• Korean Journal of Food Science and Technology
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• v.11 no.2
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• pp.86-92
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• 1979

Antioxidants. BHA, BHT and PG were added to a commercial soybean oil at a level of 200 ppm, and the antioxidant-treated oils and a control oil were subjected to 30 min. heating at $150{\pm}2^{\circ}C$ and 23.5 hr. cooling at room temperature for 6 times. Variations of % antioxidant retention and some physical and chemical properties of the oils were investigated. The results of the present study were as follows. 1. The % retention of BHA, BHT and PG after the second heating and cooling was respectively 60.5, 55.7 and 40.5 %. That of BHA, BHT and PG after the 6th heating and cooling was respectively 5.7, 3.0 and 1.8 %. 2. The refractive indices and viscosity of the oils, including the control, increased slowly at first. but after 4th heating and cooling, these values increased rapidly. The color indices of the oils, including the control, increased very rapidly, but after the 2nd heating and cooling, the rates of the increase diminished considerably. 3. The efficiency of each antioxidant in suppressing peroxide, thiobarbituric acid, and acid value development decreased rapidly as the antioxidant contents of the oils decreased. After the 6th heating and cooling, the peroxide. thiobarbituric acid and acid values of the oils treated initially with the antioxidants did not differ appreciably from those of the control.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.221-226
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• 1990

The solvolysis of substitued phenacyl tosylates was studied in binary solvent mixtures of methanol-acetonitrile and methanol-acetone at 55$^{\circ}C$. Except for m-nitrophenacyl tosylate, the rate constants were increased with both of electron-donating substituents and electron-withdrawing ones and its rate constants were the largest in the binary solvent mixtures of 90% MeOH-10% MeCN. The results show that the reactions were changed with dissociative $S_N2$ mechanism judging from the magnitude of 1/m values going from the electron-withdrawing group to the electron-donating one of the substrate. And above results were consisted with the account for the PES model and QM approach.

• Journal of the Korean GEO-environmental Society
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• v.7 no.6
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• pp.113-119
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• 2006

Recently, the ground injection method using water glasses as one of the main resources and the products of these constructions have basic problems in terms of the method of constructions for the permanent foundation reinforcement and stopping leakage of water because they have some serious problems such as durability, compressive strength, injectant eluviation and so forth even though they are still used to stop leakage of water in the temporary structures. The purpose of this study is to demonstrate the strength characteristic and environment friendliness of NDS method by unconfined compressive strenth test, permeability test, length change test, leaching test, and assessment of environmental impact in comparison water glass type material. The test results show that NDS method has significant improvement of strength, permeability, volume change, and leaching. An assessment of environmental impact also demonstrates that the NDS material is environmentally friendly.

• Journal of Life Science
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• v.12 no.1
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• pp.32-42
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• 2002

It was researched to react horse serum-BChE with hefanoylthiocholine chosen among choline esters. According as number of carbon of acyl group in choline esters was increased, reactivity was decreased but strength of ES complex was increased (Km=0,140mM). The pH-V/K profile for BChE-catalyzed hydrolysis of hexanoylthiocholine yields a p $K_{a}$ =4.974$\pm$0.028. This value is equal to recent literature that shows systematic shift from dependence of activity on the basic form fo a residue that huts a p $K_{a}$ =6.2~6.4 to catalysis by a residue or residues that has a p $K_{a}$ =4.7~5.0. The resulting kinetic solvent isotope effect of hexanoylthiocholine is $^{D/V}$K=1.18. The magnitude of the isotope effect suggests that proton transfer is not an element of transition-state stabilization.n.

• 한국지구과학회:학술대회논문집
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• 2006.02a
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• pp.230-234
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• 2006

본 연구에서는 미분화 운석 중 오디너리 콘드라이트를 주사전자 현미경으로 관찰하여 열변성, 충격 변성 정도, 지구상에서의 풍화 정도에 따라서 그 구성 성분과 조직이 어떤 변화를 보이는지 알아보았다. 이를 위해 15개의 오디너리 콘드라이트에 대해 각각 연마편 및 연마박편을 준비하였으며, 주사전자 현미경 사진을 이용하여 열변성 단계별로 콘드률과 기질의 경계를 비교하였다. 열변성이 증가할수록 콘드률과 기질의 경계는 점차 모호해 진다. 충격변성을 받았는지의 유무는 감람석을 관찰하여 비교적 쉽게 인지할 수 있다. 충격변성을 받지 않은 콘드률 내의 감람석은 완전 소광과 불규칙적인 깨짐을 보이지만 충격변성을 받은 경우 파동소광과 규칙적인 깨짐을 보인다. 지구상에서 풍화를 받은 경우 철-니켈 금속의 산화가 가장 먼저 진행된다. 풍화에 의한 철산화물은 맥상으로 나타나거나 기존의 철-니켈 금속을 치환하여 나타난다. 철산화물에 의해 풍화를 받은 콘드라이트는 전체적으로 갈색을 띄게 된다.

• Restorative Dentistry and Endodontics
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• v.35 no.1
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• pp.51-58
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• 2010

Dental composites have improved significantly in physical properties over the past few decades. However, polymerization shrinkage and stress is still the major drawback of composites, limiting its use to selected cases. Much effort has been made to make low shrinking composites to overcome this issue and silorane-based composites have recently been introduced into the market. The aim of this study was to measure the volumetric polymerization shrinkage kinetics of a silorane-based composite and compare it with conventional methacrylate-based composites in order to evaluate its effectiveness in reducing polymerization shrinkage. Five commercial methacrylate-based (Beautifil, Z100, Z250, Z350 and Gradia X) and a silorane-based (P90) composites were investigated. The volumetric change of the composites during light polymerization was detected continuously as buoyancy change in distilled water by means of Archemedes' principle, using a newly made volume shrinkage measurement instrument. The null hypothesis was that there were no differences in polymerization shrinkage, peak polymerization shrinkage rate and peak shrinkage time between the silorane-based composite and methacrylate-based composites. The results were as follows: 1. The shrinkage of silorane-based (P90) composites was the lowest (1.48%), and that of Beautifil composite was the highest (2.80%). There were also significant differences between brands among the methacrylate-based composites. 2. Peak polymerization shrinkage rate was the lowest in P90 (0.13%/s) and the highest in Z100 (0.34%/s). 3. The time to reach peak shrinkage rate of the silorane-based composite (P90) was longer (6.7 s) than those of the methacrylate-based composites (2.4-3.1 s). 4. Peak shrinkage rate showed a strong positive correlation with the product of polymerization shrinkage and the inverse of peak shrinkage time (R = 0.95).

• 순환기질환의공학회:학술대회논문집
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• 2006.10a
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• pp.40-41
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• 2006

• 순환기질환의공학회:학술대회논문집
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• 2001.11a
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• pp.59-60
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• 2001

• 순환기질환의공학회:학술대회논문집
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• 2001.11a
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• pp.33-34
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• 2001

• 순환기질환의공학회:학술대회논문집
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• 2004.11a
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• pp.30-31
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• 2004