• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.330-331
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• 2011

희토류 이온이 첨가된 형광체는 조명, 정보 디스플레이, 태양 에너지 변환 소자에 응용 가능하기 때문에 상당한 주목을 받고 있다. 특히, 결정 입자의 형상과 크기는 산업체 응용에 있어서 중요한 변수 중의 하나이다. 구형의 형광체 입자는 형광층의 광학 및 기하학적 구조를 최적화 시킬 수 있고, 결정 입자의 크기는 양질의 코팅을 위해 필요한 결정 입자의 양에 영향을 미친다. 본 연구에서는, $YVO_4$ 모체 결정에 Eu 이온의 농도를 선택적으로 주입하여 발광 효율이 높은 적색 형광체를 합성하고자 한다. 형광체 분말 시료는 활성체인 Eu의 함량을 0.00, 0.05, 0.10, 0.15, 0.20 mol로 변화시키면서 고상 반응법을 사용하여 합성하였다. 볼밀링 작업을 수행한 후에, 60$^{\circ}C$에서 20시간 건조하였고, 잘게 갈아서 체로 걸러낸 다음에 세라믹 도가니에 넣고 전기로에서 서서히 온도를 승온시켜 500$^{\circ}C$에서 10시간 동안 하소를 실시한 후에 1,100$^{\circ}C$에서 5시간 동안 소결하였다. Eu 이온의 함량비를 변화시켜 합성한 $YVO_4$ : Eu 형광체 분말 시료의 발광 세기의 변화, 결정 구조와 표면 형상을 각각 PL과 PLE, XRD, FE-SEM 장치를 사용하여 측정한 결과들을 종합해 볼 때, Eu 이온의 비가 0.15 mol일때 발광 세기가 최대값을 나타냄을 알 수 있었으며, 더욱 Eu의 함량을 증가시키자 농도 억제 현상에 의하여 발광 세기는 급격히 감소함을 보였다. SEM으로 촬영한 결정 입자의 형상의 경우에, Eu 이온의 함량비가 증가함에 따라 결정 입자들이 더욱 조밀하게 구형에 가까운 형상을 나타냄을 관측할 수 있었다(Fig. 1). 형광체 분말의 형광 스펙트럼의 경우에, 619 nm에 주 피크를 갖는 적색 형광 스펙트럼들이 관측되었으며, Eu 이온의 함량비에 따라 형광 세기는 상당한 의존성을 나타내었다(Fig. 2). Eu 함량에 따른 결정입자의 크기, 형광 세기와 회절 피크의 반치폭 사이의 상관 관계를 제시하고자 한다.

• Journal of The Korean Association For Science Education
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• v.37 no.6
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• pp.993-1003
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• 2017

Teachers expect team-based project learning to help students develop collaborative and real-world problem solving skills. In practice, however, students tend to solve problems with simple division of labor, and there is a tendency that learning transfer does not occur in solving problems. The purpose of this study is to develop a collaborative learning model based on the transactive memory system (TMS) and to verify its effectiveness. The collaborative learning model based on the TMS is composed of three stages. The first stage is developing TMS. In this stage, the students learn physics concepts and make knowledge about the expertise of group members through peer instruction. The second stage, activating TMS, is building trust through solving well-defined problems for developing near-transfer. And in the third stage, applying TMS, the students solve an ill-defined problem based on real-world context for practicing far-transfer. Based on this model, a 15-week program including two projects on geometric optics and sound waves was developed and applied to 60 college students. The data for five weeks of one project were collected and analyzed. As a result, the TMS of the experimental group with the TMS-based collaborative learning model improved stepwise. Whereas, the difference between the first week and the last week was statistically significant, while the TMS change of the comparison group using the general project learning model was not significant. Also, the experimental group showed that the learning transfer occurred better in the project than the comparison group. A collaborative learning model based on TMS can be used to learn how students gain synergy through collaboration and how students collaboratively transfer the learned concepts in problem solving.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.8 no.2
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• pp.161-172
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• 1997

In this paper, electromagnetic scattering by a perfectly conducting strip grating on dielectric multilayers is analyzed for the normalized reflected and transmitted power by applying the Fourier-Galeakin moment method. The induced current density is expanded in a series of multiplication of chebyshev polynomials of the first kind and functions with appropriate edge boundary condition, the continuous condition of electromagnetic field is applied in the boundary planes. The confirm the validity of the proposed method, the nor- malized reflected and transmitted power obtained by varying the relative permittivity and thickness of each dielectric layers are evaluated and compared with those of the existing numerical method and a paper, and then the numerical results in this paper are in good agreement with those of the existing numerical method and the paper. The sharp variation position in the geometrically normalized reflected and transmitted power can be moved by the incident angle, grating period, and the relative permittivity and thickness of the dielectric multilayers, these sharp variation points which are called the Wood's anomaly of the Geome- trically normalized reflected power are observed as a main factor when the reflected powers of the higher order mode are transitted between propagating and evanescent modes, and the local minimum positions are slightly moved to the left hand direction in which grating period is getting small according to the increase of the relative permittivity of dielectric layers.