it as a sulfated algal polysaccharide. Its structural monosaccharides were galactose (44.3%), 3,6-anhydrogalactose (34.0%), glucose (8.2%), fucose (5.4%), xylose (5.2%) and rhamnose (2.9%). After the treatment of periodate on a sample, a significant decrease in anti-complementary activity was found, which was a characteristic of bioactive polysaccharides. And-tumor activity of PE-1-A, B and C was tested in the sarcoma-180 solid tumor model. The PE-1-C with the largest molecular mass (more than 300 kDa) showed 81% of inhibition on the solid tumors, suggesting that the anti-complementary activity was, at least in part, related to anti-tumor activity. Based upon these results, the purified polysacchardes could be an immunopotentiator in vivo.

• Korean Chemical Engineering Research
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• v.45 no.1
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• pp.73-80
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• 2007

This article aims to optimize the nitrogen removal of a sequencing batch reactor (SBR) through the use of the activated sludge model and iterative dynamic programming (IDP). Using a minimum batch time and a maximum nitrogen removal for minimum energy consumption, a performance index is developed on the basis of minimum area criteria for SBR optimization. Choosing area as the performance index makes the optimization problem simpler and a proper weighting in the performance index makes it possible to solve minimum time and energy problem of SBR simultaneously. The optimized results show that the optimal set-point of dissolved oxygen affects both the total batch time and total energy cost. For two different influent loadings, IDP-based SBR optimizations suggest each supervisory control of batch scheduling and set-point trajectory of dissolved oxygen (DO) concentration, and can save 20% of the total energy cost, while meeting the treatment requirements of COD and nitrogen. Moreover, it shows that the re-optimization of IDP within a batch can solve the modelling error problem due to the influent loading changes, or the process faults.